The spin-correlated radical pair as a reaction intermediate

McLauchlan, Keith A.; Steiner, Ulrich

The spin-correlated radical pair as a reaction intermediate

Dateien

The_spin_correlated_radical_pair_as_a_reaction_intermediate.pdfGröße: 1.55 MBDownloads: 851

Datum

1991

Autor:innen

McLauchlan, Keith A.

Steiner, Ulrich

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Chemie

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Molecular Physics. 1991, 73(2), pp. 241-263. ISSN 0026-8976. eISSN 1362-3028. Available under: doi: 10.1080/00268979100101181

Zusammenfassung

The concept of the spin-correlated radical pair has been used for some time in the interpretation of the results of magnetic polarization experiments in NMR and in ESR (CIDNP and CIDEP), and of the effects of magnetic fields on chemical reactions. It has, however, a much wider general significance as a reaction intermediate in all radical reactions, including photochemistry. Here the nature of the pair is introduced, and the evidence for it reviewed, and it is further shown how it can be treated theoretically, before some of the consequences of its existence are pointed out. Its recognition, and in particular the understanding of the processes which occur within it, notably the interplay of spin-mixing and diffusion, allow the design of new experiments in the absence or presence of an external magnetic field, and the optimization of reaction yields.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

MCLAUCHLAN, Keith A., Ulrich STEINER, 1991. The spin-correlated radical pair as a reaction intermediate. In: Molecular Physics. 1991, 73(2), pp. 241-263. ISSN 0026-8976. eISSN 1362-3028. Available under: doi: 10.1080/00268979100101181

BibTex

@article{McLauchlan1991spinc-9941,
  year={1991},
  doi={10.1080/00268979100101181},
  title={The spin-correlated radical pair as a reaction intermediate},
  number={2},
  volume={73},
  issn={0026-8976},
  journal={Molecular Physics},
  pages={241--263},
  author={McLauchlan, Keith A. and Steiner, Ulrich}
}

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