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Low oxidation state aluminum-containing cluster anions : LAlH− and LAl<sub>n</sub>− (n = 2–4, L = N[Si(Me)<sub>3</sub>]<sub>2</sub>)

Low oxidation state aluminum-containing cluster anions : LAlH− and LAln− (n = 2–4, L = N[Si(Me)3]2)

Type of Publication: Journal article
Publication status: Published
Author: Zhang, Xinxing; Wang, Linjie; Montone, Georgia R.; Gill, Ann F; Ganteför, Gerd; Eichhorn, Bryan; Kandalam, Anil K.; Bowen, Kit H
Year of publication: 2017
Published in: Physical Chemistry Chemical Physics ; 19 (2017), 23. - pp. 15541-15548. - ISSN 1463-9076. - eISSN 1463-9084
DOI (citable link): https://dx.doi.org/10.1039/C7CP01560G
Summary:
Several low oxidation state aluminum-containing cluster anions, LAlH− and LAln− (n = 2–4, L = N[Si(Me)3]2), were produced via reactions between aluminum hydride cluster anions, AlxHy−, and hexamethyldisilazane (HMDS). These clusters were characterized by mass spectrometry, anion photoelectron spectroscopy, and density functional theory (DFT) based calculations. Agreement between the experimental and theoretical vertical detachment energies (VDEs) and adiabatic detachment energies (ADEs) validated the computed geometrical structures. Reactions between aluminum hydride cluster anions and ligands promise to be a new synthetic scheme for low oxidation state, ligated aluminum clusters.
Subject (DDC): 530 Physics
Bibliography of Konstanz: Yes

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ZHANG, Xinxing, Linjie WANG, Georgia R. MONTONE, Ann F GILL, Gerd GANTEFÖR, Bryan EICHHORN, Anil K. KANDALAM, Kit H BOWEN, 2017. Low oxidation state aluminum-containing cluster anions : LAlH− and LAln− (n = 2–4, L = N[Si(Me)3]2). In: Physical Chemistry Chemical Physics. 19(23), pp. 15541-15548. ISSN 1463-9076. eISSN 1463-9084. Available under: doi: 10.1039/C7CP01560G

@article{Zhang2017oxida-41742, title={Low oxidation state aluminum-containing cluster anions : LAlH− and LAln− (n = 2–4, L = N[Si(Me)3]2)}, year={2017}, doi={10.1039/C7CP01560G}, number={23}, volume={19}, issn={1463-9076}, journal={Physical Chemistry Chemical Physics}, pages={15541--15548}, author={Zhang, Xinxing and Wang, Linjie and Montone, Georgia R. and Gill, Ann F and Ganteför, Gerd and Eichhorn, Bryan and Kandalam, Anil K. and Bowen, Kit H} }

Eichhorn, Bryan Ganteför, Gerd Wang, Linjie Several low oxidation state aluminum-containing cluster anions, LAlH− and LAl<sub>n</sub>− (n = 2–4, L = N[Si(Me)<sub>3</sub>]<sub>2</sub>), were produced via reactions between aluminum hydride cluster anions, Al<sub>x</sub>H<sub>y</sub>−, and hexamethyldisilazane (HMDS). These clusters were characterized by mass spectrometry, anion photoelectron spectroscopy, and density functional theory (DFT) based calculations. Agreement between the experimental and theoretical vertical detachment energies (VDEs) and adiabatic detachment energies (ADEs) validated the computed geometrical structures. Reactions between aluminum hydride cluster anions and ligands promise to be a new synthetic scheme for low oxidation state, ligated aluminum clusters. Gill, Ann F Montone, Georgia R. Zhang, Xinxing Low oxidation state aluminum-containing cluster anions : LAlH− and LAl<sub>n</sub>− (n = 2–4, L = N[Si(Me)<sub>3</sub>]<sub>2</sub>) Eichhorn, Bryan Montone, Georgia R. Wang, Linjie 2018-03-09T13:57:12Z eng Ganteför, Gerd Bowen, Kit H Kandalam, Anil K. 2017 Kandalam, Anil K. Bowen, Kit H Gill, Ann F 2018-03-09T13:57:12Z Zhang, Xinxing

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