Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO

Voepel, Pascal; Seitz, Christoph; Waack, Jan M.; Zahn, Stefan; Leichtweiß, Thomas; Zaichenko, Aleksandr; Mollenhauer, Doreen; Amenitsch, Heinz; Voggenreiter, Markus; Polarz, Sebastian; Smarsly, Bernd M.

Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO

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Date

2017

Authors

Voepel, Pascal

Seitz, Christoph

Waack, Jan M.

Zahn, Stefan

Leichtweiß, Thomas

Zaichenko, Aleksandr

Mollenhauer, Doreen

Amenitsch, Heinz

Voggenreiter, Markus

Polarz, Sebastian

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DOI (citable link)

10.1021/acs.cgd.7b01231

Collections

Chemie

Publication type

Journal article

Publication status

Published

Published in

Crystal Growth & Design ; 17 (2017), 10. - pp. 5586-5601. - ISSN 1528-7483. - eISSN 1528-7505

Abstract

In this work, we present detailed investigations on the influence of binary ionic liquid (IL) mixtures on sol–gel syntheses of metastable metal oxide phases. The synthesis of the metastable TiO2 bronze phase and anatase as well as the rutile modification is followed via in situ diffraction methods coupled with thermal gravimetric analysis. The variation of the composition of mixtures of ILs allows for the adjustment of TiO2 phase composition at low temperatures. On the basis of these results, the synthesis of the hexagonal tungsten bronze-like titanium hydroxyl oxy fluoride was achieved. Our results pave the way for a deeper understanding of IL participation in the syntheses of inorganic nanomaterials, going further than treating them as solvents.

Subject (DDC)

540 Chemistry

Cite This

ISO 690

VOEPEL, Pascal, Christoph SEITZ, Jan M. WAACK, Stefan ZAHN, Thomas LEICHTWEISS, Aleksandr ZAICHENKO, Doreen MOLLENHAUER, Heinz AMENITSCH, Markus VOGGENREITER, Sebastian POLARZ, Bernd M. SMARSLY, 2017. Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO. In: Crystal Growth & Design. 17(10), pp. 5586-5601. ISSN 1528-7483. eISSN 1528-7505. Available under: doi: 10.1021/acs.cgd.7b01231

BibTex

@article{Voepel2017Peeri-40919,
  year={2017},
  doi={10.1021/acs.cgd.7b01231},
  title={Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO},
  number={10},
  volume={17},
  issn={1528-7483},
  journal={Crystal Growth & Design},
  pages={5586--5601},
  author={Voepel, Pascal and Seitz, Christoph and Waack, Jan M. and Zahn, Stefan and Leichtweiß, Thomas and Zaichenko, Aleksandr and Mollenhauer, Doreen and Amenitsch, Heinz and Voggenreiter, Markus and Polarz, Sebastian and Smarsly, Bernd M.}
}

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Bibliography of Konstanz

Yes