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Nanoreactor-assisted polymerization toward stable dispersions of conductive composite particles

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Datum

2011

Autor:innen

Korovin, Alexey N.
Sergeyev, Vladimir G.
Pyshkina, Olga A.
Hanske, Christoph
Fery, Andreas
Tsarkova, Larisa

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URI (zitierfähiger Link)
http://nbn-resolving.de/urn:nbn:de:bsz:352-197375
DOI (zitierfähiger Link)
https://doi.org/10.1002/marc.201000626
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Open Access-Veröffentlichung

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Chemie: Publikationen
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Macromolecular Rapid Communications. 2011, 32(5), pp. 462-467. ISSN 1022-1336. eISSN 1521-3927. Available under: doi: 10.1002/marc.201000626

Zusammenfassung

We demonstrate the functioning of a macromolecular nanoreactor which guides a reaction in a confined volume and leads toward improved functional properties of a product material. In our approach, the polymerization of aniline (ANi) is conducted within the interfacial volume of spherical polyelectrolyte brushes (SPB) which are densely affixed to colloidal particles. The SPB provide optimal conditions for matrix polymerization by the efficient confinement of ANi monomers within the finite volume of polyelectrolyte brushes and controlled delivery of the oxidizing reagent to the reaction volume. The excellent kinetic stability of the resulting core–shell particles together with the high macroscopic conductivity of the respective composite open up perspectives for novel materials (a conductive ink).

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

conducting polymers, core–shell particles, nanocomposites, nanoreactor, polyaniline

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ISO 690KOROVIN, Alexey N., Vladimir G. SERGEYEV, Olga A. PYSHKINA, Christoph HANSKE, Andreas FERY, Alexander WITTEMANN, Larisa TSARKOVA, 2011. Nanoreactor-assisted polymerization toward stable dispersions of conductive composite particles. In: Macromolecular Rapid Communications. 2011, 32(5), pp. 462-467. ISSN 1022-1336. eISSN 1521-3927. Available under: doi: 10.1002/marc.201000626
BibTex
@article{Korovin2011-03-02Nanor-19737,
  year={2011},
  doi={10.1002/marc.201000626},
  title={Nanoreactor-assisted polymerization toward stable dispersions of conductive composite particles},
  number={5},
  volume={32},
  issn={1022-1336},
  journal={Macromolecular Rapid Communications},
  pages={462--467},
  author={Korovin, Alexey N. and Sergeyev, Vladimir G. and Pyshkina, Olga A. and Hanske, Christoph and Fery, Andreas and Wittemann, Alexander and Tsarkova, Larisa}
}
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