Publikation:

Cerium(III)-catalyzed addition of diethylzinc to carbonyl compounds

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CeriumIII_catalyzed_addition_of_diethylzinc_to_carbonyl_compounds.pdf
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Datum

2002

Autor:innen

Jeske, Mario
Schütz, Thorben

Herausgeber:innen

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URI (zitierfähiger Link)
http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-46424
DOI (zitierfähiger Link)
https://doi.org/10.1055/s-2002-34897
ArXiv-ID

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Link zur Lizenz
Attribution-NonCommercial-NoDerivs 2.0 Generic

Angaben zur Forschungsförderung

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Open Access-Veröffentlichung
Open Access Green

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Chemie: Publikationen
Core Facility der Universität Konstanz

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Titel in einer weiteren Sprache

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Zeitschriftenartikel
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Published

Erschienen in

Synlett. 2002, 2002(11), pp. 1922-1924. ISSN 0936-5214. eISSN 1437-2096. Available under: doi: 10.1055/s-2002-34897

Zusammenfassung

CeCl3 catalyzes the addition of Et2Zn to a variety of alipahtic and aromatic aldehydes and ketones in THF in the presence of TMSCl as a scavenger. Optimization of the applied solvent allowed to avoid the TMSCl mediated addition using CeCl3·(THF)2 or Ce(i-PrO)3 as catalysts. This represents the first application of lanthanide compounds for the addition of Et2Zn to carbonyl compounds.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

lanthanides, cerium, catalysis, diethylzinc, addition to carbonyls

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ISO 690FISCHER, Stefan, Ulrich GROTH, Mario JESKE, Thorben SCHÜTZ, 2002. Cerium(III)-catalyzed addition of diethylzinc to carbonyl compounds. In: Synlett. 2002, 2002(11), pp. 1922-1924. ISSN 0936-5214. eISSN 1437-2096. Available under: doi: 10.1055/s-2002-34897
BibTex
@article{Fischer2002Ceriu-10042,
  year={2002},
  doi={10.1055/s-2002-34897},
  title={Cerium(III)-catalyzed addition of diethylzinc to carbonyl compounds},
  number={11},
  volume={2002},
  issn={0936-5214},
  journal={Synlett},
  pages={1922--1924},
  author={Fischer, Stefan and Groth, Ulrich and Jeske, Mario and Schütz, Thorben}
}
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