Nanoreactor-assisted polymerization toward stable dispersions of conductive composite particles

dc.contributor.authorKorovin, Alexey N.deu
dc.contributor.authorSergeyev, Vladimir G.deu
dc.contributor.authorPyshkina, Olga A.deu
dc.contributor.authorHanske, Christophdeu
dc.contributor.authorFery, Andreasdeu
dc.contributor.authorWittemann, Alexander
dc.contributor.authorTsarkova, Larisadeu
dc.date.accessioned2012-07-12T09:45:26Zdeu
dc.date.available2012-07-12T09:45:26Zdeu
dc.date.issued2011-03-02
dc.description.abstractWe demonstrate the functioning of a macromolecular nanoreactor which guides a reaction in a confined volume and leads toward improved functional properties of a product material. In our approach, the polymerization of aniline (ANi) is conducted within the interfacial volume of spherical polyelectrolyte brushes (SPB) which are densely affixed to colloidal particles. The SPB provide optimal conditions for matrix polymerization by the efficient confinement of ANi monomers within the finite volume of polyelectrolyte brushes and controlled delivery of the oxidizing reagent to the reaction volume. The excellent kinetic stability of the resulting core–shell particles together with the high macroscopic conductivity of the respective composite open up perspectives for novel materials (a conductive ink).eng
dc.description.versionpublished
dc.identifier.citationPubl. in: Macromolecular rapid communications ; 32 (2011), 5. - S. 462-467deu
dc.identifier.doi10.1002/marc.201000626deu
dc.identifier.pmid21433200
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/19737
dc.language.isoengdeu
dc.legacy.dateIssued2012-07-12deu
dc.rightsterms-of-usedeu
dc.rights.urihttps://rightsstatements.org/page/InC/1.0/deu
dc.subjectconducting polymersdeu
dc.subjectcore–shell particlesdeu
dc.subjectnanocompositesdeu
dc.subjectnanoreactordeu
dc.subjectpolyanilinedeu
dc.subject.ddc540deu
dc.titleNanoreactor-assisted polymerization toward stable dispersions of conductive composite particleseng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Korovin2011-03-02Nanor-19737,
  year={2011},
  doi={10.1002/marc.201000626},
  title={Nanoreactor-assisted polymerization toward stable dispersions of conductive composite particles},
  number={5},
  volume={32},
  issn={1022-1336},
  journal={Macromolecular Rapid Communications},
  pages={462--467},
  author={Korovin, Alexey N. and Sergeyev, Vladimir G. and Pyshkina, Olga A. and Hanske, Christoph and Fery, Andreas and Wittemann, Alexander and Tsarkova, Larisa}
}
kops.citation.iso690KOROVIN, Alexey N., Vladimir G. SERGEYEV, Olga A. PYSHKINA, Christoph HANSKE, Andreas FERY, Alexander WITTEMANN, Larisa TSARKOVA, 2011. Nanoreactor-assisted polymerization toward stable dispersions of conductive composite particles. In: Macromolecular Rapid Communications. 2011, 32(5), pp. 462-467. ISSN 1022-1336. eISSN 1521-3927. Available under: doi: 10.1002/marc.201000626deu
kops.citation.iso690KOROVIN, Alexey N., Vladimir G. SERGEYEV, Olga A. PYSHKINA, Christoph HANSKE, Andreas FERY, Alexander WITTEMANN, Larisa TSARKOVA, 2011. Nanoreactor-assisted polymerization toward stable dispersions of conductive composite particles. In: Macromolecular Rapid Communications. 2011, 32(5), pp. 462-467. ISSN 1022-1336. eISSN 1521-3927. Available under: doi: 10.1002/marc.201000626eng
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kops.sourcefieldMacromolecular Rapid Communications. 2011, <b>32</b>(5), pp. 462-467. ISSN 1022-1336. eISSN 1521-3927. Available under: doi: 10.1002/marc.201000626deu
kops.sourcefield.plainMacromolecular Rapid Communications. 2011, 32(5), pp. 462-467. ISSN 1022-1336. eISSN 1521-3927. Available under: doi: 10.1002/marc.201000626deu
kops.sourcefield.plainMacromolecular Rapid Communications. 2011, 32(5), pp. 462-467. ISSN 1022-1336. eISSN 1521-3927. Available under: doi: 10.1002/marc.201000626eng
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source.periodicalTitleMacromolecular Rapid Communications

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