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Immobilization of a catalytically active rhodium complex by electrostatic interactions of multiply charged phosphine ligands with a soluble polyelectrolyte and recovery by ultrafiltration

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2001_Organometallics_20_5504_Mecking_Schwab.pdf
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2001

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Schwab, Ernst

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http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-62254
DOI (zitierfähiger Link)
https://doi.org/10.1021/om0107542
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Attribution-NonCommercial-NoDerivs 2.0 Generic

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Chemie: Publikationen
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Published

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Organometallics. 2001, 20(26), pp. 5504-5506. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om0107542

Zusammenfassung

Binding via noncovalent electrostatic interactions of multiply sulfonated phosphine ligands with a soluble polyelectrolyte represents a convenient approach for immobilization of a catalytically active rhodium complex. As a polyelectrolyte, PDADMA-BArF 4 (poly-(diallyldimethylammonium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate)) can be utilized. The polyelectrolyte-bound catalyst is active for hexene hydroformylation, and it can be recovered and recycled by ultrafiltration.

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540 Chemie

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ISO 690SCHWAB, Ernst, Stefan MECKING, 2001. Immobilization of a catalytically active rhodium complex by electrostatic interactions of multiply charged phosphine ligands with a soluble polyelectrolyte and recovery by ultrafiltration. In: Organometallics. 2001, 20(26), pp. 5504-5506. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om0107542
BibTex
@article{Schwab2001Immob-9810,
  year={2001},
  doi={10.1021/om0107542},
  title={Immobilization of a catalytically active rhodium complex by electrostatic interactions of multiply charged phosphine ligands with a soluble polyelectrolyte and recovery by ultrafiltration},
  number={26},
  volume={20},
  issn={0276-7333},
  journal={Organometallics},
  pages={5504--5506},
  author={Schwab, Ernst and Mecking, Stefan}
}
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