ansa-Metallocene derivatives : V. Synthesis of tetramethylethylene-bridged titanocene and zirconocene derivatives via reductive fulvene coupling

Schwemlein, Heinz; Brintzinger, Hans-Herbert

ansa-Metallocene derivatives : V. Synthesis of tetramethylethylene-bridged titanocene and zirconocene derivatives via reductive fulvene coupling

Dateien

Schwemlein_239621.pdfGröße: 279.53 KBDownloads: 302

Datum

1983

Autor:innen

Schwemlein, Heinz

Brintzinger, Hans-Herbert

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Chemie

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Journal of Organometallic Chemistry. 1983, 254(1), pp. 69-73. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(83)85118-3

Zusammenfassung

Titanocene and zirconocene derivatives with an interannular tetramethylethylene bridge can be made by reductive coupling of 6,6-dimethylfulvene with sodium amalgam, sodium anthracenide, or magnesium metal/CCl₄ as reducing agents and subsequent reaction of the anionic tetramethyldicyclopentadienylethane product with TiCl₃ or ZrCl₄ in THF.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

SCHWEMLEIN, Heinz, Hans-Herbert BRINTZINGER, 1983. ansa-Metallocene derivatives : V. Synthesis of tetramethylethylene-bridged titanocene and zirconocene derivatives via reductive fulvene coupling. In: Journal of Organometallic Chemistry. 1983, 254(1), pp. 69-73. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(83)85118-3

BibTex

@article{Schwemlein1983ansaM-23962,
  year={1983},
  doi={10.1016/0022-328X(83)85118-3},
  title={ansa-Metallocene derivatives : V. Synthesis of tetramethylethylene-bridged titanocene and zirconocene derivatives via reductive fulvene coupling},
  number={1},
  volume={254},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={69--73},
  author={Schwemlein, Heinz and Brintzinger, Hans-Herbert}
}

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