Immobilization of a catalytically active rhodium complex by electrostatic interactions of multiply charged phosphine ligands with a soluble polyelectrolyte and recovery by ultrafiltration

Kurzanzeige
dc.contributor.authorSchwab, Ernstdeu
dc.contributor.authorMecking, Stefan
dc.date.accessioned2011-03-24T18:14:34Zdeu
dc.date.issued2001deu
dc.description.abstractBinding via noncovalent electrostatic interactions of multiply sulfonated phosphine ligands with a soluble polyelectrolyte represents a convenient approach for immobilization of a catalytically active rhodium complex. As a polyelectrolyte, PDADMA-BArF 4 (poly-(diallyldimethylammonium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate)) can be utilized. The polyelectrolyte-bound catalyst is active for hexene hydroformylation, and it can be recovered and recycled by ultrafiltration.eng
dc.description.versionpublished
dc.format.mimetypeapplication/pdfdeu
dc.identifier.citationFirst publ. in: Organometallics ; 20 (2001), 26. - S. 5504-5506deu
dc.identifier.doi10.1021/om0107542
dc.identifier.ppn285019708deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/9810
dc.language.isoengdeu
dc.legacy.dateIssued2008deu
dc.rightsAttribution-NonCommercial-NoDerivs 2.0 Generic
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.0/
dc.subject.ddc540deu
dc.titleImmobilization of a catalytically active rhodium complex by electrostatic interactions of multiply charged phosphine ligands with a soluble polyelectrolyte and recovery by ultrafiltrationeng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Schwab2001Immob-9810,
  year={2001},
  doi={10.1021/om0107542},
  title={Immobilization of a catalytically active rhodium complex by electrostatic interactions of multiply charged phosphine ligands with a soluble polyelectrolyte and recovery by ultrafiltration},
  number={26},
  volume={20},
  issn={0276-7333},
  journal={Organometallics},
  pages={5504--5506},
  author={Schwab, Ernst and Mecking, Stefan}
}
kops.citation.iso690SCHWAB, Ernst, Stefan MECKING, 2001. Immobilization of a catalytically active rhodium complex by electrostatic interactions of multiply charged phosphine ligands with a soluble polyelectrolyte and recovery by ultrafiltration. In: Organometallics. 2001, 20(26), pp. 5504-5506. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om0107542deu
kops.citation.iso690SCHWAB, Ernst, Stefan MECKING, 2001. Immobilization of a catalytically active rhodium complex by electrostatic interactions of multiply charged phosphine ligands with a soluble polyelectrolyte and recovery by ultrafiltration. In: Organometallics. 2001, 20(26), pp. 5504-5506. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om0107542eng
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