Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO

dc.contributor.authorVoepel, Pascal
dc.contributor.authorSeitz, Christoph
dc.contributor.authorWaack, Jan M.
dc.contributor.authorZahn, Stefan
dc.contributor.authorLeichtweiß, Thomas
dc.contributor.authorZaichenko, Aleksandr
dc.contributor.authorMollenhauer, Doreen
dc.contributor.authorAmenitsch, Heinz
dc.contributor.authorVoggenreiter, Markus
dc.contributor.authorPolarz, Sebastian
dc.contributor.authorSmarsly, Bernd M.
dc.date.accessioned2017-12-13T11:09:06Z
dc.date.available2017-12-13T11:09:06Z
dc.date.issued2017eng
dc.description.abstractIn this work, we present detailed investigations on the influence of binary ionic liquid (IL) mixtures on sol–gel syntheses of metastable metal oxide phases. The synthesis of the metastable TiO2 bronze phase and anatase as well as the rutile modification is followed via in situ diffraction methods coupled with thermal gravimetric analysis. The variation of the composition of mixtures of ILs allows for the adjustment of TiO2 phase composition at low temperatures. On the basis of these results, the synthesis of the hexagonal tungsten bronze-like titanium hydroxyl oxy fluoride was achieved. Our results pave the way for a deeper understanding of IL participation in the syntheses of inorganic nanomaterials, going further than treating them as solvents.eng
dc.description.versionpublishedde
dc.identifier.doi10.1021/acs.cgd.7b01231eng
dc.identifier.urihttps://kops.uni-konstanz.de/handle/123456789/40919
dc.language.isoengeng
dc.subject.ddc540eng
dc.titlePeering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiOeng
dc.typeJOURNAL_ARTICLEde
dspace.entity.typePublication
kops.citation.bibtex
@article{Voepel2017Peeri-40919,
  year={2017},
  doi={10.1021/acs.cgd.7b01231},
  title={Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO},
  number={10},
  volume={17},
  issn={1528-7483},
  journal={Crystal Growth & Design},
  pages={5586--5601},
  author={Voepel, Pascal and Seitz, Christoph and Waack, Jan M. and Zahn, Stefan and Leichtweiß, Thomas and Zaichenko, Aleksandr and Mollenhauer, Doreen and Amenitsch, Heinz and Voggenreiter, Markus and Polarz, Sebastian and Smarsly, Bernd M.}
}
kops.citation.iso690VOEPEL, Pascal, Christoph SEITZ, Jan M. WAACK, Stefan ZAHN, Thomas LEICHTWEISS, Aleksandr ZAICHENKO, Doreen MOLLENHAUER, Heinz AMENITSCH, Markus VOGGENREITER, Sebastian POLARZ, Bernd M. SMARSLY, 2017. Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO. In: Crystal Growth & Design. 2017, 17(10), pp. 5586-5601. ISSN 1528-7483. eISSN 1528-7505. Available under: doi: 10.1021/acs.cgd.7b01231deu
kops.citation.iso690VOEPEL, Pascal, Christoph SEITZ, Jan M. WAACK, Stefan ZAHN, Thomas LEICHTWEISS, Aleksandr ZAICHENKO, Doreen MOLLENHAUER, Heinz AMENITSCH, Markus VOGGENREITER, Sebastian POLARZ, Bernd M. SMARSLY, 2017. Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO. In: Crystal Growth & Design. 2017, 17(10), pp. 5586-5601. ISSN 1528-7483. eISSN 1528-7505. Available under: doi: 10.1021/acs.cgd.7b01231eng
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kops.sourcefieldCrystal Growth & Design. 2017, <b>17</b>(10), pp. 5586-5601. ISSN 1528-7483. eISSN 1528-7505. Available under: doi: 10.1021/acs.cgd.7b01231deu
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