The Reaction of alpha-Chlorocarbenium Salts with Nitriles : Formation of Chloro-Substituted 2-Azoniaallene Salts

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dc.contributor.authorJochims, Johannes
dc.contributor.authorFischer, Helmut
dc.contributor.authorHamed, Atefdeu
dc.contributor.authorHuu-Phuoc, Trandeu
dc.contributor.authorHofmann, Josefdeu
dc.date.accessioned2013-07-04T06:52:15Zdeu
dc.date.available2013-07-04T06:52:15Zdeu
dc.date.issued1989
dc.description.abstractDiaryl or arylchloro substituted α-chlorocarbenium salts react with benzonitriles or dimethylcyanamide to afford chloro substituted 2-azoniaallene salts 10a, b, 11c. An X-ray structural analysis confirms the constitution of one of these salts (11c). Substitution of the chlorine atoms in 1,3-dichloro-1,3-diphenyl-2-azoniaallene hexachloroantimonate (10a) by the nucleophiles water, p-cresol, p-toluidine, diethylamine, hydrazine, methyl-, phenyl-, 2.4,6-trichlorophenylhydrazine, hydroxylamine, N-phenylhydroxylamine, 1,3-dimethylurea, and ethyl allophanate have been carried out affording heterocycles and open-chain compounds 13-21.eng
dc.description.versionpublished
dc.identifier.citationSynthesis : journal of synthetic organic chemistry ; (1989), 12. - S. 918-922deu
dc.identifier.doi10.1055/s-1989-27430deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/23551
dc.language.isoengdeu
dc.legacy.dateIssued2013-07-04deu
dc.rightsterms-of-usedeu
dc.rights.urihttps://rightsstatements.org/page/InC/1.0/deu
dc.subject.ddc540deu
dc.titleThe Reaction of alpha-Chlorocarbenium Salts with Nitriles : Formation of Chloro-Substituted 2-Azoniaallene Saltseng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Jochims1989React-23551,
  title={The Reaction of alpha-Chlorocarbenium Salts with Nitriles : Formation of Chloro-Substituted 2-Azoniaallene Salts},
  year={1989},
  doi={10.1055/s-1989-27430},
  number={12},
  volume={1989},
  issn={0039-7881},
  journal={Synthesis},
  pages={918--922},
  author={Jochims, Johannes and Fischer, Helmut and Hamed, Atef and Huu-Phuoc, Tran and Hofmann, Josef}
}
kops.citation.iso690JOCHIMS, Johannes, Helmut FISCHER, Atef HAMED, Tran HUU-PHUOC, Josef HOFMANN, 1989. The Reaction of alpha-Chlorocarbenium Salts with Nitriles : Formation of Chloro-Substituted 2-Azoniaallene Salts. In: Synthesis. 1989, 1989(12), S. 918-922. ISSN 0039-7881. eISSN 1437-210X. Verfügbar unter: doi: 10.1055/s-1989-27430deu
kops.citation.iso690JOCHIMS, Johannes, Helmut FISCHER, Atef HAMED, Tran HUU-PHUOC, Josef HOFMANN, 1989. The Reaction of alpha-Chlorocarbenium Salts with Nitriles : Formation of Chloro-Substituted 2-Azoniaallene Salts. In: Synthesis. 1989, 1989(12), pp. 918-922. ISSN 0039-7881. eISSN 1437-210X. Available under: doi: 10.1055/s-1989-27430eng
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    <dcterms:abstract xml:lang="eng">Diaryl or arylchloro substituted α-chlorocarbenium salts react with benzonitriles or dimethylcyanamide to afford chloro substituted 2-azoniaallene salts 10a, b, 11c. An X-ray structural analysis confirms the constitution of one of these salts (11c). Substitution of the chlorine atoms in 1,3-dichloro-1,3-diphenyl-2-azoniaallene hexachloroantimonate (10a) by the nucleophiles water, p-cresol, p-toluidine, diethylamine, hydrazine, methyl-, phenyl-, 2.4,6-trichlorophenylhydrazine, hydroxylamine, N-phenylhydroxylamine, 1,3-dimethylurea, and ethyl allophanate have been carried out affording heterocycles and open-chain compounds 13-21.</dcterms:abstract>
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kops.sourcefieldSynthesis. 1989, <b>1989</b>(12), S. 918-922. ISSN 0039-7881. eISSN 1437-210X. Verfügbar unter: doi: 10.1055/s-1989-27430deu
kops.sourcefield.plainSynthesis. 1989, 1989(12), S. 918-922. ISSN 0039-7881. eISSN 1437-210X. Verfügbar unter: doi: 10.1055/s-1989-27430deu
kops.sourcefield.plainSynthesis. 1989, 1989(12), pp. 918-922. ISSN 0039-7881. eISSN 1437-210X. Available under: doi: 10.1055/s-1989-27430eng
kops.submitter.emailkarin.hoch@uni-konstanz.dedeu
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source.periodicalTitleSynthesis

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