On the Reaction of 1-Aza-2-azoniaallene Salts with Carbodiimides

Kurzanzeige
dc.contributor.authorWang, Quanruideu
dc.contributor.authorTroll, Carstendeu
dc.contributor.authorFischer, Helmut
dc.contributor.authorJochims, Johannes
dc.contributor.authorAmer, Atefdeu
dc.date.accessioned2013-06-26T10:04:44Zdeu
dc.date.available2013-06-26T10:04:44Zdeu
dc.date.issued1993
dc.description.abstract1-Aza-2-azoniaallene cations 3, prepared in situ from geminal (chloroalkyl)azo compounds 2, react with carbodiimides 4 to give 4,5-dihydro-5-imino-1H-1,2,4-triazolium salts 7. An X-ray structural analysis was carried out for 71. According to AM1 calculations the cycloaddition of carbodiimides to 1-aza-2-azoniaallene cations occurs in a nonconcerted manner via cyanamidium cations 5 as intermediates. Hetero-Wagner-Meerwein rearrangements of the primary cycloadducts 6 provide the final products 7.eng
dc.description.versionpublished
dc.identifier.citationEuropean Journal of Inorganic Chemistry : Chemische Berichte ; 126 (1993), 11. - S.2519-2524deu
dc.identifier.doi10.1002/cber.19931261128deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/23390
dc.language.isoengdeu
dc.legacy.dateIssued2013-06-26deu
dc.rightsterms-of-usedeu
dc.rights.urihttps://rightsstatements.org/page/InC/1.0/deu
dc.subject1-Aza-2-azoniaallene cationsdeu
dc.subjectCarbodiimidesdeu
dc.subject1H-1deu
dc.subject2deu
dc.subject4-Triazolium saltsdeu
dc.subject.ddc540deu
dc.titleOn the Reaction of 1-Aza-2-azoniaallene Salts with Carbodiimideseng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Wang1993React-23390,
  year={1993},
  doi={10.1002/cber.19931261128},
  title={On the Reaction of 1-Aza-2-azoniaallene Salts with Carbodiimides},
  number={11},
  volume={126},
  issn={0009-2940},
  journal={Chemische Berichte},
  pages={2519--2524},
  author={Wang, Quanrui and Troll, Carsten and Fischer, Helmut and Jochims, Johannes and Amer, Atef}
}
kops.citation.iso690WANG, Quanrui, Carsten TROLL, Helmut FISCHER, Johannes JOCHIMS, Atef AMER, 1993. On the Reaction of 1-Aza-2-azoniaallene Salts with Carbodiimides. In: Chemische Berichte. 1993, 126(11), pp. 2519-2524. ISSN 0009-2940. eISSN 1873-3751. Available under: doi: 10.1002/cber.19931261128deu
kops.citation.iso690WANG, Quanrui, Carsten TROLL, Helmut FISCHER, Johannes JOCHIMS, Atef AMER, 1993. On the Reaction of 1-Aza-2-azoniaallene Salts with Carbodiimides. In: Chemische Berichte. 1993, 126(11), pp. 2519-2524. ISSN 0009-2940. eISSN 1873-3751. Available under: doi: 10.1002/cber.19931261128eng
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kops.sourcefieldChemische Berichte. 1993, <b>126</b>(11), pp. 2519-2524. ISSN 0009-2940. eISSN 1873-3751. Available under: doi: 10.1002/cber.19931261128deu
kops.sourcefield.plainChemische Berichte. 1993, 126(11), pp. 2519-2524. ISSN 0009-2940. eISSN 1873-3751. Available under: doi: 10.1002/cber.19931261128deu
kops.sourcefield.plainChemische Berichte. 1993, 126(11), pp. 2519-2524. ISSN 0009-2940. eISSN 1873-3751. Available under: doi: 10.1002/cber.19931261128eng
kops.submitter.emailkarin.hoch@uni-konstanz.dedeu
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source.periodicalTitleChemische Berichte

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