The spin-correlated radical pair as a reaction intermediate

Kurzanzeige
dc.contributor.authorMcLauchlan, Keith A.deu
dc.contributor.authorSteiner, Ulrich
dc.date.accessioned2011-03-24T18:15:28Zdeu
dc.date.available2011-03-24T18:15:28Zdeu
dc.date.issued1991deu
dc.description.abstractThe concept of the spin-correlated radical pair has been used for some time in the interpretation of the results of magnetic polarization experiments in NMR and in ESR (CIDNP and CIDEP), and of the effects of magnetic fields on chemical reactions. It has, however, a much wider general significance as a reaction intermediate in all radical reactions, including photochemistry. Here the nature of the pair is introduced, and the evidence for it reviewed, and it is further shown how it can be treated theoretically, before some of the consequences of its existence are pointed out. Its recognition, and in particular the understanding of the processes which occur within it, notably the interplay of spin-mixing and diffusion, allow the design of new experiments in the absence or presence of an external magnetic field, and the optimization of reaction yields.eng
dc.description.versionpublished
dc.format.mimetypeapplication/pdfdeu
dc.identifier.citationFirst publ. in: Molecular Physics 73 (1991), 2, pp. 241 - 263deu
dc.identifier.doi10.1080/00268979100101181
dc.identifier.ppn276899326deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/9941
dc.language.isoengdeu
dc.legacy.dateIssued2008deu
dc.rightsAttribution-NonCommercial-NoDerivs 2.0 Generic
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.0/
dc.subject.ddc540deu
dc.titleThe spin-correlated radical pair as a reaction intermediateeng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{McLauchlan1991spinc-9941,
  year={1991},
  doi={10.1080/00268979100101181},
  title={The spin-correlated radical pair as a reaction intermediate},
  number={2},
  volume={73},
  issn={0026-8976},
  journal={Molecular Physics},
  pages={241--263},
  author={McLauchlan, Keith A. and Steiner, Ulrich}
}
kops.citation.iso690MCLAUCHLAN, Keith A., Ulrich STEINER, 1991. The spin-correlated radical pair as a reaction intermediate. In: Molecular Physics. 1991, 73(2), pp. 241-263. ISSN 0026-8976. eISSN 1362-3028. Available under: doi: 10.1080/00268979100101181deu
kops.citation.iso690MCLAUCHLAN, Keith A., Ulrich STEINER, 1991. The spin-correlated radical pair as a reaction intermediate. In: Molecular Physics. 1991, 73(2), pp. 241-263. ISSN 0026-8976. eISSN 1362-3028. Available under: doi: 10.1080/00268979100101181eng
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kops.sourcefieldMolecular Physics. 1991, <b>73</b>(2), pp. 241-263. ISSN 0026-8976. eISSN 1362-3028. Available under: doi: 10.1080/00268979100101181deu
kops.sourcefield.plainMolecular Physics. 1991, 73(2), pp. 241-263. ISSN 0026-8976. eISSN 1362-3028. Available under: doi: 10.1080/00268979100101181deu
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