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Photo and mechanochemically induced reduction of nitroarenes using ammonia borane

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2026

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Mkrtchyan, Satenik
Purohit, Vishal B.
Shalimov, Oleksandr
Karpun, Yevhen
Prajapati, Ronak V.
Prajapati, Vaibhav D.
Bielec, Björn
Addová, Gabriela
Filo, Juraj
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https://doi.org/10.1039/d5qo01451d
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Swiss National Science Foundation: IZSEZ0_238400
Deutsche Forschungsgemeinschaft (DFG): 535142873
Austrian Science Fund (FWF): 10.55776/P35594

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Organic Chemistry Frontiers. Royal Society of Chemistry (RSC). 2026, 13(3), S. 874-883. ISSN 2052-4110. eISSN 2052-4129. Verfügbar unter: doi: 10.1039/d5qo01451d

Zusammenfassung

This study presents an advanced approach for the reduction of nitroarenes to anilines, employing cucurbit[7]uril as a catalyst and ammonia borane as a hydrogen source, signifying noteworthy progression in photochemical supramolecular catalysis. Expanding the capability of ammonia borane, a mechanochemical reduction approach for the same reaction has also been established. Additionally, the developed mechanochemical protocol was successfully extended for similar types of synthetic scenarios, including (a) reductive amidation of nitro compounds with carboxylic acids and (b) amidation of carboxylic acids. The products of these reactions i.e., anilines and amides, are indispensable precursors in the manufacture of pharmaceuticals, agrochemicals, and other chemically significant entities.

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540 Chemie

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ISO 690MKRTCHYAN, Satenik, Vishal B. PUROHIT, Oleksandr SHALIMOV, Yevhen KARPUN, Ronak V. PRAJAPATI, Vaibhav D. PRAJAPATI, Björn BIELEC, Gabriela ADDOVÁ, Juraj FILO, Pengyue JIN, Cui WANG, Dmitry KATAYEV, Viktor O. IAROSHENKO, 2026. Photo and mechanochemically induced reduction of nitroarenes using ammonia borane. In: Organic Chemistry Frontiers. Royal Society of Chemistry (RSC). 2026, 13(3), S. 874-883. ISSN 2052-4110. eISSN 2052-4129. Verfügbar unter: doi: 10.1039/d5qo01451d
BibTex
@article{Mkrtchyan2026Photo-76217,
  title={Photo and mechanochemically induced reduction of nitroarenes using ammonia borane},
  year={2026},
  doi={10.1039/d5qo01451d},
  number={3},
  volume={13},
  issn={2052-4110},
  journal={Organic Chemistry Frontiers},
  pages={874--883},
  author={Mkrtchyan, Satenik and Purohit, Vishal B. and Shalimov, Oleksandr and Karpun, Yevhen and Prajapati, Ronak V. and Prajapati, Vaibhav D. and Bielec, Björn and Addová, Gabriela and Filo, Juraj and Jin, Pengyue and Wang, Cui and Katayev, Dmitry and Iaroshenko, Viktor O.}
}
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