Photo and mechanochemically induced reduction of nitroarenes using ammonia borane

dc.contributor.authorMkrtchyan, Satenik
dc.contributor.authorPurohit, Vishal B.
dc.contributor.authorShalimov, Oleksandr
dc.contributor.authorKarpun, Yevhen
dc.contributor.authorPrajapati, Ronak V.
dc.contributor.authorPrajapati, Vaibhav D.
dc.contributor.authorBielec, Björn
dc.contributor.authorAddová, Gabriela
dc.contributor.authorFilo, Juraj
dc.contributor.authorJin, Pengyue
dc.contributor.authorWang, Cui
dc.contributor.authorKatayev, Dmitry
dc.contributor.authorIaroshenko, Viktor O.
dc.date.accessioned2026-02-18T16:08:32Z
dc.date.available2026-02-18T16:08:32Z
dc.date.issued2026
dc.description.abstractThis study presents an advanced approach for the reduction of nitroarenes to anilines, employing cucurbit[7]uril as a catalyst and ammonia borane as a hydrogen source, signifying noteworthy progression in photochemical supramolecular catalysis. Expanding the capability of ammonia borane, a mechanochemical reduction approach for the same reaction has also been established. Additionally, the developed mechanochemical protocol was successfully extended for similar types of synthetic scenarios, including (a) reductive amidation of nitro compounds with carboxylic acids and (b) amidation of carboxylic acids. The products of these reactions i.e., anilines and amides, are indispensable precursors in the manufacture of pharmaceuticals, agrochemicals, and other chemically significant entities.
dc.description.versionpublisheddeu
dc.identifier.doi10.1039/d5qo01451d
dc.identifier.urihttps://kops.uni-konstanz.de/handle/123456789/76217
dc.language.isoeng
dc.subject.ddc540
dc.titlePhoto and mechanochemically induced reduction of nitroarenes using ammonia boraneeng
dc.typeJOURNAL_ARTICLE
dspace.entity.typePublication
kops.citation.bibtex
@article{Mkrtchyan2026Photo-76217,
  title={Photo and mechanochemically induced reduction of nitroarenes using ammonia borane},
  year={2026},
  doi={10.1039/d5qo01451d},
  number={3},
  volume={13},
  issn={2052-4110},
  journal={Organic Chemistry Frontiers},
  pages={874--883},
  author={Mkrtchyan, Satenik and Purohit, Vishal B. and Shalimov, Oleksandr and Karpun, Yevhen and Prajapati, Ronak V. and Prajapati, Vaibhav D. and Bielec, Björn and Addová, Gabriela and Filo, Juraj and Jin, Pengyue and Wang, Cui and Katayev, Dmitry and Iaroshenko, Viktor O.}
}
kops.citation.iso690MKRTCHYAN, Satenik, Vishal B. PUROHIT, Oleksandr SHALIMOV, Yevhen KARPUN, Ronak V. PRAJAPATI, Vaibhav D. PRAJAPATI, Björn BIELEC, Gabriela ADDOVÁ, Juraj FILO, Pengyue JIN, Cui WANG, Dmitry KATAYEV, Viktor O. IAROSHENKO, 2026. Photo and mechanochemically induced reduction of nitroarenes using ammonia borane. In: Organic Chemistry Frontiers. Royal Society of Chemistry (RSC). 2026, 13(3), S. 874-883. ISSN 2052-4110. eISSN 2052-4129. Verfügbar unter: doi: 10.1039/d5qo01451ddeu
kops.citation.iso690MKRTCHYAN, Satenik, Vishal B. PUROHIT, Oleksandr SHALIMOV, Yevhen KARPUN, Ronak V. PRAJAPATI, Vaibhav D. PRAJAPATI, Björn BIELEC, Gabriela ADDOVÁ, Juraj FILO, Pengyue JIN, Cui WANG, Dmitry KATAYEV, Viktor O. IAROSHENKO, 2026. Photo and mechanochemically induced reduction of nitroarenes using ammonia borane. In: Organic Chemistry Frontiers. Royal Society of Chemistry (RSC). 2026, 13(3), pp. 874-883. ISSN 2052-4110. eISSN 2052-4129. Available under: doi: 10.1039/d5qo01451deng
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kops.sourcefieldOrganic Chemistry Frontiers. Royal Society of Chemistry (RSC). 2026, <b>13</b>(3), S. 874-883. ISSN 2052-4110. eISSN 2052-4129. Verfügbar unter: doi: 10.1039/d5qo01451ddeu
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