Cobalt mediated intramolecular [2+2+2]-cycloaddition of enediynes ­towards linear annelated polycycles

Kurzanzeige
dc.contributor.authorEckenberg, Peterdeu
dc.contributor.authorGroth, Ulrich
dc.date.accessioned2011-03-24T18:13:19Zdeu
dc.date.available2011-03-24T18:13:19Zdeu
dc.date.issued2003deu
dc.description.abstractThe cobalt mediated [2+2+2]-cycloaddition of enediynes 13 and 18 affords linear annelated polycycles such as the hexahydro naphthalene 14 and the decahydro anthracene 19. This latter compound can be transformed into the enantiomerically pure anthracene derivative 21 in only two reaction steps. 1,9,10-Trihydroxy octahydro anthracene (21) represents the ABC-framework of many anthracycline antibiotics such as the antitumor active daunomycine.eng
dc.description.versionpublished
dc.format.mimetypeapplication/pdfdeu
dc.identifier.citationFirst publ. in: Synlett 2003, 14, pp. 2188-2192deu
dc.identifier.doi10.1002/anie.198405393
dc.identifier.ppn276473000deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/9632
dc.language.isoengdeu
dc.legacy.dateIssued2008deu
dc.rightsAttribution-NonCommercial-NoDerivs 2.0 Generic
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.0/
dc.subject[2+2+2]-cycloadditiondeu
dc.subjectenediynesdeu
dc.subjectannelated poly­cyclesdeu
dc.subject.ddc540deu
dc.titleCobalt mediated intramolecular [2+2+2]-cycloaddition of enediynes ­towards linear annelated polycycleseng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
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@article{Eckenberg2003Cobal-9632,
  year={2003},
  doi={10.1002/anie.198405393},
  title={Cobalt mediated intramolecular [2+2+2]-cycloaddition of enediynes ­towards linear annelated polycycles},
  number={14},
  volume={23},
  issn={0570-0833},
  journal={Synlett},
  pages={2188--2192},
  author={Eckenberg, Peter and Groth, Ulrich}
}
kops.citation.iso690ECKENBERG, Peter, Ulrich GROTH, 2003. Cobalt mediated intramolecular [2+2+2]-cycloaddition of enediynes ­towards linear annelated polycycles. In: Synlett. 2003, 23(14), pp. 2188-2192. ISSN 0570-0833. eISSN 1521-3773. Available under: doi: 10.1002/anie.198405393deu
kops.citation.iso690ECKENBERG, Peter, Ulrich GROTH, 2003. Cobalt mediated intramolecular [2+2+2]-cycloaddition of enediynes ­towards linear annelated polycycles. In: Synlett. 2003, 23(14), pp. 2188-2192. ISSN 0570-0833. eISSN 1521-3773. Available under: doi: 10.1002/anie.198405393eng
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