Structure and spectroscopy of phosphorus cluster anions : theory (simulated annealing) and experiment (photoelectron detachment)

Kurzanzeige
dc.contributor.authorJones, Robert O.deu
dc.contributor.authorGanteför, Gerd
dc.contributor.authorHunsicker, Stefandeu
dc.contributor.authorPieperhoff, Peterdeu
dc.date.accessioned2011-03-24T17:54:09Zdeu
dc.date.available2011-03-24T17:54:09Zdeu
dc.date.issued1995deu
dc.description.abstractPhotoelectron detachment measurements have been performed on singly charged phosphorus cluster anions with up to nine atoms, generated by a pulsed arc cluster ion source (PACIS). Transitions between the anion ground states and states of the neutral clusters are observed for all clusters, and vibrational fine structure in both dimer and trimer. A comparison with the results of density functional calculations with simulated annealing an extension to negative ions of earlier work on neutral and positively charged clusters provides a consistent overall picture for all cluster sizes and the first experimental structural information on several.eng
dc.description.versionpublished
dc.format.mimetypeapplication/pdfdeu
dc.identifier.citationFirst publ. in: Journal of Chemical Physics 103 (1995), 22, pp. 9549-9562deu
dc.identifier.doi10.1063/1.469969
dc.identifier.ppn312039425deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/9163
dc.language.isoengdeu
dc.legacy.dateIssued2009deu
dc.rightsterms-of-usedeu
dc.rights.urihttps://rightsstatements.org/page/InC/1.0/deu
dc.subjectAnionsdeu
dc.subjectAtomic clustersdeu
dc.subjectDensity functional methoddeu
dc.subjectElectron detachmentdeu
dc.subjectEnergy-deu
dc.subjectLevel transitionsdeu
dc.subjectPhosphorusdeu
dc.subjectSpectradeu
dc.subjectStructure factorsdeu
dc.subject.ddc530deu
dc.subject.pacs36.40.Mrdeu
dc.subject.pacs36.40.Wadeu
dc.titleStructure and spectroscopy of phosphorus cluster anions : theory (simulated annealing) and experiment (photoelectron detachment)eng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Jones1995Struc-9163,
  year={1995},
  doi={10.1063/1.469969},
  title={Structure and spectroscopy of phosphorus cluster anions : theory (simulated annealing) and experiment (photoelectron detachment)},
  number={22},
  volume={103},
  journal={Journal of Chemical Physics},
  pages={9549--9562},
  author={Jones, Robert O. and Ganteför, Gerd and Hunsicker, Stefan and Pieperhoff, Peter}
}
kops.citation.iso690JONES, Robert O., Gerd GANTEFÖR, Stefan HUNSICKER, Peter PIEPERHOFF, 1995. Structure and spectroscopy of phosphorus cluster anions : theory (simulated annealing) and experiment (photoelectron detachment). In: Journal of Chemical Physics. 1995, 103(22), pp. 9549-9562. Available under: doi: 10.1063/1.469969deu
kops.citation.iso690JONES, Robert O., Gerd GANTEFÖR, Stefan HUNSICKER, Peter PIEPERHOFF, 1995. Structure and spectroscopy of phosphorus cluster anions : theory (simulated annealing) and experiment (photoelectron detachment). In: Journal of Chemical Physics. 1995, 103(22), pp. 9549-9562. Available under: doi: 10.1063/1.469969eng
kops.citation.rdf
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/9163">
    <dc:creator>Jones, Robert O.</dc:creator>
    <dc:creator>Ganteför, Gerd</dc:creator>
    <dc:format>application/pdf</dc:format>
    <dc:creator>Pieperhoff, Peter</dc:creator>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:contributor>Hunsicker, Stefan</dc:contributor>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dc:rights>terms-of-use</dc:rights>
    <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9163"/>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T17:54:09Z</dc:date>
    <dc:contributor>Pieperhoff, Peter</dc:contributor>
    <dcterms:bibliographicCitation>First publ. in: Journal of Chemical Physics 103 (1995), 22, pp. 9549-9562</dcterms:bibliographicCitation>
    <dcterms:issued>1995</dcterms:issued>
    <dc:contributor>Ganteför, Gerd</dc:contributor>
    <dc:contributor>Jones, Robert O.</dc:contributor>
    <dc:language>eng</dc:language>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9163/1/JChemPhys103199522.pdf"/>
    <dcterms:title>Structure and spectroscopy of phosphorus cluster anions : theory (simulated annealing) and experiment (photoelectron detachment)</dcterms:title>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T17:54:09Z</dcterms:available>
    <dc:creator>Hunsicker, Stefan</dc:creator>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9163/1/JChemPhys103199522.pdf"/>
    <dcterms:abstract xml:lang="eng">Photoelectron detachment measurements have been performed on singly charged phosphorus cluster anions with up to nine atoms, generated by a pulsed arc cluster ion source (PACIS). Transitions between the anion ground states and states of the neutral clusters are observed for all clusters, and vibrational fine structure in both dimer and trimer. A comparison with the results of density functional calculations with simulated annealing an extension to negative ions of earlier work on neutral and positively charged clusters provides a consistent overall picture for all cluster sizes and the first experimental structural information on several.</dcterms:abstract>
  </rdf:Description>
</rdf:RDF>
kops.description.openAccessopenaccessgreen
kops.flag.knbibliographyfalse
kops.identifier.nbnurn:nbn:de:bsz:352-opus-87710deu
kops.opus.id8771deu
kops.sourcefieldJournal of Chemical Physics. 1995, <b>103</b>(22), pp. 9549-9562. Available under: doi: 10.1063/1.469969deu
kops.sourcefield.plainJournal of Chemical Physics. 1995, 103(22), pp. 9549-9562. Available under: doi: 10.1063/1.469969deu
kops.sourcefield.plainJournal of Chemical Physics. 1995, 103(22), pp. 9549-9562. Available under: doi: 10.1063/1.469969eng
relation.isAuthorOfPublicationd81f0b28-9ec2-4bdb-b325-21714f128d3c
relation.isAuthorOfPublication.latestForDiscoveryd81f0b28-9ec2-4bdb-b325-21714f128d3c
source.bibliographicInfo.fromPage9549
source.bibliographicInfo.issue22
source.bibliographicInfo.toPage9562
source.bibliographicInfo.volume103
source.periodicalTitleJournal of Chemical Physics

Dateien

Originalbündel

Gerade angezeigt 1 - 1 von 1
Vorschaubild nicht verfügbar
Name:
JChemPhys103199522.pdf
Größe:
337.36 KB
Format:
Adobe Portable Document Format
JChemPhys103199522.pdf
JChemPhys103199522.pdfGröße: 337.36 KBDownloads: 396

Sammlungen

Physik: Publikationen