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The effect of substituents at silicon on the cross-metathesis of trisubstituted vinylsilanes with olefins

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2005

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Pietraszuk, Cezary
Rogalski, Szymon
Marciniec, Bogdan

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http://nbn-resolving.de/urn:nbn:de:bsz:352-228821
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https://doi.org/10.1016/j.jorganchem.2005.07.091
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Journal of Organometallic Chemistry. 2005, 690(24-25), pp. 5912-5921. ISSN 0022-328X. Available under: doi: 10.1016/j.jorganchem.2005.07.091

Zusammenfassung

Efficient cross-metathesis of vinylsilanes, carrying a large spectrum of different substituents at silicon, with various olefins in the presence of the first and second generation Grubbs catalyst and Hoveyda–Grubbs catalyst is described. On the basis of the results of equimolar reactions of vinylsilanes with ruthenium alkylidene complexes and experiments with deuterium-labelled reagents, a general, metallacarbene mechanism for the cross-metathesis of trisubstituted vinylsilanes with olefins has been suggested. Reaction was proved to be a valuable method for synthesis of unsaturated organosilicon derivatives.

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540 Chemie

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ISO 690PIETRASZUK, Cezary, Helmut FISCHER, Szymon ROGALSKI, Bogdan MARCINIEC, 2005. The effect of substituents at silicon on the cross-metathesis of trisubstituted vinylsilanes with olefins. In: Journal of Organometallic Chemistry. 2005, 690(24-25), pp. 5912-5921. ISSN 0022-328X. Available under: doi: 10.1016/j.jorganchem.2005.07.091
BibTex
@article{Pietraszuk2005effec-22882,
  year={2005},
  doi={10.1016/j.jorganchem.2005.07.091},
  title={The effect of substituents at silicon on the cross-metathesis of trisubstituted vinylsilanes with olefins},
  number={24-25},
  volume={690},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={5912--5921},
  author={Pietraszuk, Cezary and Fischer, Helmut and Rogalski, Szymon and Marciniec, Bogdan}
}
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