Charge transfer in copper oxide thin films deposited at different electrodeposition potential
| dc.contributor.author | Ali, Nazakat | |
| dc.contributor.author | Hussain, Sajad | |
| dc.contributor.author | Waqas, Muhammad | |
| dc.contributor.author | Faheem, M. | |
| dc.contributor.author | Ahmad, Naveed | |
| dc.contributor.author | Ali, Adnan | |
| dc.contributor.author | Ali, Muhammad Yasir | |
| dc.contributor.author | Mahmood, Khalid | |
| dc.contributor.author | Schmidt-Mende, Lukas | |
| dc.date.accessioned | 2023-05-05T12:52:08Z | |
| dc.date.available | 2023-05-05T12:52:08Z | |
| dc.date.issued | 2023 | |
| dc.description.abstract | The deposition potential affects the structural, morphological, optical, and electrochemical impedance spectroscopy properties of cuprous oxide (Cu2O) thin films formed on copper (Cu) substrates adopting a three-electrode electrochemical deposition procedure. XRD data revealed that the deposited films have a cubic structure established with desired (111) growth orientation. Scanning electron microscopy (SEM) images reveal that Cu2O film has very well three-sided pyramid-shaped grains which are equally spread over the surface of the Cu substrates and change substantially when the plating potential is changed. The photo-current density of prepared Cu2O thin films was increased from −1.41 × 10−4 to −3.01 × 10−4 A/cm2 with increasing the deposition potential of −0.3 to −0.6 V, respectively. Further, Cu2O thin films obtained at −0.6 V have the minimum charge transfer resistance (Rct) than Cu2O thin films synthesized at −0.3 to −0.5 V, suggesting that Cu2O thin films produced at −0.6 V have the highest electron transfer efficiency. | |
| dc.description.version | published | deu |
| dc.identifier.doi | 10.1016/j.physb.2023.414881 | |
| dc.identifier.uri | https://kops.uni-konstanz.de/handle/123456789/66800 | |
| dc.language.iso | eng | |
| dc.subject.ddc | 530 | |
| dc.title | Charge transfer in copper oxide thin films deposited at different electrodeposition potential | eng |
| dc.type | JOURNAL_ARTICLE | |
| dspace.entity.type | Publication | |
| kops.citation.bibtex | @article{Ali2023Charg-66800,
year={2023},
doi={10.1016/j.physb.2023.414881},
title={Charge transfer in copper oxide thin films deposited at different electrodeposition potential},
volume={659},
issn={0921-4526},
journal={Physica B: Condensed Matter},
author={Ali, Nazakat and Hussain, Sajad and Waqas, Muhammad and Faheem, M. and Ahmad, Naveed and Ali, Adnan and Ali, Muhammad Yasir and Mahmood, Khalid and Schmidt-Mende, Lukas},
note={Article Number: 414881}
} | |
| kops.citation.iso690 | ALI, Nazakat, Sajad HUSSAIN, Muhammad WAQAS, M. FAHEEM, Naveed AHMAD, Adnan ALI, Muhammad Yasir ALI, Khalid MAHMOOD, Lukas SCHMIDT-MENDE, 2023. Charge transfer in copper oxide thin films deposited at different electrodeposition potential. In: Physica B: Condensed Matter. Elsevier. 2023, 659, 414881. ISSN 0921-4526. eISSN 1873-2135. Available under: doi: 10.1016/j.physb.2023.414881 | deu |
| kops.citation.iso690 | ALI, Nazakat, Sajad HUSSAIN, Muhammad WAQAS, M. FAHEEM, Naveed AHMAD, Adnan ALI, Muhammad Yasir ALI, Khalid MAHMOOD, Lukas SCHMIDT-MENDE, 2023. Charge transfer in copper oxide thin films deposited at different electrodeposition potential. In: Physica B: Condensed Matter. Elsevier. 2023, 659, 414881. ISSN 0921-4526. eISSN 1873-2135. Available under: doi: 10.1016/j.physb.2023.414881 | eng |
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<dcterms:abstract>The deposition potential affects the structural, morphological, optical, and electrochemical impedance spectroscopy properties of cuprous oxide (Cu<sub>2</sub>O) thin films formed on copper (Cu) substrates adopting a three-electrode electrochemical deposition procedure. XRD data revealed that the deposited films have a cubic structure established with desired (111) growth orientation. Scanning electron microscopy (SEM) images reveal that Cu<sub>2</sub>O film has very well three-sided pyramid-shaped grains which are equally spread over the surface of the Cu substrates and change substantially when the plating potential is changed. The photo-current density of prepared Cu<sub>2</sub>O thin films was increased from −1.41 × 10<sup>−4</sup> to −3.01 × 10<sup>−4</sup> A/cm<sup>2</sup> with increasing the deposition potential of −0.3 to −0.6 V, respectively. Further, Cu<sub>2</sub>O thin films obtained at −0.6 V have the minimum charge transfer resistance (R<sub>ct</sub>) than Cu<sub>2</sub>O thin films synthesized at −0.3 to −0.5 V, suggesting that Cu<sub>2</sub>O thin films produced at −0.6 V have the highest electron transfer efficiency.</dcterms:abstract>
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