Low oxidation state aluminum-containing cluster anions : LAlH− and LAln− (n = 2–4, L = N[Si(Me)3]2)

Kurzanzeige
dc.contributor.authorZhang, Xinxing
dc.contributor.authorWang, Linjie
dc.contributor.authorMontone, Georgia R.
dc.contributor.authorGill, Ann F
dc.contributor.authorGanteför, Gerd
dc.contributor.authorEichhorn, Bryan
dc.contributor.authorKandalam, Anil K.
dc.contributor.authorBowen, Kit H
dc.date.accessioned2018-03-09T13:57:12Z
dc.date.available2018-03-09T13:57:12Z
dc.date.issued2017eng
dc.description.abstractSeveral low oxidation state aluminum-containing cluster anions, LAlH− and LAln− (n = 2–4, L = N[Si(Me)3]2), were produced via reactions between aluminum hydride cluster anions, AlxHy−, and hexamethyldisilazane (HMDS). These clusters were characterized by mass spectrometry, anion photoelectron spectroscopy, and density functional theory (DFT) based calculations. Agreement between the experimental and theoretical vertical detachment energies (VDEs) and adiabatic detachment energies (ADEs) validated the computed geometrical structures. Reactions between aluminum hydride cluster anions and ligands promise to be a new synthetic scheme for low oxidation state, ligated aluminum clusters.eng
dc.description.versionpublishedeng
dc.identifier.doi10.1039/C7CP01560Geng
dc.identifier.urihttps://kops.uni-konstanz.de/handle/123456789/41742
dc.language.isoengeng
dc.subject.ddc530eng
dc.titleLow oxidation state aluminum-containing cluster anions : LAlH− and LAl<sub>n</sub>− (n = 2–4, L = N[Si(Me)<sub>3</sub>]<sub>2</sub>)eng
dc.typeJOURNAL_ARTICLEeng
dspace.entity.typePublication
kops.citation.bibtex
@article{Zhang2017oxida-41742,
  year={2017},
  doi={10.1039/C7CP01560G},
  title={Low oxidation state aluminum-containing cluster anions : LAlH− and LAl<sub>n</sub>− (n = 2–4, L = N[Si(Me)<sub>3</sub>]<sub>2</sub>)},
  number={23},
  volume={19},
  issn={1463-9076},
  journal={Physical Chemistry Chemical Physics},
  pages={15541--15548},
  author={Zhang, Xinxing and Wang, Linjie and Montone, Georgia R. and Gill, Ann F and Ganteför, Gerd and Eichhorn, Bryan and Kandalam, Anil K. and Bowen, Kit H}
}
kops.citation.iso690ZHANG, Xinxing, Linjie WANG, Georgia R. MONTONE, Ann F GILL, Gerd GANTEFÖR, Bryan EICHHORN, Anil K. KANDALAM, Kit H BOWEN, 2017. Low oxidation state aluminum-containing cluster anions : LAlH− and LAln− (n = 2–4, L = N[Si(Me)3]2). In: Physical Chemistry Chemical Physics. 2017, 19(23), pp. 15541-15548. ISSN 1463-9076. eISSN 1463-9084. Available under: doi: 10.1039/C7CP01560Gdeu
kops.citation.iso690ZHANG, Xinxing, Linjie WANG, Georgia R. MONTONE, Ann F GILL, Gerd GANTEFÖR, Bryan EICHHORN, Anil K. KANDALAM, Kit H BOWEN, 2017. Low oxidation state aluminum-containing cluster anions : LAlH− and LAln− (n = 2–4, L = N[Si(Me)3]2). In: Physical Chemistry Chemical Physics. 2017, 19(23), pp. 15541-15548. ISSN 1463-9076. eISSN 1463-9084. Available under: doi: 10.1039/C7CP01560Geng
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kops.sourcefieldPhysical Chemistry Chemical Physics. 2017, <b>19</b>(23), pp. 15541-15548. ISSN 1463-9076. eISSN 1463-9084. Available under: doi: 10.1039/C7CP01560Gdeu
kops.sourcefield.plainPhysical Chemistry Chemical Physics. 2017, 19(23), pp. 15541-15548. ISSN 1463-9076. eISSN 1463-9084. Available under: doi: 10.1039/C7CP01560Gdeu
kops.sourcefield.plainPhysical Chemistry Chemical Physics. 2017, 19(23), pp. 15541-15548. ISSN 1463-9076. eISSN 1463-9084. Available under: doi: 10.1039/C7CP01560Geng
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source.periodicalTitlePhysical Chemistry Chemical Physicseng

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