Synthesis and electrochemical behavior of the ferrocenyl units assembled on imidoalane and carbaalane clusters

Kurzanzeige
dc.contributor.authorWinter, Rainer F.
dc.contributor.authorBaldus, Marcdeu
dc.contributor.authorAndronesi, Ovidiudeu
dc.contributor.authorRoesky, Herbertdeu
dc.contributor.authorSrisailam, Shravan Kumardeu
dc.date.accessioned2011-06-30T10:55:39Zdeu
dc.date.available2011-06-30T10:55:39Zdeu
dc.date.issued2005
dc.description.abstractHydroalumination reaction was effectively carried out on ferrocenylnitrile in the synthesis of imidoalane cluster [HAlNCH2C5H4FeCp]6 (3). Compound 3 exhibits a reversible electrochemical behavior. In the presence of ferrocenylmethanol, meta thesis reactions were carried out on [HAlNCH2(C4H3S)]6 (4) and [HAlNCH2Ph]6 (5) in the synthesis of [CpFeC5H4CH2OAlNCH2(C4H3S)]6 (6) and [CpFeC5H4CH2OAlNCH2Ph]6 (7). The ferrocenylmethoxide groups present in these two compounds show a single reversible oxidation wave, which suggests their electrochemical equivalence. Electrochemical studies were also carried out on the carbaalane [(AlH)2(FcCtriple bond; length of mdashCAl)4(AlNMe3)2(CCH2Ph)6] (9), which exhibited a considerably broadened wave with shoulders preceding the main anodic and cathodic peak, and it can be assigned to weak electronic interactions between the individual ferrocenyl sites.eng
dc.description.versionpublished
dc.identifier.citationFirst publ. in: Inorganica Chimica Acta 358 (2005), 7, pp. 2349-2354deu
dc.identifier.doi10.1016/j.ica.2005.01.016deu
dc.identifier.ppn346673372deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/13804
dc.language.isoengdeu
dc.legacy.dateIssued2011-06-30deu
dc.rightsterms-of-usedeu
dc.rights.urihttps://rightsstatements.org/page/InC/1.0/deu
dc.subjectHydroaluminationdeu
dc.subjectImidoalanedeu
dc.subjectCarbaalanedeu
dc.subjectFerrocenedeu
dc.subjectElectrochemistrydeu
dc.subject.ddc540deu
dc.titleSynthesis and electrochemical behavior of the ferrocenyl units assembled on imidoalane and carbaalane clusterseng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Winter2005Synth-13804,
  year={2005},
  doi={10.1016/j.ica.2005.01.016},
  title={Synthesis and electrochemical behavior of the ferrocenyl units assembled on imidoalane and carbaalane clusters},
  number={7},
  volume={358},
  issn={0020-1693},
  journal={Inorganica Chimica Acta},
  pages={2349--2354},
  author={Winter, Rainer F. and Baldus, Marc and Andronesi, Ovidiu and Roesky, Herbert and Srisailam, Shravan Kumar}
}
kops.citation.iso690WINTER, Rainer F., Marc BALDUS, Ovidiu ANDRONESI, Herbert ROESKY, Shravan Kumar SRISAILAM, 2005. Synthesis and electrochemical behavior of the ferrocenyl units assembled on imidoalane and carbaalane clusters. In: Inorganica Chimica Acta. 2005, 358(7), pp. 2349-2354. ISSN 0020-1693. Available under: doi: 10.1016/j.ica.2005.01.016deu
kops.citation.iso690WINTER, Rainer F., Marc BALDUS, Ovidiu ANDRONESI, Herbert ROESKY, Shravan Kumar SRISAILAM, 2005. Synthesis and electrochemical behavior of the ferrocenyl units assembled on imidoalane and carbaalane clusters. In: Inorganica Chimica Acta. 2005, 358(7), pp. 2349-2354. ISSN 0020-1693. Available under: doi: 10.1016/j.ica.2005.01.016eng
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    <dcterms:abstract xml:lang="eng">Hydroalumination reaction was effectively carried out on ferrocenylnitrile in the synthesis of imidoalane cluster [HAlNCH2C5H4FeCp]6 (3). Compound 3 exhibits a reversible electrochemical behavior. In the presence of ferrocenylmethanol, meta thesis reactions were carried out on [HAlNCH2(C4H3S)]6 (4) and [HAlNCH2Ph]6 (5) in the synthesis of [CpFeC5H4CH2OAlNCH2(C4H3S)]6 (6) and [CpFeC5H4CH2OAlNCH2Ph]6 (7). The ferrocenylmethoxide groups present in these two compounds show a single reversible oxidation wave, which suggests their electrochemical equivalence. Electrochemical studies were also carried out on the carbaalane [(AlH)2(FcCtriple bond; length of mdashCAl)4(AlNMe3)2(CCH2Ph)6] (9), which exhibited a considerably broadened wave with shoulders preceding the main anodic and cathodic peak, and it can be assigned to weak electronic interactions between the individual ferrocenyl sites.</dcterms:abstract>
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kops.sourcefieldInorganica Chimica Acta. 2005, <b>358</b>(7), pp. 2349-2354. ISSN 0020-1693. Available under: doi: 10.1016/j.ica.2005.01.016deu
kops.sourcefield.plainInorganica Chimica Acta. 2005, 358(7), pp. 2349-2354. ISSN 0020-1693. Available under: doi: 10.1016/j.ica.2005.01.016deu
kops.sourcefield.plainInorganica Chimica Acta. 2005, 358(7), pp. 2349-2354. ISSN 0020-1693. Available under: doi: 10.1016/j.ica.2005.01.016eng
kops.submitter.emailkarin.hoch@uni-konstanz.dedeu
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source.periodicalTitleInorganica Chimica Acta

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