Structure and spectroscopy of phosphorus cluster anions : theory (simulated annealing) and experiment (photoelectron detachment)

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JChemPhys103199522.pdf(337.36 KB)
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1995
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Jones, Robert O.
Hunsicker, Stefan
Pieperhoff, Peter
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urn:nbn:de:bsz:352-opus-87710
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10.1063/1.469969
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Journal of Chemical Physics ; 103 (1995), 22. - pp. 9549-9562
Abstract
Photoelectron detachment measurements have been performed on singly charged phosphorus cluster anions with up to nine atoms, generated by a pulsed arc cluster ion source (PACIS). Transitions between the anion ground states and states of the neutral clusters are observed for all clusters, and vibrational fine structure in both dimer and trimer. A comparison with the results of density functional calculations with simulated annealing an extension to negative ions of earlier work on neutral and positively charged clusters provides a consistent overall picture for all cluster sizes and the first experimental structural information on several.
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530 Physics
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Anions,Atomic clusters,Density functional method,Electron detachment,Energy-,Level transitions,Phosphorus,Spectra,Structure factors
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Cite This
ISO 690JONES, Robert O., Gerd GANTEFĂ–R, Stefan HUNSICKER, Peter PIEPERHOFF, 1995. Structure and spectroscopy of phosphorus cluster anions : theory (simulated annealing) and experiment (photoelectron detachment). In: Journal of Chemical Physics. 103(22), pp. 9549-9562. Available under: doi: 10.1063/1.469969
BibTex
@article{Jones1995Struc-9163,
  year={1995},
  doi={10.1063/1.469969},
  title={Structure and spectroscopy of phosphorus cluster anions : theory (simulated annealing) and experiment (photoelectron detachment)},
  number={22},
  volume={103},
  journal={Journal of Chemical Physics},
  pages={9549--9562},
  author={Jones, Robert O. and Ganteför, Gerd and Hunsicker, Stefan and Pieperhoff, Peter}
}
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