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The [Fe{(SePPh : The [Fe{(SePPh2)2N}2] Complex Revisited: X-ray Crystallography, Magnetometry, High-Frequency EPR, and Mössbauer Studies Reveal Its Tetrahedral FeIISe4

The [Fe{(SePPh : The [Fe{(SePPh2)2N}2] Complex Revisited: X-ray Crystallography, Magnetometry, High-Frequency EPR, and Mössbauer Studies Reveal Its Tetrahedral FeIISe4

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FERENTINOS, Eleftherios, Spyros CHATZIEFTHIMIOU, Athanassios K. BOUDALIS, Michael PISSAS, Guinevere MATHIES, Peter GAST, Edgar J. J. GROENEN, Yiannis SANAKIS, Panayotis KYRITSIS, 2018. The [Fe{(SePPh : The [Fe{(SePPh2)2N}2] Complex Revisited: X-ray Crystallography, Magnetometry, High-Frequency EPR, and Mössbauer Studies Reveal Its Tetrahedral FeIISe4. In: European Journal of Inorganic Chemistry. 2018(6), pp. 713-721. ISSN 1434-1948. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201701459

@article{Ferentinos2018FeSeP-42277, title={The [Fe(SePPh : The [Fe(SePPh2)2N2] Complex Revisited: X-ray Crystallography, Magnetometry, High-Frequency EPR, and Mössbauer Studies Reveal Its Tetrahedral FeIISe4}, year={2018}, doi={10.1002/ejic.201701459}, number={6}, volume={2018}, issn={1434-1948}, journal={European Journal of Inorganic Chemistry}, pages={713--721}, author={Ferentinos, Eleftherios and Chatziefthimiou, Spyros and Boudalis, Athanassios K. and Pissas, Michael and Mathies, Guinevere and Gast, Peter and Groenen, Edgar J. J. and Sanakis, Yiannis and Kyritsis, Panayotis} }

<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/42277"> <dc:creator>Mathies, Guinevere</dc:creator> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dc:creator>Sanakis, Yiannis</dc:creator> <dc:creator>Chatziefthimiou, Spyros</dc:creator> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2018-05-09T08:52:10Z</dcterms:available> <dc:contributor>Boudalis, Athanassios K.</dc:contributor> <dc:contributor>Ferentinos, Eleftherios</dc:contributor> <dc:creator>Kyritsis, Panayotis</dc:creator> <dc:contributor>Kyritsis, Panayotis</dc:contributor> <dc:creator>Gast, Peter</dc:creator> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2018-05-09T08:52:10Z</dc:date> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dcterms:issued>2018</dcterms:issued> <dc:creator>Pissas, Michael</dc:creator> <dc:contributor>Chatziefthimiou, Spyros</dc:contributor> <dc:contributor>Groenen, Edgar J. J.</dc:contributor> <dc:language>eng</dc:language> <dc:contributor>Pissas, Michael</dc:contributor> <dc:contributor>Mathies, Guinevere</dc:contributor> <dc:creator>Groenen, Edgar J. J.</dc:creator> <dc:contributor>Sanakis, Yiannis</dc:contributor> <dcterms:title>The [Fe{(SePPh : The [Fe{(SePPh2)2N}2] Complex Revisited: X-ray Crystallography, Magnetometry, High-Frequency EPR, and Mössbauer Studies Reveal Its Tetrahedral FeIISe4</dcterms:title> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dc:creator>Boudalis, Athanassios K.</dc:creator> <dc:creator>Ferentinos, Eleftherios</dc:creator> <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/42277"/> <dcterms:abstract xml:lang="eng">The synthesis and characterization of complex [Fe{(SePPh2)2N}2] (1) is described. X‐ray crystallography shows that this system contains a tetrahedral FeSe4 coordination sphere. The structural features of 1 are compared with those of similar first row transition element complexes, including a recently reported preparation of [Fe{(SePPh2)2N}2] (1SP) exhibiting a highly unusual square planar FeSe4 coordination sphere. The electronic structure of 1 was elucidated by magnetometry, high‐frequency EPR, and Mössbauer spectroscopic studies, which reveal zero‐field splitting (ZFS) parameters typical of high spin S = 2 tetrahedral FeII sites. Accurate ZFS parameters (D = +8.22 cm–1, E/D = 0.104) were obtained by analysis of the EPR spectra and compared with those of the analogous [Fe{(SPPh2)2N}2] complex.</dcterms:abstract> <dc:contributor>Gast, Peter</dc:contributor> </rdf:Description> </rdf:RDF>

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