Nanoreactor-assisted polymerization toward stable dispersions of conductive composite particles
| dc.contributor.author | Korovin, Alexey N. | deu |
| dc.contributor.author | Sergeyev, Vladimir G. | deu |
| dc.contributor.author | Pyshkina, Olga A. | deu |
| dc.contributor.author | Hanske, Christoph | deu |
| dc.contributor.author | Fery, Andreas | deu |
| dc.contributor.author | Wittemann, Alexander | |
| dc.contributor.author | Tsarkova, Larisa | deu |
| dc.date.accessioned | 2012-07-12T09:45:26Z | deu |
| dc.date.available | 2012-07-12T09:45:26Z | deu |
| dc.date.issued | 2011-03-02 | |
| dc.description.abstract | We demonstrate the functioning of a macromolecular nanoreactor which guides a reaction in a confined volume and leads toward improved functional properties of a product material. In our approach, the polymerization of aniline (ANi) is conducted within the interfacial volume of spherical polyelectrolyte brushes (SPB) which are densely affixed to colloidal particles. The SPB provide optimal conditions for matrix polymerization by the efficient confinement of ANi monomers within the finite volume of polyelectrolyte brushes and controlled delivery of the oxidizing reagent to the reaction volume. The excellent kinetic stability of the resulting core–shell particles together with the high macroscopic conductivity of the respective composite open up perspectives for novel materials (a conductive ink). | eng |
| dc.description.version | published | |
| dc.identifier.citation | Publ. in: Macromolecular rapid communications ; 32 (2011), 5. - S. 462-467 | deu |
| dc.identifier.doi | 10.1002/marc.201000626 | deu |
| dc.identifier.pmid | 21433200 | |
| dc.identifier.uri | http://kops.uni-konstanz.de/handle/123456789/19737 | |
| dc.language.iso | eng | deu |
| dc.legacy.dateIssued | 2012-07-12 | deu |
| dc.rights | terms-of-use | deu |
| dc.rights.uri | https://rightsstatements.org/page/InC/1.0/ | deu |
| dc.subject | conducting polymers | deu |
| dc.subject | core–shell particles | deu |
| dc.subject | nanocomposites | deu |
| dc.subject | nanoreactor | deu |
| dc.subject | polyaniline | deu |
| dc.subject.ddc | 540 | deu |
| dc.title | Nanoreactor-assisted polymerization toward stable dispersions of conductive composite particles | eng |
| dc.type | JOURNAL_ARTICLE | deu |
| dspace.entity.type | Publication | |
| kops.citation.bibtex | @article{Korovin2011-03-02Nanor-19737,
year={2011},
doi={10.1002/marc.201000626},
title={Nanoreactor-assisted polymerization toward stable dispersions of conductive composite particles},
number={5},
volume={32},
issn={1022-1336},
journal={Macromolecular Rapid Communications},
pages={462--467},
author={Korovin, Alexey N. and Sergeyev, Vladimir G. and Pyshkina, Olga A. and Hanske, Christoph and Fery, Andreas and Wittemann, Alexander and Tsarkova, Larisa}
} | |
| kops.citation.iso690 | KOROVIN, Alexey N., Vladimir G. SERGEYEV, Olga A. PYSHKINA, Christoph HANSKE, Andreas FERY, Alexander WITTEMANN, Larisa TSARKOVA, 2011. Nanoreactor-assisted polymerization toward stable dispersions of conductive composite particles. In: Macromolecular Rapid Communications. 2011, 32(5), pp. 462-467. ISSN 1022-1336. eISSN 1521-3927. Available under: doi: 10.1002/marc.201000626 | deu |
| kops.citation.iso690 | KOROVIN, Alexey N., Vladimir G. SERGEYEV, Olga A. PYSHKINA, Christoph HANSKE, Andreas FERY, Alexander WITTEMANN, Larisa TSARKOVA, 2011. Nanoreactor-assisted polymerization toward stable dispersions of conductive composite particles. In: Macromolecular Rapid Communications. 2011, 32(5), pp. 462-467. ISSN 1022-1336. eISSN 1521-3927. Available under: doi: 10.1002/marc.201000626 | eng |
| kops.citation.rdf | <rdf:RDF
xmlns:dcterms="http://purl.org/dc/terms/"
xmlns:dc="http://purl.org/dc/elements/1.1/"
xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
xmlns:bibo="http://purl.org/ontology/bibo/"
xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
xmlns:foaf="http://xmlns.com/foaf/0.1/"
