Publikation:

A CaCO3/nanocellulose-based bioinspired nacre-like material

Vorschaubild

Dateien

Farhadi_0-393911.pdf
Farhadi_0-393911.pdfGröße: 630.29 KBDownloads: 522

Datum

2017

Autor:innen

Farhadi-Khouzani, Masoud
Schütz, Christina
Durak, Grazyna Malgorzata
Fornell, Jordina
Sort, Jordi
Salazar-Alvarez, Germán
Bergström, Lennart
Gebauer, Denis

Herausgeber:innen

Kontakt

ISSN der Zeitschrift

Electronic ISSN

ISBN

Bibliografische Daten

Verlag

Schriftenreihe

Auflagebezeichnung

URI (zitierfähiger Link)
http://nbn-resolving.de/urn:nbn:de:bsz:352-0-393911
DOI (zitierfähiger Link)
https://doi.org/10.1039/C6TA09524K
ArXiv-ID

Internationale Patentnummer

Link zur Lizenz
Attribution 3.0 Unported

Angaben zur Forschungsförderung

Projekt

Open Access-Veröffentlichung
Open Access Hybrid

Sammlungen

Chemie: Publikationen
Zukunftskolleg: Publikationen
Core Facility der Universität Konstanz

Gesperrt bis

Titel in einer weiteren Sprache

Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published

Erschienen in

Journal of Materials Chemistry A. 2017, 5(31), pp. 16128-16133. ISSN 2050-7488. eISSN 2050-7496. Available under: doi: 10.1039/C6TA09524K

Zusammenfassung

Nacre continues to be an inspiration for the fabrication of strong and tough materials from renewable and earth-abundant raw materials. Herein, we showed how a nacre-like hybrid material based on nanocellulose (NC) and CaCO3 can be prepared via the sequential infiltration of polymer-stabilised CaCO3 liquid precursors into layers of pre-deposited NC films. Layer-by-layer assembly of the NC films followed by controlled spreading and infiltration with liquid CaCO3 precursors generated a lamellar material with an architecture and iridescent appearance similar to those of nacre. The wettability of the NC films towards the liquid CaCO3 precursors was controlled by hydroxyl and carboxyl functionalization of the NC fibrils and the addition of magnesium ions. The combination of a high stiffness and plasticity of the nacre-like NC/CaCO3 hybrid materials show that excellent mechanical properties can be obtained employing a fibrillar organic constituent that is relatively hard. The fabrication of a nacre-like hybrid material via an aqueous route of assembly and infiltration processing demonstrates how a sustainable composite material with outstanding properties can be produced using the most abundant biopolymer and biomineral on earth.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

Konferenz

Rezension
undefined / . - undefined, undefined

Forschungsvorhaben

Organisationseinheiten

Zeitschriftenheft

Zugehörige Datensätze in KOPS

Zitieren

ISO 690FARHADI-KHOUZANI, Masoud, Christina SCHÜTZ, Grazyna Malgorzata DURAK, Jordina FORNELL, Jordi SORT, Germán SALAZAR-ALVAREZ, Lennart BERGSTRÖM, Denis GEBAUER, 2017. A CaCO3/nanocellulose-based bioinspired nacre-like material. In: Journal of Materials Chemistry A. 2017, 5(31), pp. 16128-16133. ISSN 2050-7488. eISSN 2050-7496. Available under: doi: 10.1039/C6TA09524K
BibTex
@article{FarhadiKhouzani2017nanoc-37685,
  year={2017},
  doi={10.1039/C6TA09524K},
  title={A CaCO<sub>3</sub>/nanocellulose-based bioinspired nacre-like material},
  number={31},
  volume={5},
  issn={2050-7488},
  journal={Journal of Materials Chemistry A},
  pages={16128--16133},
  author={Farhadi-Khouzani, Masoud and Schütz, Christina and Durak, Grazyna Malgorzata and Fornell, Jordina and Sort, Jordi and Salazar-Alvarez, Germán and Bergström, Lennart and Gebauer, Denis}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/37685">
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/37685"/>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dcterms:rights rdf:resource="http://creativecommons.org/licenses/by/3.0/"/>
    <dc:contributor>Gebauer, Denis</dc:contributor>
    <dcterms:title>A CaCO&lt;sub&gt;3&lt;/sub&gt;/nanocellulose-based bioinspired nacre-like material</dcterms:title>
    <dc:creator>Sort, Jordi</dc:creator>
    <dcterms:issued>2017</dcterms:issued>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dc:contributor>Salazar-Alvarez, Germán</dc:contributor>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/52"/>
    <dc:contributor>Schütz, Christina</dc:contributor>
    <dc:contributor>Durak, Grazyna Malgorzata</dc:contributor>
    <dc:creator>Farhadi-Khouzani, Masoud</dc:creator>
    <dc:contributor>Bergström, Lennart</dc:contributor>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/37685/1/Farhadi_0-393911.pdf"/>
    <dc:creator>Fornell, Jordina</dc:creator>
    <dc:rights>Attribution 3.0 Unported</dc:rights>
    <dc:language>eng</dc:language>
    <dc:contributor>Fornell, Jordina</dc:contributor>
    <dc:creator>Schütz, Christina</dc:creator>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/52"/>
    <dc:contributor>Farhadi-Khouzani, Masoud</dc:contributor>
    <dcterms:abstract xml:lang="eng">Nacre continues to be an inspiration for the fabrication of strong and tough materials from renewable and earth-abundant raw materials. Herein, we showed how a nacre-like hybrid material based on nanocellulose (NC) and CaCO&lt;sub&gt;3&lt;/sub&gt; can be prepared via the sequential infiltration of polymer-stabilised CaCO&lt;sub&gt;3&lt;/sub&gt; liquid precursors into layers of pre-deposited NC films. Layer-by-layer assembly of the NC films followed by controlled spreading and infiltration with liquid CaCO&lt;sub&gt;3&lt;/sub&gt; precursors generated a lamellar material with an architecture and iridescent appearance similar to those of nacre. The wettability of the NC films towards the liquid CaCO&lt;sub&gt;3&lt;/sub&gt; precursors was controlled by hydroxyl and carboxyl functionalization of the NC fibrils and the addition of magnesium ions. The combination of a high stiffness and plasticity of the nacre-like NC/CaCO&lt;sub&gt;3&lt;/sub&gt; hybrid materials show that excellent mechanical properties can be obtained employing a fibrillar organic constituent that is relatively hard. The fabrication of a nacre-like hybrid material via an aqueous route of assembly and infiltration processing demonstrates how a sustainable composite material with outstanding properties can be produced using the most abundant biopolymer and biomineral on earth.</dcterms:abstract>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dc:creator>Bergström, Lennart</dc:creator>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/37685/1/Farhadi_0-393911.pdf"/>
    <dc:creator>Durak, Grazyna Malgorzata</dc:creator>
    <dc:creator>Salazar-Alvarez, Germán</dc:creator>
    <dc:creator>Gebauer, Denis</dc:creator>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2017-02-22T15:30:24Z</dc:date>
    <dc:contributor>Sort, Jordi</dc:contributor>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2017-02-22T15:30:24Z</dcterms:available>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
  </rdf:Description>
</rdf:RDF>

Interner Vermerk

xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter

Kontakt
URL der Originalveröffentl.

Prüfdatum der URL

Prüfungsdatum der Dissertation

Finanzierungsart

Kommentar zur Publikation

Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
Begutachtet
Diese Publikation teilen