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Synthesis and electrochemical behavior of the ferrocenyl units assembled on imidoalane and carbaalane clusters

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Datum

2005

Autor:innen

Baldus, Marc
Andronesi, Ovidiu
Roesky, Herbert
Srisailam, Shravan Kumar

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http://nbn-resolving.de/urn:nbn:de:bsz:352-138044
DOI (zitierfähiger Link)
https://doi.org/10.1016/j.ica.2005.01.016
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Open Access-Veröffentlichung
Open Access Green

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Chemie: Publikationen
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Published

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Inorganica Chimica Acta. 2005, 358(7), pp. 2349-2354. ISSN 0020-1693. Available under: doi: 10.1016/j.ica.2005.01.016

Zusammenfassung

Hydroalumination reaction was effectively carried out on ferrocenylnitrile in the synthesis of imidoalane cluster [HAlNCH2C5H4FeCp]6 (3). Compound 3 exhibits a reversible electrochemical behavior. In the presence of ferrocenylmethanol, meta thesis reactions were carried out on [HAlNCH2(C4H3S)]6 (4) and [HAlNCH2Ph]6 (5) in the synthesis of [CpFeC5H4CH2OAlNCH2(C4H3S)]6 (6) and [CpFeC5H4CH2OAlNCH2Ph]6 (7). The ferrocenylmethoxide groups present in these two compounds show a single reversible oxidation wave, which suggests their electrochemical equivalence. Electrochemical studies were also carried out on the carbaalane [(AlH)2(FcCtriple bond; length of mdashCAl)4(AlNMe3)2(CCH2Ph)6] (9), which exhibited a considerably broadened wave with shoulders preceding the main anodic and cathodic peak, and it can be assigned to weak electronic interactions between the individual ferrocenyl sites.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

Hydroalumination, Imidoalane, Carbaalane, Ferrocene, Electrochemistry

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ISO 690WINTER, Rainer F., Marc BALDUS, Ovidiu ANDRONESI, Herbert ROESKY, Shravan Kumar SRISAILAM, 2005. Synthesis and electrochemical behavior of the ferrocenyl units assembled on imidoalane and carbaalane clusters. In: Inorganica Chimica Acta. 2005, 358(7), pp. 2349-2354. ISSN 0020-1693. Available under: doi: 10.1016/j.ica.2005.01.016
BibTex
@article{Winter2005Synth-13804,
  year={2005},
  doi={10.1016/j.ica.2005.01.016},
  title={Synthesis and electrochemical behavior of the ferrocenyl units assembled on imidoalane and carbaalane clusters},
  number={7},
  volume={358},
  issn={0020-1693},
  journal={Inorganica Chimica Acta},
  pages={2349--2354},
  author={Winter, Rainer F. and Baldus, Marc and Andronesi, Ovidiu and Roesky, Herbert and Srisailam, Shravan Kumar}
}
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