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Low oxidation state aluminum-containing cluster anions: Cp<sup>∗</sup>Al<sub>n</sub>H<sup>−</sup>, n = 1–3

Low oxidation state aluminum-containing cluster anions: CpAlnH, n = 1–3

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ZHANG, Xinxing, Gerd GANTEFÖR, Bryan EICHHORN, Dennis MAYO, William H SAWYER, Ann F GILL, Anil K. KANDALAM, Hansgeorg SCHNÖCKEL, Kit BOWEN, 2016. Low oxidation state aluminum-containing cluster anions: CpAlnH, n = 1–3. In: The Journal of Chemical Physics. 145(7), 074305. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4959847

@article{Zhang2016oxida-36947, title={Low oxidation state aluminum-containing cluster anions: CpAlnH, n = 1–3}, year={2016}, doi={10.1063/1.4959847}, number={7}, volume={145}, issn={0021-9606}, journal={The Journal of Chemical Physics}, author={Zhang, Xinxing and Ganteför, Gerd and Eichhorn, Bryan and Mayo, Dennis and Sawyer, William H and Gill, Ann F and Kandalam, Anil K. and Schnöckel, Hansgeorg and Bowen, Kit}, note={Article Number: 074305} }

Ganteför, Gerd Schnöckel, Hansgeorg Three new, low oxidation state, aluminum-containing cluster anions, Cp*AlnH(-), n = 1-3, were prepared via reactions between aluminum hydride cluster anions, AlnHm (-), and Cp*H ligands. These were characterized by mass spectrometry, anion photoelectron spectroscopy, and density functional theory based calculations. Agreement between the experimentally and theoretically determined vertical detachment energies and adiabatic detachment energies validated the computed geometrical structures. Reactions between aluminum hydride cluster anions and ligands provide a new avenue for discovering low oxidation state, ligated aluminum clusters. Eichhorn, Bryan 2016 2017-01-25T10:50:01Z Mayo, Dennis Zhang, Xinxing Bowen, Kit Low oxidation state aluminum-containing cluster anions: Cp<sup>∗</sup>Al<sub>n</sub>H<sup>−</sup>, n = 1–3 eng 2017-01-25T10:50:01Z Gill, Ann F Gill, Ann F Zhang, Xinxing Kandalam, Anil K. Eichhorn, Bryan Mayo, Dennis Kandalam, Anil K. Ganteför, Gerd Sawyer, William H Sawyer, William H Schnöckel, Hansgeorg Bowen, Kit

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