Coordinative Chain Transfer Polymerization of Butadiene with Functionalized Aluminum Reagents
| Type of Publication: | Journal article |
| Publication status: | Published |
| URI (citable link): | http://nbn-resolving.de/urn:nbn:de:bsz:352-2-shdjr7bkxla01 |
| Author: | Goettker-Schnetmann, Inigo; Kenyon, Philip; Mecking, Stefan |
| Year of publication: | 2019 |
| Published in: | Angewandte Chemie International Edition ; 58 (2019), 49. - pp. 17777-17781. - ISSN 1433-7851. - eISSN 1521-3773 |
| Pubmed ID: | 31571376 |
| DOI (citable link): | https://dx.doi.org/10.1002/anie.201909843 |
| Summary: |
Functionalized aluminium alkyls enable an effective coordinative chain transfer polymerization with selective chain initiation by the functionalized alkyl. (ω-aminoalkyl)diisobutyl aluminum reagents (twelve examples studied) obtained by hydroalumination of α-amino-ω-enes with diisobutyl aluminum hydride promote the stereoselective catalytic chain growth of butadiene on aluminum in presence of Nd(versatate)3, Cp*2Nd(allyl) or Cp*2Gd(allyl) precatalysts and [PhNMe2H+]/[B(C6F5)4-]. Carbazolyl- and indolyl- aluminum reagents result in efficient molecular weight control and chain initiation by the aminoalkyl rather than isobutyl substitutent bound to aluminum. As evidenced for (3-(9H-carbazol-9-yl)propyl) initiated polybutadiene (PBD) inter alia by deuterium quenching studies, polymer chain transfer by β-hydride transfer is negligible in comparison to back-transfer to aluminum.
|
| Subject (DDC): | 540 Chemistry |
| Keywords: | Coordinative Chain Transfer Polymerization, Functionalized Chain Transfer Reagents, Aluminum, Neodymium, Polybutadiene |
| Link to License: | In Copyright |
| Bibliography of Konstanz: | Yes |
| Refereed: | Yes |
Cite This
Files in this item
![[PDF]](/themes/Kops/images/mimes/pdf.png "PDF file"){kind=small}
GOETTKER-SCHNETMANN, Inigo, Philip KENYON, Stefan MECKING, 2019. Coordinative Chain Transfer Polymerization of Butadiene with Functionalized Aluminum Reagents. In: Angewandte Chemie International Edition. 58(49), pp. 17777-17781. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.201909843
@article{GoettkerSchnetmann2019-12-02Coord-47282, title={Coordinative Chain Transfer Polymerization of Butadiene with Functionalized Aluminum Reagents}, year={2019}, doi={10.1002/anie.201909843}, number={49}, volume={58}, issn={1433-7851}, journal={Angewandte Chemie International Edition}, pages={17777--17781}, author={Goettker-Schnetmann, Inigo and Kenyon, Philip and Mecking, Stefan} }
<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/47282"> <dcterms:title>Coordinative Chain Transfer Polymerization of Butadiene with Functionalized Aluminum Reagents</dcterms:title> <dc:contributor>Goettker-Schnetmann, Inigo</dc:contributor> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/47282/1/Goettker-Schnetmann_2-shdjr7bkxla01.pdf"/> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/> <dc:language>eng</dc:language> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dc:rights>terms-of-use</dc:rights> <dc:contributor>Mecking, Stefan</dc:contributor> <dc:contributor>Kenyon, Philip</dc:contributor> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dc:creator>Kenyon, Philip</dc:creator> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2019-10-22T11:08:37Z</dc:date> <dc:creator>Mecking, Stefan</dc:creator> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2019-10-22T11:08:37Z</dcterms:available> <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/47282"/> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/47282/1/Goettker-Schnetmann_2-shdjr7bkxla01.pdf"/> <dcterms:abstract xml:lang="eng">Functionalized aluminium alkyls enable an effective coordinative chain transfer polymerization with selective chain initiation by the functionalized alkyl. (ω-aminoalkyl)diisobutyl aluminum reagents (twelve examples studied) obtained by hydroalumination of α-amino-ω-enes with diisobutyl aluminum hydride promote the stereoselective catalytic chain growth of butadiene on aluminum in presence of Nd(versatate)3, Cp*2Nd(allyl) or Cp*2Gd(allyl) precatalysts and [PhNMe2H+]/[B(C6F5)4-]. Carbazolyl- and indolyl- aluminum reagents result in efficient molecular weight control and chain initiation by the aminoalkyl rather than isobutyl substitutent bound to aluminum. As evidenced for (3-(9H-carbazol-9-yl)propyl) initiated polybutadiene (PBD) inter alia by deuterium quenching studies, polymer chain transfer by β-hydride transfer is negligible in comparison to back-transfer to aluminum.</dcterms:abstract> <dc:creator>Goettker-Schnetmann, Inigo</dc:creator> <dcterms:issued>2019-12-02</dcterms:issued> </rdf:Description> </rdf:RDF>
Downloads since Oct 22, 2019 (Information about access statistics)
| Goettker-Schnetmann_2-shdjr7bkxla01.pdf | 79 |
This item appears in the following Collection(s)
Search KOPS
Browse
My Account
