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Cytotoxic heteroleptic heptacoordinate salan zirconium(IV)-bis-chelates : synthesis, aqueous stability and X-ray structure analysis

Cytotoxic heteroleptic heptacoordinate salan zirconium(IV)-bis-chelates : synthesis, aqueous stability and X-ray structure analysis

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Prüfsumme: MD5:c2aeb68a8d5b2977ddfe166bfe4a622d

SCHNEIDER, Fabian, Tiankun ZHAO, Thomas HUHN, 2016. Cytotoxic heteroleptic heptacoordinate salan zirconium(IV)-bis-chelates : synthesis, aqueous stability and X-ray structure analysis. In: Chemical Communications : ChemComm. 52(66), pp. 10151-10154. ISSN 1359-7345. eISSN 1364-548X

@article{Schneider2016Cytot-37041, title={Cytotoxic heteroleptic heptacoordinate salan zirconium(IV)-bis-chelates : synthesis, aqueous stability and X-ray structure analysis}, year={2016}, doi={10.1039/C6CC05359A}, number={66}, volume={52}, issn={1359-7345}, journal={Chemical Communications : ChemComm}, pages={10151--10154}, author={Schneider, Fabian and Zhao, Tiankun and Huhn, Thomas} }

2016 Zhao, Tiankun Huhn, Thomas Zhao, Tiankun 2017-02-01T08:28:30Z Herein we report the synthesis and structural characterization of a series of novel Zr(IV)salan complexes. The initial metalation product [(L1)<sub>2</sub>Zr] is highly water sensitive while ligand exchanged [L1Zr(dipic)] hydrolyses slowly with a bis-hydroxo Zr(IV) species identified by MS as an intermediate. [L1Zr(dipic)] is cytotoxic in the range of cisplatin against two human carcinoma cell lines. 2017-02-01T08:28:30Z Schneider, Fabian Schneider, Fabian eng Cytotoxic heteroleptic heptacoordinate salan zirconium(IV)-bis-chelates : synthesis, aqueous stability and X-ray structure analysis Huhn, Thomas

Dateiabrufe seit 01.02.2017 (Informationen über die Zugriffsstatistik)

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