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Photoelectron spectroscopy of boron aluminum hydride cluster anions

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2014

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Wang, Haopeng
Zhang, Xinxing
Ko, Yeon Jae
Bowen, Kit H.
Li, Xiang
Kiran, Boggavarapu
Kandalam, Anil K.

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https://doi.org/10.1063/1.4871884
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The Journal of Chemical Physics. 2014, 140(16), 164317. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4871884

Zusammenfassung

Boron aluminum hydride clusters are studied through a synergetic combination of anion photoelectron spectroscopy and density functional theory based calculations. Boron aluminum hydride cluster anions, BxAlyHz-, were generated in a pulsed arc cluster ionization source and identified by time-of-flight mass spectrometry. After mass selection, their photoelectron spectra were measured by a magnetic bottle-type electron energy analyzer. The resultant photoelectron spectra as well as calculations on a selected series of stoichiometries reveal significant geometrical changes upon substitution of aluminum atoms by boron atoms.

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ISO 690WANG, Haopeng, Xinxing ZHANG, Yeon Jae KO, Gerd GANTEFÖR, Kit H. BOWEN, Xiang LI, Boggavarapu KIRAN, Anil K. KANDALAM, 2014. Photoelectron spectroscopy of boron aluminum hydride cluster anions. In: The Journal of Chemical Physics. 2014, 140(16), 164317. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4871884
BibTex
@article{Wang2014Photo-30940,
  year={2014},
  doi={10.1063/1.4871884},
  title={Photoelectron spectroscopy of boron aluminum hydride cluster anions},
  number={16},
  volume={140},
  issn={0021-9606},
  journal={The Journal of Chemical Physics},
  author={Wang, Haopeng and Zhang, Xinxing and Ko, Yeon Jae and Ganteför, Gerd and Bowen, Kit H. and Li, Xiang and Kiran, Boggavarapu and Kandalam, Anil K.},
  note={Article Number: 164317}
}
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