xmlns:void="http://rdfs.org/ns/void#"
xmlns:xsd="http://www.w3.org/2001/XMLSchema#" >
<rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/19737">
<dc:rights>terms-of-use</dc:rights>
<dc:creator>Tsarkova, Larisa</dc:creator>
<dc:language>eng</dc:language>
<dc:contributor>Tsarkova, Larisa</dc:contributor>
<void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
<dc:contributor>Wittemann, Alexander</dc:contributor>
<dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
<dc:contributor>Fery, Andreas</dc:contributor>
<foaf:homepage rdf:resource="http://localhost:8080/"/>
<dc:creator>Sergeyev, Vladimir G.</dc:creator>
<dc:contributor>Pyshkina, Olga A.</dc:contributor>
<dc:contributor>Sergeyev, Vladimir G.</dc:contributor>
<dc:creator>Pyshkina, Olga A.</dc:creator>
<dc:creator>Fery, Andreas</dc:creator>
<dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
<dcterms:issued>2011-03-02</dcterms:issued>
<dc:creator>Wittemann, Alexander</dc:creator>
<dc:creator>Korovin, Alexey N.</dc:creator>
<dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
<dc:contributor>Korovin, Alexey N.</dc:contributor>
<bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/19737"/>
<dcterms:abstract xml:lang="eng">We demonstrate the functioning of a macromolecular nanoreactor which guides a reaction in a confined volume and leads toward improved functional properties of a product material. In our approach, the polymerization of aniline (ANi) is conducted within the interfacial volume of spherical polyelectrolyte brushes (SPB) which are densely affixed to colloidal particles. The SPB provide optimal conditions for matrix polymerization by the efficient confinement of ANi monomers within the finite volume of polyelectrolyte brushes and controlled delivery of the oxidizing reagent to the reaction volume. The excellent kinetic stability of the resulting core–shell particles together with the high macroscopic conductivity of the respective composite open up perspectives for novel materials (a conductive ink).</dcterms:abstract>
<dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2012-07-12T09:45:26Z</dc:date>
<dcterms:bibliographicCitation>Publ. in: Macromolecular rapid communications ; 32 (2011), 5. - S. 462-467</dcterms:bibliographicCitation>
<dcterms:title>Nanoreactor-assisted polymerization toward stable dispersions of conductive composite particles</dcterms:title>
<dc:creator>Hanske, Christoph</dc:creator>
<dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2012-07-12T09:45:26Z</dcterms:available>
<dc:contributor>Hanske, Christoph</dc:contributor>
</rdf:Description>
</rdf:RDF> | |
| kops.flag.knbibliography | true | |
| kops.identifier.nbn | urn:nbn:de:bsz:352-197375 | deu |
| kops.sourcefield | Macromolecular Rapid Communications. 2011, <b>32</b>(5), pp. 462-467. ISSN 1022-1336. eISSN 1521-3927. Available under: doi: 10.1002/marc.201000626 | deu |
| kops.sourcefield.plain | Macromolecular Rapid Communications. 2011, 32(5), pp. 462-467. ISSN 1022-1336. eISSN 1521-3927. Available under: doi: 10.1002/marc.201000626 | deu |
| kops.sourcefield.plain | Macromolecular Rapid Communications. 2011, 32(5), pp. 462-467. ISSN 1022-1336. eISSN 1521-3927. Available under: doi: 10.1002/marc.201000626 | eng |
| kops.submitter.email | larysa.herasymova@uni-konstanz.de | deu |
| relation.isAuthorOfPublication | bc30fa0d-f4df-4f85-8c38-ab6430c71a68 | |
| relation.isAuthorOfPublication.latestForDiscovery | bc30fa0d-f4df-4f85-8c38-ab6430c71a68 | |
| source.bibliographicInfo.fromPage | 462 | |
| source.bibliographicInfo.issue | 5 | |
| source.bibliographicInfo.toPage | 467 | |
| source.bibliographicInfo.volume | 32 | |
| source.identifier.eissn | 1521-3927 | |
| source.identifier.issn | 1022-1336 | |
| source.periodicalTitle | Macromolecular Rapid Communications |
Dateien
Lizenzbündel
1 - 1 von 1
Vorschaubild nicht verfügbar
- Name:
- license.txt
- Größe:
- 1.92 KB
- Format:
- Plain Text
- Beschreibung:
