In search of four-atom chiral metal clusters

dc.contributor.authorZhang, Xinxingdeu
dc.contributor.authorVisser, Bradleydeu
dc.contributor.authorTschurl, Martindeu
dc.contributor.authorCollins, Evandeu
dc.contributor.authorWang, Yideu
dc.contributor.authorWang, Qiandeu
dc.contributor.authorLi, Yaweideu
dc.contributor.authorSun, Qiangdeu
dc.contributor.authorJena, Purudeu
dc.contributor.authorGanteför, Gerd
dc.contributor.authorBoesl, Ulrichdeu
dc.contributor.authorHeiz, Ulrichdeu
dc.contributor.authorBowen, Kitdeu
dc.date.accessioned2014-03-19T14:47:02Zdeu
dc.date.available2014-03-19T14:47:02Zdeu
dc.date.issued2013-09-21
dc.description.abstractA combined study utilizing anion photoelectron spectroscopy and density functional theory was conducted to search for four-atom, chiral, metal, and mostly metal clusters. The clusters considered were AuCoMnBi−/0, AlAuMnO−/0, AgMnOAl−/0, and AuAlPtAg−/0, where the superscripts, −/0, refer to anionic and neutral cluster species, respectively. Based on the agreement of experimentally and theoretically determined values of both electron affinities and vertical detachment energies, the calculated cluster geometries were validated and examined for chirality. Among both anionic and neutral clusters, five structures were identified as being chiral.eng
dc.description.versionpublished
dc.identifier.citationThe Journal of Chemical Physics ; 139 (2013). - 111101deu
dc.identifier.doi10.1063/1.4821766deu
dc.identifier.pmid24070270
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/27157
dc.language.isoengdeu
dc.legacy.dateIssued2014-03-19deu
dc.rightsterms-of-usedeu
dc.rights.urihttps://rightsstatements.org/page/InC/1.0/deu
dc.subject.ddc530deu
dc.titleIn search of four-atom chiral metal clusterseng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Zhang2013-09-21searc-27157,
  year={2013},
  doi={10.1063/1.4821766},
  title={In search of four-atom chiral metal clusters},
  number={11},
  volume={139},
  issn={0021-9606},
  journal={The Journal of Chemical Physics},
  author={Zhang, Xinxing and Visser, Bradley and Tschurl, Martin and Collins, Evan and Wang, Yi and Wang, Qian and Li, Yawei and Sun, Qiang and Jena, Puru and Ganteför, Gerd and Boesl, Ulrich and Heiz, Ulrich and Bowen, Kit},
  note={Article Number: 111101}
}
kops.citation.iso690ZHANG, Xinxing, Bradley VISSER, Martin TSCHURL, Evan COLLINS, Yi WANG, Qian WANG, Yawei LI, Qiang SUN, Puru JENA, Gerd GANTEFÖR, Ulrich BOESL, Ulrich HEIZ, Kit BOWEN, 2013. In search of four-atom chiral metal clusters. In: The Journal of Chemical Physics. 2013, 139(11), 111101. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4821766deu
kops.citation.iso690ZHANG, Xinxing, Bradley VISSER, Martin TSCHURL, Evan COLLINS, Yi WANG, Qian WANG, Yawei LI, Qiang SUN, Puru JENA, Gerd GANTEFÖR, Ulrich BOESL, Ulrich HEIZ, Kit BOWEN, 2013. In search of four-atom chiral metal clusters. In: The Journal of Chemical Physics. 2013, 139(11), 111101. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4821766eng
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    <dcterms:abstract xml:lang="eng">A combined study utilizing anion photoelectron spectroscopy and density functional theory was conducted to search for four-atom, chiral, metal, and mostly metal clusters. The clusters considered were AuCoMnBi−/0, AlAuMnO−/0, AgMnOAl−/0, and AuAlPtAg−/0, where the superscripts, −/0, refer to anionic and neutral cluster species, respectively. Based on the agreement of experimentally and theoretically determined values of both electron affinities and vertical detachment energies, the calculated cluster geometries were validated and examined for chirality. Among both anionic and neutral clusters, five structures were identified as being chiral.</dcterms:abstract>
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kops.sourcefieldThe Journal of Chemical Physics. 2013, <b>139</b>(11), 111101. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4821766deu
kops.sourcefield.plainThe Journal of Chemical Physics. 2013, 139(11), 111101. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4821766deu
kops.sourcefield.plainThe Journal of Chemical Physics. 2013, 139(11), 111101. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4821766eng
kops.submitter.emailregina.fleischmann@uni-konstanz.dedeu
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source.identifier.eissn1089-7690
source.identifier.issn0021-9606
source.periodicalTitleThe Journal of Chemical Physics

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