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Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO

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2017

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Voepel, Pascal
Seitz, Christoph
Waack, Jan M.
Zahn, Stefan
Leichtweiß, Thomas
Zaichenko, Aleksandr
Mollenhauer, Doreen
Amenitsch, Heinz

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Crystal Growth & Design. 2017, 17(10), pp. 5586-5601. ISSN 1528-7483. eISSN 1528-7505. Available under: doi: 10.1021/acs.cgd.7b01231

Zusammenfassung

In this work, we present detailed investigations on the influence of binary ionic liquid (IL) mixtures on sol–gel syntheses of metastable metal oxide phases. The synthesis of the metastable TiO2 bronze phase and anatase as well as the rutile modification is followed via in situ diffraction methods coupled with thermal gravimetric analysis. The variation of the composition of mixtures of ILs allows for the adjustment of TiO2 phase composition at low temperatures. On the basis of these results, the synthesis of the hexagonal tungsten bronze-like titanium hydroxyl oxy fluoride was achieved. Our results pave the way for a deeper understanding of IL participation in the syntheses of inorganic nanomaterials, going further than treating them as solvents.

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ISO 690VOEPEL, Pascal, Christoph SEITZ, Jan M. WAACK, Stefan ZAHN, Thomas LEICHTWEISS, Aleksandr ZAICHENKO, Doreen MOLLENHAUER, Heinz AMENITSCH, Markus VOGGENREITER, Sebastian POLARZ, Bernd M. SMARSLY, 2017. Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO. In: Crystal Growth & Design. 2017, 17(10), pp. 5586-5601. ISSN 1528-7483. eISSN 1528-7505. Available under: doi: 10.1021/acs.cgd.7b01231
BibTex
@article{Voepel2017Peeri-40919,
  year={2017},
  doi={10.1021/acs.cgd.7b01231},
  title={Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO},
  number={10},
  volume={17},
  issn={1528-7483},
  journal={Crystal Growth & Design},
  pages={5586--5601},
  author={Voepel, Pascal and Seitz, Christoph and Waack, Jan M. and Zahn, Stefan and Leichtweiß, Thomas and Zaichenko, Aleksandr and Mollenhauer, Doreen and Amenitsch, Heinz and Voggenreiter, Markus and Polarz, Sebastian and Smarsly, Bernd M.}
}
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