KOPS - The Institutional Repository of the University of Konstanz

Synergetic Effect of Monomer Functional Group Coordination in Catalytic Insertion Polymerization

Synergetic Effect of Monomer Functional Group Coordination in Catalytic Insertion Polymerization

Cite This

Files in this item

Files Size Format View

There are no files associated with this item.

LEICHT, Hannes, Inigo GÖTTKER-SCHNETMANN, Stefan MECKING, 2017. Synergetic Effect of Monomer Functional Group Coordination in Catalytic Insertion Polymerization. In: Journal of the American Chemical Society : JACS. 139(20), pp. 6823-6826. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/jacs.7b03087

@article{Leicht2017-05-24Syner-39106, title={Synergetic Effect of Monomer Functional Group Coordination in Catalytic Insertion Polymerization}, year={2017}, doi={10.1021/jacs.7b03087}, number={20}, volume={139}, issn={0002-7863}, journal={Journal of the American Chemical Society : JACS}, pages={6823--6826}, author={Leicht, Hannes and Göttker-Schnetmann, Inigo and Mecking, Stefan} }

<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/39106"> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2017-06-01T09:50:23Z</dcterms:available> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dc:contributor>Göttker-Schnetmann, Inigo</dc:contributor> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2017-06-01T09:50:23Z</dc:date> <dc:creator>Mecking, Stefan</dc:creator> <dc:contributor>Mecking, Stefan</dc:contributor> <dc:creator>Leicht, Hannes</dc:creator> <dc:contributor>Leicht, Hannes</dc:contributor> <dc:language>eng</dc:language> <dcterms:title>Synergetic Effect of Monomer Functional Group Coordination in Catalytic Insertion Polymerization</dcterms:title> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dcterms:issued>2017-05-24</dcterms:issued> <dcterms:abstract xml:lang="eng">PhS- and PhNH-functionalized dienes are copolymerized efficiently with butadiene to stereoregular copolymers by [(mesitylene)Ni(allyl)][BAr(F)4] (Ni-1). Overall polymerization rates and comonomer incorporations depend strongly on the linker length between the diene moiety and functional group, in, e.g., PhS-(CH2)xC(═CH2)-CH═CH2 (PhS-x-BD, x = 3-7), in particular for certain linker lengths high comonomer reactivity ratios stand out. This effect is related to a favorable binding of the comonomer to the active site comprising coordination of its functional group, which significantly enhances comonomer incorporation in the growing polymer chain.</dcterms:abstract> <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/39106"/> <dc:creator>Göttker-Schnetmann, Inigo</dc:creator> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> </rdf:Description> </rdf:RDF>

This item appears in the following Collection(s)

Search KOPS


Browse

My Account