Publikation:

The spin-correlated radical pair as a reaction intermediate

Lade...
Vorschaubild

Datum

1991

Autor:innen

McLauchlan, Keith A.

Herausgeber:innen

Kontakt

ISSN der Zeitschrift

Electronic ISSN

ISBN

Bibliografische Daten

Verlag

Schriftenreihe

Auflagebezeichnung

ArXiv-ID

Internationale Patentnummer

Angaben zur Forschungsförderung

Projekt

Open Access-Veröffentlichung
Open Access Green
Core Facility der Universität Konstanz

Gesperrt bis

Titel in einer weiteren Sprache

Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published

Erschienen in

Molecular Physics. 1991, 73(2), pp. 241-263. ISSN 0026-8976. eISSN 1362-3028. Available under: doi: 10.1080/00268979100101181

Zusammenfassung

The concept of the spin-correlated radical pair has been used for some time in the interpretation of the results of magnetic polarization experiments in NMR and in ESR (CIDNP and CIDEP), and of the effects of magnetic fields on chemical reactions. It has, however, a much wider general significance as a reaction intermediate in all radical reactions, including photochemistry. Here the nature of the pair is introduced, and the evidence for it reviewed, and it is further shown how it can be treated theoretically, before some of the consequences of its existence are pointed out. Its recognition, and in particular the understanding of the processes which occur within it, notably the interplay of spin-mixing and diffusion, allow the design of new experiments in the absence or presence of an external magnetic field, and the optimization of reaction yields.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

Konferenz

Rezension
undefined / . - undefined, undefined

Forschungsvorhaben

Organisationseinheiten

Zeitschriftenheft

Zugehörige Datensätze in KOPS

Zitieren

ISO 690MCLAUCHLAN, Keith A., Ulrich STEINER, 1991. The spin-correlated radical pair as a reaction intermediate. In: Molecular Physics. 1991, 73(2), pp. 241-263. ISSN 0026-8976. eISSN 1362-3028. Available under: doi: 10.1080/00268979100101181
BibTex
@article{McLauchlan1991spinc-9941,
  year={1991},
  doi={10.1080/00268979100101181},
  title={The spin-correlated radical pair as a reaction intermediate},
  number={2},
  volume={73},
  issn={0026-8976},
  journal={Molecular Physics},
  pages={241--263},
  author={McLauchlan, Keith A. and Steiner, Ulrich}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/9941">
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dc:creator>McLauchlan, Keith A.</dc:creator>
    <dcterms:rights rdf:resource="http://creativecommons.org/licenses/by-nc-nd/2.0/"/>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9941/1/The_spin_correlated_radical_pair_as_a_reaction_intermediate.pdf"/>
    <dc:format>application/pdf</dc:format>
    <dcterms:title>The spin-correlated radical pair as a reaction intermediate</dcterms:title>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:contributor>Steiner, Ulrich</dc:contributor>
    <dcterms:bibliographicCitation>First publ. in: Molecular Physics 73 (1991), 2, pp. 241 - 263</dcterms:bibliographicCitation>
    <dc:rights>Attribution-NonCommercial-NoDerivs 2.0 Generic</dc:rights>
    <dcterms:abstract xml:lang="eng">The concept of the spin-correlated radical pair has been used for some time in the interpretation of the results of magnetic polarization experiments in NMR and in ESR (CIDNP and CIDEP), and of the effects of magnetic fields on chemical reactions. It has, however, a much wider general significance as a reaction intermediate in all radical reactions, including photochemistry. Here the nature of the pair is introduced, and the evidence for it reviewed, and it is further shown how it can be treated theoretically, before some of the consequences of its existence are pointed out. Its recognition, and in particular the understanding of the processes which occur within it, notably the interplay of spin-mixing and diffusion, allow the design of new experiments in the absence or presence of an external magnetic field, and the optimization of reaction yields.</dcterms:abstract>
    <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9941"/>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dc:language>eng</dc:language>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:15:28Z</dc:date>
    <dcterms:issued>1991</dcterms:issued>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:15:28Z</dcterms:available>
    <dc:contributor>McLauchlan, Keith A.</dc:contributor>
    <dc:creator>Steiner, Ulrich</dc:creator>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9941/1/The_spin_correlated_radical_pair_as_a_reaction_intermediate.pdf"/>
  </rdf:Description>
</rdf:RDF>

Interner Vermerk

xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter

Kontakt
URL der Originalveröffentl.

Prüfdatum der URL

Prüfungsdatum der Dissertation

Finanzierungsart

Kommentar zur Publikation

Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Nein
Begutachtet
Diese Publikation teilen