Immobilization of a catalytically active rhodium complex by electrostatic interactions of multiply charged phosphine ligands with a soluble polyelectrolyte and recovery by ultrafiltration

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2001
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Schwab, Ernst
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Binding via noncovalent electrostatic interactions of multiply sulfonated phosphine ligands with a soluble polyelectrolyte represents a convenient approach for immobilization of a catalytically active rhodium complex. As a polyelectrolyte, PDADMA-BArF 4 (poly-(diallyldimethylammonium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate)) can be utilized. The polyelectrolyte-bound catalyst is active for hexene hydroformylation, and it can be recovered and recycled by ultrafiltration.

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ISO 690SCHWAB, Ernst, Stefan MECKING, 2001. Immobilization of a catalytically active rhodium complex by electrostatic interactions of multiply charged phosphine ligands with a soluble polyelectrolyte and recovery by ultrafiltration. In: Organometallics. 2001, 20(26), pp. 5504-5506. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om0107542
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@article{Schwab2001Immob-9810,
  year={2001},
  doi={10.1021/om0107542},
  title={Immobilization of a catalytically active rhodium complex by electrostatic interactions of multiply charged phosphine ligands with a soluble polyelectrolyte and recovery by ultrafiltration},
  number={26},
  volume={20},
  issn={0276-7333},
  journal={Organometallics},
  pages={5504--5506},
  author={Schwab, Ernst and Mecking, Stefan}
}
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    <dcterms:abstract xml:lang="eng">Binding via noncovalent electrostatic interactions of multiply sulfonated phosphine ligands with a soluble polyelectrolyte represents a convenient approach for immobilization of a catalytically active rhodium complex. As a polyelectrolyte, PDADMA-BArF 4 (poly-(diallyldimethylammonium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate)) can be utilized. The polyelectrolyte-bound catalyst is active for hexene hydroformylation, and it can be recovered and recycled by ultrafiltration.</dcterms:abstract>
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