@article{Koo2019-03-27Unidi-45546,
  year={2019},
  doi={10.1021/acsami.8b19372},
  title={Unidirectional Real-Time Photoswitching of Diarylethene Molecular Monolayer Junctions with Multilayer Graphene Electrodes},
  number={12},
  volume={11},
  issn={1944-8244},
  journal={ACS applied materials & interfaces},
  pages={11645--11653},
  author={Koo, Jeongmin and Jang, Yeonsik and Martin, León and Kim, Dongku and Jeong, Hyunhak and Scheer, Elke and Kabdulov, Mikhail and Huhn, Thomas and Pauly, Fabian and Lee, Takhee}
}

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    <dcterms:title>Unidirectional Real-Time Photoswitching of Diarylethene Molecular Monolayer Junctions with Multilayer Graphene Electrodes</dcterms:title>
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    <dcterms:abstract xml:lang="eng">We fabricate and characterize vertical molecular junctions consisting of self-assembled monolayers (SAMs) of diarylethene (DAE) contacted by a multilayer graphene (MLG) electrode on the top and gold on the bottom. The DAE molecular junctions show two stable electrical states, a closed state (high conductance) or an open state (low conductance), which are created upon illumination with UV or visible light, respectively. For the Au-DAE-MLG junction structure, we observe that the current levels between the two conductance states are separated by two orders of magnitude. However, in a real-time measurement, we observe only unidirectional switching behavior from the open to the closed state.</dcterms:abstract>
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