ansa-Metallocene derivatives : V. Synthesis of tetramethylethylene-bridged titanocene and zirconocene derivatives via reductive fulvene coupling
ansa-Metallocene derivatives : V. Synthesis of tetramethylethylene-bridged titanocene and zirconocene derivatives via reductive fulvene coupling
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1983
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Schwemlein, Heinz
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Journal of Organometallic Chemistry ; 254 (1983), 1. - pp. 69-73. - ISSN 0022-328X
Abstract
Titanocene and zirconocene derivatives with an interannular tetramethylethylene bridge can be made by reductive coupling of 6,6-dimethylfulvene with sodium amalgam, sodium anthracenide, or magnesium metal/CCl4 as reducing agents and subsequent reaction of the anionic tetramethyldicyclopentadienylethane product with TiCl3 or ZrCl4 in THF.
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ISO 690
SCHWEMLEIN, Heinz, Hans-Herbert BRINTZINGER, 1983. ansa-Metallocene derivatives : V. Synthesis of tetramethylethylene-bridged titanocene and zirconocene derivatives via reductive fulvene coupling. In: Journal of Organometallic Chemistry. 254(1), pp. 69-73. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(83)85118-3BibTex
@article{Schwemlein1983ansaM-23962,
year={1983},
doi={10.1016/0022-328X(83)85118-3},
title={ansa-Metallocene derivatives : V. Synthesis of tetramethylethylene-bridged titanocene and zirconocene derivatives via reductive fulvene coupling},
number={1},
volume={254},
issn={0022-328X},
journal={Journal of Organometallic Chemistry},
pages={69--73},
author={Schwemlein, Heinz and Brintzinger, Hans-Herbert}
}
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