Publikation:

Single‐Molecule Doping : Conductance Changed By Transition Metal Centers in Salen Molecules

Lade...
Vorschaubild

Dateien

Kilibarda_2-1j0p7e567bkcd5.pdf
Kilibarda_2-1j0p7e567bkcd5.pdfGröße: 863.2 KBDownloads: 80

Datum

2021

Autor:innen

Kilibarda, Filip
Strobel, Alexander
Sendler, Torsten
Wieser, Matthias
Mortensen, Michael
Trads, Julie Brender
Helm, Manfred
Kerbusch, Jochen
Gemming, Sibylle

Herausgeber:innen

Kontakt

ISSN der Zeitschrift

Electronic ISSN

ISBN

Bibliografische Daten

Verlag

Schriftenreihe

Auflagebezeichnung

ArXiv-ID

Internationale Patentnummer

Link zur Lizenz

Angaben zur Forschungsförderung

Projekt

Open Access-Veröffentlichung
Open Access Hybrid
Core Facility der Universität Konstanz

Gesperrt bis

Titel in einer weiteren Sprache

Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published

Erschienen in

Advanced Electronic Materials. Wiley. 2021, 7(10), 2100252. ISSN 2199-160X. eISSN 2199-160X. Available under: doi: 10.1002/aelm.202100252

Zusammenfassung

The creation of molecular components for use as electronic devices has made enormous progress. In order to advance the field further toward realistic electronic concepts, methods for the controlled modification of the conducting properties of the molecules contacted by metallic electrodes need to be further developed. Here a comprehensive study of charge transport in a class of molecules that allows modifications by introducing metal centers into organic structures is presented. Single molecules are electrically contacted and characterized in order to understand the role of the metal centers in the conductance mechanism through the molecular junctions. It is shown that the presence of single metal ions modifies the energy levels and the coupling of the molecules to the electrical contacts, and that these modifications lead to systematic variations in the statistical behavior of transport properties of the molecular junctions. A rigorous statistical analysis of thousands of junctions is performed to reveal this correlation. The understanding of the role of the metal ion in the resulting conductance properties is an essential step toward the development of molecular electronic circuits.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
530 Physik

Schlagwörter

Konferenz

Rezension
undefined / . - undefined, undefined

Forschungsvorhaben

Organisationseinheiten

Zeitschriftenheft

Zugehörige Datensätze in KOPS

Zitieren

ISO 690KILIBARDA, Filip, Alexander STROBEL, Torsten SENDLER, Matthias WIESER, Michael MORTENSEN, Julie Brender TRADS, Manfred HELM, Jochen KERBUSCH, Elke SCHEER, Sibylle GEMMING, Kurt V. GOTHELF, Artur ERBE, 2021. Single‐Molecule Doping : Conductance Changed By Transition Metal Centers in Salen Molecules. In: Advanced Electronic Materials. Wiley. 2021, 7(10), 2100252. ISSN 2199-160X. eISSN 2199-160X. Available under: doi: 10.1002/aelm.202100252
BibTex
@article{Kilibarda2021-10Singl-54671,
  year={2021},
  doi={10.1002/aelm.202100252},
  title={Single‐Molecule Doping : Conductance Changed By Transition Metal Centers in Salen Molecules},
  number={10},
  volume={7},
  issn={2199-160X},
  journal={Advanced Electronic Materials},
  author={Kilibarda, Filip and Strobel, Alexander and Sendler, Torsten and Wieser, Matthias and Mortensen, Michael and Trads, Julie Brender and Helm, Manfred and Kerbusch, Jochen and Scheer, Elke and Gemming, Sibylle and Gothelf, Kurt V. and Erbe, Artur},
  note={Article Number: 2100252}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/54671">
    <dc:creator>Helm, Manfred</dc:creator>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2021-08-20T12:40:24Z</dc:date>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/54671/1/Kilibarda_2-1j0p7e567bkcd5.pdf"/>
    <dc:contributor>Gothelf, Kurt V.</dc:contributor>
    <dc:language>eng</dc:language>
    <dc:contributor>Kilibarda, Filip</dc:contributor>
    <dc:creator>Mortensen, Michael</dc:creator>
    <dc:creator>Strobel, Alexander</dc:creator>
    <dc:creator>Sendler, Torsten</dc:creator>
    <dc:creator>Trads, Julie Brender</dc:creator>
    <dc:contributor>Scheer, Elke</dc:contributor>
    <dc:contributor>Trads, Julie Brender</dc:contributor>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2021-08-20T12:40:24Z</dcterms:available>
    <dcterms:issued>2021-10</dcterms:issued>
    <dcterms:title>Single‐Molecule Doping : Conductance Changed By Transition Metal Centers in Salen Molecules</dcterms:title>
    <dc:creator>Gothelf, Kurt V.</dc:creator>
    <dc:creator>Scheer, Elke</dc:creator>
    <dc:creator>Kilibarda, Filip</dc:creator>
    <dc:contributor>Gemming, Sibylle</dc:contributor>
    <dcterms:rights rdf:resource="http://creativecommons.org/licenses/by/4.0/"/>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:contributor>Erbe, Artur</dc:contributor>
    <dc:rights>Attribution 4.0 International</dc:rights>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/54671/1/Kilibarda_2-1j0p7e567bkcd5.pdf"/>
    <dc:creator>Wieser, Matthias</dc:creator>
    <dc:creator>Kerbusch, Jochen</dc:creator>
    <dc:creator>Gemming, Sibylle</dc:creator>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/54671"/>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dc:contributor>Mortensen, Michael</dc:contributor>
    <dc:contributor>Kerbusch, Jochen</dc:contributor>
    <dcterms:abstract xml:lang="eng">The creation of molecular components for use as electronic devices has made enormous progress. In order to advance the field further toward realistic electronic concepts, methods for the controlled modification of the conducting properties of the molecules contacted by metallic electrodes need to be further developed. Here a comprehensive study of charge transport in a class of molecules that allows modifications by introducing metal centers into organic structures is presented. Single molecules are electrically contacted and characterized in order to understand the role of the metal centers in the conductance mechanism through the molecular junctions. It is shown that the presence of single metal ions modifies the energy levels and the coupling of the molecules to the electrical contacts, and that these modifications lead to systematic variations in the statistical behavior of transport properties of the molecular junctions. A rigorous statistical analysis of thousands of junctions is performed to reveal this correlation. The understanding of the role of the metal ion in the resulting conductance properties is an essential step toward the development of molecular electronic circuits.</dcterms:abstract>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dc:contributor>Sendler, Torsten</dc:contributor>
    <dc:contributor>Strobel, Alexander</dc:contributor>
    <dc:contributor>Wieser, Matthias</dc:contributor>
    <dc:contributor>Helm, Manfred</dc:contributor>
    <dc:creator>Erbe, Artur</dc:creator>
  </rdf:Description>
</rdf:RDF>

Interner Vermerk

xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter

Kontakt
URL der Originalveröffentl.

Prüfdatum der URL

Prüfungsdatum der Dissertation

Finanzierungsart

Kommentar zur Publikation

Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
Begutachtet
Unbekannt
Diese Publikation teilen