Publikation: One-dimensional (Mo3S3)n clusters : building blocks of clusters materials and ideal nanowires for molecular electronics
Lade...
Dateien
Datum
2009
Autor:innen
Herausgeber:innen
ISSN der Zeitschrift
Electronic ISSN
ISBN
Bibliografische Daten
Verlag
Schriftenreihe
Auflagebezeichnung
URI (zitierfähiger Link)
DOI (zitierfähiger Link)
Internationale Patentnummer
Link zur Lizenz
Angaben zur Forschungsförderung
Projekt
Open Access-Veröffentlichung
Open Access Green
Sammlungen
Core Facility der Universität Konstanz
Titel in einer weiteren Sprache
Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published
Erschienen in
Chemical Physics Letters. 2009, 474(1-3), pp. 127-131. Available under: doi: 10.1016/j.cplett.2009.04.020
Zusammenfassung
The geometric and electronic structures of gas phase (Mo3S3)nS2 and (Mo3S3)n-1(MoS4)2 clusters with n = 2, 3, 4, . . . are studied experimentally using mass and photoelectron spectroscopy. The Mo3S3 units form one-dimensional chains with length n . There are two possible types of terminations at the ends: a single S atom or a MoS4 cluster. The experimental results are compared to calculations based on density- functional theory. Although clusters of this type have been known for decades as constituents of Chevrel phases, we here report their first gas phase synthesis for sizes up to n = 17. With increasing n, the gap vanishes extending such clusters to a conducting wire.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
530 Physik
Schlagwörter
Konferenz
Rezension
undefined / . - undefined, undefined
Zitieren
ISO 690
GEMMING, Sibylle, Gotthard SEIFERT, Nils BERTRAM, Tim FISCHER, Matthias GÖTZ, Gerd GANTEFÖR, 2009. One-dimensional (Mo3S3)n clusters : building blocks of clusters materials and ideal nanowires for molecular electronics. In: Chemical Physics Letters. 2009, 474(1-3), pp. 127-131. Available under: doi: 10.1016/j.cplett.2009.04.020BibTex
@article{Gemming2009Onedi-5322,
year={2009},
doi={10.1016/j.cplett.2009.04.020},
title={One-dimensional (Mo3S3)n clusters : building blocks of clusters materials and ideal nanowires for molecular electronics},
number={1-3},
volume={474},
journal={Chemical Physics Letters},
pages={127--131},
author={Gemming, Sibylle and Seifert, Gotthard and Bertram, Nils and Fischer, Tim and Götz, Matthias and Ganteför, Gerd}
}RDF
<rdf:RDF
xmlns:dcterms="http://purl.org/dc/terms/"
xmlns:dc="http://purl.org/dc/elements/1.1/"
xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
xmlns:bibo="http://purl.org/ontology/bibo/"
xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
xmlns:foaf="http://xmlns.com/foaf/0.1/"
xmlns:void="http://rdfs.org/ns/void#"
xmlns:xsd="http://www.w3.org/2001/XMLSchema#" >
<rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/5322">
<dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
<dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/5322/1/ChemPhysLett474.pdf"/>
<dc:creator>Ganteför, Gerd</dc:creator>
<dc:rights>terms-of-use</dc:rights>
<dc:contributor>Gemming, Sibylle</dc:contributor>
<dc:contributor>Fischer, Tim</dc:contributor>
<dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
<dc:contributor>Seifert, Gotthard</dc:contributor>
<dc:language>deu</dc:language>
<dc:contributor>Götz, Matthias</dc:contributor>
<dcterms:bibliographicCitation>First publ. in: Chemical Physics Letters 474 (2009), 1-3, pp. 127 131</dcterms:bibliographicCitation>
<dc:contributor>Ganteför, Gerd</dc:contributor>
<dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
<dc:contributor>Bertram, Nils</dc:contributor>
<dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:54:55Z</dcterms:available>
<dc:creator>Fischer, Tim</dc:creator>
<dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/5322/1/ChemPhysLett474.pdf"/>
<dc:creator>Götz, Matthias</dc:creator>
<dcterms:abstract xml:lang="eng">The geometric and electronic structures of gas phase (Mo3S3)nS2 and (Mo3S3)n-1(MoS4)2 clusters with n = 2, 3, 4, . . . are studied experimentally using mass and photoelectron spectroscopy. The Mo3S3 units form one-dimensional chains with length n . There are two possible types of terminations at the ends: a single S atom or a MoS4 cluster. The experimental results are compared to calculations based on density- functional theory. Although clusters of this type have been known for decades as constituents of Chevrel phases, we here report their first gas phase synthesis for sizes up to n = 17. With increasing n, the gap vanishes extending such clusters to a conducting wire.</dcterms:abstract>
<dc:format>application/pdf</dc:format>
<dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:54:55Z</dc:date>
<dc:creator>Gemming, Sibylle</dc:creator>
<dc:creator>Seifert, Gotthard</dc:creator>
<dc:creator>Bertram, Nils</dc:creator>
<dcterms:title>One-dimensional (Mo3S3)n clusters : building blocks of clusters materials and ideal nanowires for molecular electronics</dcterms:title>
<foaf:homepage rdf:resource="http://localhost:8080/"/>
<void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
<bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/5322"/>
<dcterms:issued>2009</dcterms:issued>
</rdf:Description>
</rdf:RDF>Interner Vermerk
xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter
Prüfungsdatum der Dissertation
Finanzierungsart
Kommentar zur Publikation
Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
