Glycopolymer-grafted polystyrene nanospheres

dc.contributor.authorPfaff, Andrédeu
dc.contributor.authorShinde, Vaishali S.deu
dc.contributor.authorLu, Yandeu
dc.contributor.authorWittemann, Alexander
dc.contributor.authorBallauff, Matthiasdeu
dc.contributor.authorMüller, Axel H. E.deu
dc.date.accessioned2012-07-12T09:39:03Zdeu
dc.date.available2012-07-12T09:39:03Zdeu
dc.date.issued2011-02-11
dc.description.abstractThe synthesis and characterization of spherical sugar-containing polymer brushes consisting of PS cores onto which chains of sugar-containing polymers have been grafted via two different techniques are described. Photopolymerization in aqueous dispersion using the functional monomer MAGlc and crosslinked or non-crosslinked PS particles covered with a thin layer of photo-initiator yielded homogeneous glycopolymer brushes attached to spherical PS cores. As an alternative, ATRP was used to graft poly-(N-acetylglucosamine) arms from crosslinked PS cores. Deprotection of the grafted brushes led to water-soluble particles that act as carriers for catalytically active gold nanoparticles. These glycopolymer chains show a high affinity to adsorb WGA whereas no binding to BSA or PNA could be detected.eng
dc.description.versionpublished
dc.identifier.citationPubl. in: Macromolecular Bioscience ; 11 (2011), 2. - S. 199-210deu
dc.identifier.doi10.1002/mabi.201000324deu
dc.identifier.pmid21104878
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/19735
dc.language.isoengdeu
dc.legacy.dateIssued2012-07-12deu
dc.rightsterms-of-usedeu
dc.rights.urihttps://rightsstatements.org/page/InC/1.0/deu
dc.subjectatom-transfer radical polymerization (ATRP)deu
dc.subjectglycopolymerdeu
dc.subjectgold nanoparticlesdeu
dc.subjectlectin recognitiondeu
dc.subjectspherical brushesdeu
dc.subject.ddc540deu
dc.titleGlycopolymer-grafted polystyrene nanosphereseng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Pfaff2011-02-11Glyco-19735,
  year={2011},
  doi={10.1002/mabi.201000324},
  title={Glycopolymer-grafted polystyrene nanospheres},
  number={2},
  volume={11},
  issn={1616-5187},
  journal={Macromolecular Bioscience},
  pages={199--210},
  author={Pfaff, André and Shinde, Vaishali S. and Lu, Yan and Wittemann, Alexander and Ballauff, Matthias and Müller, Axel H. E.}
}
kops.citation.iso690PFAFF, André, Vaishali S. SHINDE, Yan LU, Alexander WITTEMANN, Matthias BALLAUFF, Axel H. E. MÜLLER, 2011. Glycopolymer-grafted polystyrene nanospheres. In: Macromolecular Bioscience. 2011, 11(2), pp. 199-210. ISSN 1616-5187. eISSN 1616-5195. Available under: doi: 10.1002/mabi.201000324deu
kops.citation.iso690PFAFF, André, Vaishali S. SHINDE, Yan LU, Alexander WITTEMANN, Matthias BALLAUFF, Axel H. E. MÜLLER, 2011. Glycopolymer-grafted polystyrene nanospheres. In: Macromolecular Bioscience. 2011, 11(2), pp. 199-210. ISSN 1616-5187. eISSN 1616-5195. Available under: doi: 10.1002/mabi.201000324eng
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kops.sourcefieldMacromolecular Bioscience. 2011, <b>11</b>(2), pp. 199-210. ISSN 1616-5187. eISSN 1616-5195. Available under: doi: 10.1002/mabi.201000324deu
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kops.sourcefield.plainMacromolecular Bioscience. 2011, 11(2), pp. 199-210. ISSN 1616-5187. eISSN 1616-5195. Available under: doi: 10.1002/mabi.201000324eng
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source.periodicalTitleMacromolecular Bioscience

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