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Low oxidation state aluminum-containing cluster anions : LAlH− and LAln− (n = 2–4, L = N[Si(Me)3]2)

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2017

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Zhang, Xinxing
Wang, Linjie
Montone, Georgia R.
Gill, Ann F
Eichhorn, Bryan
Kandalam, Anil K.
Bowen, Kit H

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https://doi.org/10.1039/C7CP01560G
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Physical Chemistry Chemical Physics. 2017, 19(23), pp. 15541-15548. ISSN 1463-9076. eISSN 1463-9084. Available under: doi: 10.1039/C7CP01560G

Zusammenfassung

Several low oxidation state aluminum-containing cluster anions, LAlH− and LAln− (n = 2–4, L = N[Si(Me)3]2), were produced via reactions between aluminum hydride cluster anions, AlxHy−, and hexamethyldisilazane (HMDS). These clusters were characterized by mass spectrometry, anion photoelectron spectroscopy, and density functional theory (DFT) based calculations. Agreement between the experimental and theoretical vertical detachment energies (VDEs) and adiabatic detachment energies (ADEs) validated the computed geometrical structures. Reactions between aluminum hydride cluster anions and ligands promise to be a new synthetic scheme for low oxidation state, ligated aluminum clusters.

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ISO 690ZHANG, Xinxing, Linjie WANG, Georgia R. MONTONE, Ann F GILL, Gerd GANTEFÖR, Bryan EICHHORN, Anil K. KANDALAM, Kit H BOWEN, 2017. Low oxidation state aluminum-containing cluster anions : LAlH− and LAln− (n = 2–4, L = N[Si(Me)3]2). In: Physical Chemistry Chemical Physics. 2017, 19(23), pp. 15541-15548. ISSN 1463-9076. eISSN 1463-9084. Available under: doi: 10.1039/C7CP01560G
BibTex
@article{Zhang2017oxida-41742,
  year={2017},
  doi={10.1039/C7CP01560G},
  title={Low oxidation state aluminum-containing cluster anions : LAlH− and LAl<sub>n</sub>− (n = 2–4, L = N[Si(Me)<sub>3</sub>]<sub>2</sub>)},
  number={23},
  volume={19},
  issn={1463-9076},
  journal={Physical Chemistry Chemical Physics},
  pages={15541--15548},
  author={Zhang, Xinxing and Wang, Linjie and Montone, Georgia R. and Gill, Ann F and Ganteför, Gerd and Eichhorn, Bryan and Kandalam, Anil K. and Bowen, Kit H}
}
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