The effect of substituents at silicon on the cross-metathesis of trisubstituted vinylsilanes with olefins

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dc.contributor.authorPietraszuk, Cezarydeu
dc.contributor.authorFischer, Helmut
dc.contributor.authorRogalski, Szymondeu
dc.contributor.authorMarciniec, Bogdandeu
dc.date.accessioned2013-05-27T08:40:19Zdeu
dc.date.available2013-05-27T08:40:19Zdeu
dc.date.issued2005
dc.description.abstractEfficient cross-metathesis of vinylsilanes, carrying a large spectrum of different substituents at silicon, with various olefins in the presence of the first and second generation Grubbs catalyst and Hoveyda–Grubbs catalyst is described. On the basis of the results of equimolar reactions of vinylsilanes with ruthenium alkylidene complexes and experiments with deuterium-labelled reagents, a general, metallacarbene mechanism for the cross-metathesis of trisubstituted vinylsilanes with olefins has been suggested. Reaction was proved to be a valuable method for synthesis of unsaturated organosilicon derivatives.eng
dc.description.versionpublished
dc.identifier.citationJournal of Organometallic Chemistry ; 690 (2005), 24-25. - S. 5912-5921deu
dc.identifier.doi10.1016/j.jorganchem.2005.07.091deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/22882
dc.language.isoengdeu
dc.legacy.dateIssued2013-05-27deu
dc.rightsterms-of-usedeu
dc.rights.urihttps://rightsstatements.org/page/InC/1.0/deu
dc.subject.ddc540deu
dc.titleThe effect of substituents at silicon on the cross-metathesis of trisubstituted vinylsilanes with olefinseng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
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@article{Pietraszuk2005effec-22882,
  year={2005},
  doi={10.1016/j.jorganchem.2005.07.091},
  title={The effect of substituents at silicon on the cross-metathesis of trisubstituted vinylsilanes with olefins},
  number={24-25},
  volume={690},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={5912--5921},
  author={Pietraszuk, Cezary and Fischer, Helmut and Rogalski, Szymon and Marciniec, Bogdan}
}
kops.citation.iso690PIETRASZUK, Cezary, Helmut FISCHER, Szymon ROGALSKI, Bogdan MARCINIEC, 2005. The effect of substituents at silicon on the cross-metathesis of trisubstituted vinylsilanes with olefins. In: Journal of Organometallic Chemistry. 2005, 690(24-25), pp. 5912-5921. ISSN 0022-328X. Available under: doi: 10.1016/j.jorganchem.2005.07.091deu
kops.citation.iso690PIETRASZUK, Cezary, Helmut FISCHER, Szymon ROGALSKI, Bogdan MARCINIEC, 2005. The effect of substituents at silicon on the cross-metathesis of trisubstituted vinylsilanes with olefins. In: Journal of Organometallic Chemistry. 2005, 690(24-25), pp. 5912-5921. ISSN 0022-328X. Available under: doi: 10.1016/j.jorganchem.2005.07.091eng
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    <dcterms:abstract xml:lang="eng">Efficient cross-metathesis of vinylsilanes, carrying a large spectrum of different substituents at silicon, with various olefins in the presence of the first and second generation Grubbs catalyst and Hoveyda–Grubbs catalyst is described. On the basis of the results of equimolar reactions of vinylsilanes with ruthenium alkylidene complexes and experiments with deuterium-labelled reagents, a general, metallacarbene mechanism for the cross-metathesis of trisubstituted vinylsilanes with olefins has been suggested. Reaction was proved to be a valuable method for synthesis of unsaturated organosilicon derivatives.</dcterms:abstract>
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kops.sourcefieldJournal of Organometallic Chemistry. 2005, <b>690</b>(24-25), pp. 5912-5921. ISSN 0022-328X. Available under: doi: 10.1016/j.jorganchem.2005.07.091deu
kops.sourcefield.plainJournal of Organometallic Chemistry. 2005, 690(24-25), pp. 5912-5921. ISSN 0022-328X. Available under: doi: 10.1016/j.jorganchem.2005.07.091deu
kops.sourcefield.plainJournal of Organometallic Chemistry. 2005, 690(24-25), pp. 5912-5921. ISSN 0022-328X. Available under: doi: 10.1016/j.jorganchem.2005.07.091eng
kops.submitter.emailkarin.hoch@uni-konstanz.dedeu
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source.identifier.issn0022-328X
source.periodicalTitleJournal of Organometallic Chemistry

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