Cerium(III)-catalyzed addition of diethylzinc to carbonyl compounds

Kurzanzeige
dc.contributor.authorFischer, Stefan
dc.contributor.authorGroth, Ulrich
dc.contributor.authorJeske, Mariodeu
dc.contributor.authorSchütz, Thorbendeu
dc.date.accessioned2011-03-24T18:16:11Zdeu
dc.date.available2011-03-24T18:16:11Zdeu
dc.date.issued2002deu
dc.description.abstractCeCl3 catalyzes the addition of Et2Zn to a variety of alipahtic and aromatic aldehydes and ketones in THF in the presence of TMSCl as a scavenger. Optimization of the applied solvent allowed to avoid the TMSCl mediated addition using CeCl3·(THF)2 or Ce(i-PrO)3 as catalysts. This represents the first application of lanthanide compounds for the addition of Et2Zn to carbonyl compounds.eng
dc.description.versionpublished
dc.format.mimetypeapplication/pdfdeu
dc.identifier.citationFirst publ. in: Synlett 2002, 11, pp. 1922-1924deu
dc.identifier.doi10.1055/s-2002-34897
dc.identifier.ppn302701435deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/10042
dc.language.isoengdeu
dc.legacy.dateIssued2008deu
dc.rightsAttribution-NonCommercial-NoDerivs 2.0 Generic
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.0/
dc.subjectlanthanidesdeu
dc.subjectceriumdeu
dc.subjectcatalysisdeu
dc.subjectdiethylzincdeu
dc.subjectaddition to carbonylsdeu
dc.subject.ddc540deu
dc.titleCerium(III)-catalyzed addition of diethylzinc to carbonyl compoundseng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Fischer2002Ceriu-10042,
  year={2002},
  doi={10.1055/s-2002-34897},
  title={Cerium(III)-catalyzed addition of diethylzinc to carbonyl compounds},
  number={11},
  volume={2002},
  issn={0936-5214},
  journal={Synlett},
  pages={1922--1924},
  author={Fischer, Stefan and Groth, Ulrich and Jeske, Mario and Schütz, Thorben}
}
kops.citation.iso690FISCHER, Stefan, Ulrich GROTH, Mario JESKE, Thorben SCHÜTZ, 2002. Cerium(III)-catalyzed addition of diethylzinc to carbonyl compounds. In: Synlett. 2002, 2002(11), pp. 1922-1924. ISSN 0936-5214. eISSN 1437-2096. Available under: doi: 10.1055/s-2002-34897deu
kops.citation.iso690FISCHER, Stefan, Ulrich GROTH, Mario JESKE, Thorben SCHÜTZ, 2002. Cerium(III)-catalyzed addition of diethylzinc to carbonyl compounds. In: Synlett. 2002, 2002(11), pp. 1922-1924. ISSN 0936-5214. eISSN 1437-2096. Available under: doi: 10.1055/s-2002-34897eng
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