@article{Ferentinos2018FeSeP-42277,
  year={2018},
  doi={10.1002/ejic.201701459},
  title={The [Fe{(SePPh<sub>2</sub>)<sub>2</sub>N}<sub>2</sub>] Complex Revisited : X‐ray Crystallography, Magnetometry, High‐Frequency EPR, and Mössbauer Studies Reveal Its Tetrahedral Fe<sup>II</sup>Se<sub>4</sub> Coordination Sphere},
  number={6},
  volume={2018},
  issn={1434-1948},
  journal={European Journal of Inorganic Chemistry},
  pages={713--721},
  author={Ferentinos, Eleftherios and Chatziefthimiou, Spyros and Boudalis, Athanassios K. and Pissas, Michael and Mathies, Guinevere and Gast, Peter and Groenen, Edgar J. J. and Sanakis, Yiannis and Kyritsis, Panayotis}
}

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    <dc:contributor>Sanakis, Yiannis</dc:contributor>
    <dc:creator>Mathies, Guinevere</dc:creator>
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    <dcterms:title>The [Fe{(SePPh&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;N}&lt;sub&gt;2&lt;/sub&gt;] Complex Revisited : X‐ray Crystallography, Magnetometry, High‐Frequency EPR, and Mössbauer Studies Reveal Its Tetrahedral Fe&lt;sup&gt;II&lt;/sup&gt;Se&lt;sub&gt;4&lt;/sub&gt; Coordination Sphere</dcterms:title>
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    <dc:contributor>Chatziefthimiou, Spyros</dc:contributor>
    <dc:creator>Chatziefthimiou, Spyros</dc:creator>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2018-05-09T08:52:10Z</dc:date>
    <dc:contributor>Kyritsis, Panayotis</dc:contributor>
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    <dc:language>eng</dc:language>
    <dc:creator>Sanakis, Yiannis</dc:creator>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/42277"/>
    <dc:creator>Boudalis, Athanassios K.</dc:creator>
    <dc:contributor>Pissas, Michael</dc:contributor>
    <dc:contributor>Ferentinos, Eleftherios</dc:contributor>
    <dcterms:issued>2018</dcterms:issued>
    <dc:contributor>Gast, Peter</dc:contributor>
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    <dc:creator>Ferentinos, Eleftherios</dc:creator>
    <dc:rights>terms-of-use</dc:rights>
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    <dc:creator>Kyritsis, Panayotis</dc:creator>
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    <dc:contributor>Mathies, Guinevere</dc:contributor>
    <dc:creator>Groenen, Edgar J. J.</dc:creator>
    <dc:creator>Pissas, Michael</dc:creator>
    <dc:contributor>Boudalis, Athanassios K.</dc:contributor>
    <dcterms:abstract xml:lang="eng">The synthesis and characterization of complex [Fe{(SePPh&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;N}&lt;sub&gt;2&lt;/sub&gt;] (1) is described. X-ray crystallography shows that this system contains a tetrahedral FeSe&lt;sub&gt;4&lt;/sub&gt; coordination sphere. The structural features of 1 are compared with those of similar first row transition element complexes, including a recently reported preparation of [Fe{(SePPh&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;N}&lt;sub&gt;2&lt;/sub&gt;] (1&lt;sub&gt;SP&lt;/sub&gt;) exhibiting a highly unusual square planar FeSe&lt;sub&gt;4&lt;/sub&gt; coordination sphere. The electronic structure of 1 was elucidated by magnetometry, high-frequency EPR, and Mössbauer spectroscopic studies, which reveal zero-field splitting (ZFS) parameters typical of high spin S = 2 tetrahedral Fe&lt;sup&gt;II&lt;/sup&gt; sites. Accurate ZFS parameters (D = +8.22 cm&lt;sup&gt;–1&lt;/sup&gt;, E/D = 0.104) were obtained by analysis of the EPR spectra and compared with those of the analogous [Fe{(SePPh&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;N}&lt;sub&gt;2&lt;/sub&gt;] complex.</dcterms:abstract>
    <dc:contributor>Groenen, Edgar J. J.</dc:contributor>
    <dc:creator>Gast, Peter</dc:creator>
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