Aufgrund von Vorbereitungen auf eine neue Version von KOPS, können kommenden Montag und Dienstag keine Publikationen eingereicht werden. (Due to preparations for a new version of KOPS, no publications can be submitted next Monday and Tuesday.)
Type of Publication: | Journal article |
Publication status: | Published |
Author: | Zhang, Xinxing; Wang, Linjie; Montone, Georgia R.; Gill, Ann F; Ganteför, Gerd; Eichhorn, Bryan; Kandalam, Anil K.; Bowen, Kit H |
Year of publication: | 2017 |
Published in: | Physical Chemistry Chemical Physics ; 19 (2017), 23. - pp. 15541-15548. - ISSN 1463-9076. - eISSN 1463-9084 |
DOI (citable link): | https://dx.doi.org/10.1039/C7CP01560G |
Summary: |
Several low oxidation state aluminum-containing cluster anions, LAlH− and LAln− (n = 2–4, L = N[Si(Me)3]2), were produced via reactions between aluminum hydride cluster anions, AlxHy−, and hexamethyldisilazane (HMDS). These clusters were characterized by mass spectrometry, anion photoelectron spectroscopy, and density functional theory (DFT) based calculations. Agreement between the experimental and theoretical vertical detachment energies (VDEs) and adiabatic detachment energies (ADEs) validated the computed geometrical structures. Reactions between aluminum hydride cluster anions and ligands promise to be a new synthetic scheme for low oxidation state, ligated aluminum clusters.
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Subject (DDC): | 530 Physics |
Bibliography of Konstanz: | Yes |
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ZHANG, Xinxing, Linjie WANG, Georgia R. MONTONE, Ann F GILL, Gerd GANTEFÖR, Bryan EICHHORN, Anil K. KANDALAM, Kit H BOWEN, 2017. Low oxidation state aluminum-containing cluster anions : LAlH− and LAln− (n = 2–4, L = N[Si(Me)3]2). In: Physical Chemistry Chemical Physics. 19(23), pp. 15541-15548. ISSN 1463-9076. eISSN 1463-9084. Available under: doi: 10.1039/C7CP01560G
@article{Zhang2017oxida-41742, title={Low oxidation state aluminum-containing cluster anions : LAlH− and LAln− (n = 2–4, L = N[Si(Me)3]2)}, year={2017}, doi={10.1039/C7CP01560G}, number={23}, volume={19}, issn={1463-9076}, journal={Physical Chemistry Chemical Physics}, pages={15541--15548}, author={Zhang, Xinxing and Wang, Linjie and Montone, Georgia R. and Gill, Ann F and Ganteför, Gerd and Eichhorn, Bryan and Kandalam, Anil K. and Bowen, Kit H} }