Heterobinuclear Zn-Ln and Ni-Ln Complexes with Schiff-Base and Carbacylamidophosphate Ligands : Synthesis, Crystal Structures, and Catalytic Activity

Amirkhanov, Oleksiy V.; Moroz, Olesia V.; Znovjyak, Kateryna O.; Silva, Tetiana Yu.; Penkova, Larysa V.; Yushchenko, Tetyana; Szyrwiel, Lukasz; Konovalova, Irina S.; Dyakonenko, Viktoriya; Shishkin, Oleg V.; Amirkhanov, Vadimir M.

Heterobinuclear Zn-Ln and Ni-Ln Complexes with Schiff-Base and Carbacylamidophosphate Ligands : Synthesis, Crystal Structures, and Catalytic Activity

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Datum

2014

Autor:innen

Amirkhanov, Oleksiy V.

Moroz, Olesia V.

Znovjyak, Kateryna O.

Silva, Tetiana Yu.

Penkova, Larysa V.

Yushchenko, Tetyana

Szyrwiel, Lukasz

Konovalova, Irina S.

Dyakonenko, Viktoriya

Shishkin, Oleg V.

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DOI (zitierfähiger Link)

https://doi.org/10.1002/ejic.201402224

Sammlungen

Chemie

Publikationstyp

Zeitschriftenartikel

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European Journal of Inorganic Chemistry. 2014, 2014(23), pp. 3720-3730. ISSN 0009-2940. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201402224

Zusammenfassung

The reaction of Salen-like Zn^IIand Ni^II precursors with carbacylamidophosphate lanthanide moieties yields six new types of 3d–4f compounds. The complexes were characterized by means of ¹H, ³¹P NMR and IR spectroscopy, elemental analysis, ESI mass spectrometry, and X-ray diffraction analysis. Depending on the Schiff base ligands, the Ni^II ion adopts either a square-planar or an octahedral geometry, whereas the Zn^II ion has a tetragonal-pyramidal geometry. The coordination number of lanthanides is nine or ten. Hydrolytic activities of some heterobimetallic Zn–Ln and Ni–Ln coordination compounds in the reaction of intramolecular hydrolytic degradation of the 2-(hydroxypropyl)-p-nitrophenyl phosphate were investigated.

Fachgebiet (DDC)

540 Chemie

Schlagwörter

Heterometallic complexes, Kinetics, Lanthanide, N,O-ligands, Structure elucidation

Zitieren

ISO 690

AMIRKHANOV, Oleksiy V., Olesia V. MOROZ, Kateryna O. ZNOVJYAK, Tetiana Yu. SILVA, Larysa V. PENKOVA, Tetyana YUSHCHENKO, Lukasz SZYRWIEL, Irina S. KONOVALOVA, Viktoriya DYAKONENKO, Oleg V. SHISHKIN, Vadimir M. AMIRKHANOV, 2014. Heterobinuclear Zn-Ln and Ni-Ln Complexes with Schiff-Base and Carbacylamidophosphate Ligands : Synthesis, Crystal Structures, and Catalytic Activity. In: European Journal of Inorganic Chemistry. 2014, 2014(23), pp. 3720-3730. ISSN 0009-2940. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201402224

BibTex

@article{Amirkhanov2014Heter-29582,
  year={2014},
  doi={10.1002/ejic.201402224},
  title={Heterobinuclear Zn-Ln and Ni-Ln Complexes with Schiff-Base and Carbacylamidophosphate Ligands : Synthesis, Crystal Structures, and Catalytic Activity},
  number={23},
  volume={2014},
  issn={0009-2940},
  journal={European Journal of Inorganic Chemistry},
  pages={3720--3730},
  author={Amirkhanov, Oleksiy V. and Moroz, Olesia V. and Znovjyak, Kateryna O. and Silva, Tetiana Yu. and Penkova, Larysa V. and Yushchenko, Tetyana and Szyrwiel, Lukasz and Konovalova, Irina S. and Dyakonenko, Viktoriya and Shishkin, Oleg V. and Amirkhanov, Vadimir M.}
}

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