Glycopolymer-grafted polystyrene nanospheres
| dc.contributor.author | Pfaff, André | deu |
| dc.contributor.author | Shinde, Vaishali S. | deu |
| dc.contributor.author | Lu, Yan | deu |
| dc.contributor.author | Wittemann, Alexander | |
| dc.contributor.author | Ballauff, Matthias | deu |
| dc.contributor.author | Müller, Axel H. E. | deu |
| dc.date.accessioned | 2012-07-12T09:39:03Z | deu |
| dc.date.available | 2012-07-12T09:39:03Z | deu |
| dc.date.issued | 2011-02-11 | |
| dc.description.abstract | The synthesis and characterization of spherical sugar-containing polymer brushes consisting of PS cores onto which chains of sugar-containing polymers have been grafted via two different techniques are described. Photopolymerization in aqueous dispersion using the functional monomer MAGlc and crosslinked or non-crosslinked PS particles covered with a thin layer of photo-initiator yielded homogeneous glycopolymer brushes attached to spherical PS cores. As an alternative, ATRP was used to graft poly-(N-acetylglucosamine) arms from crosslinked PS cores. Deprotection of the grafted brushes led to water-soluble particles that act as carriers for catalytically active gold nanoparticles. These glycopolymer chains show a high affinity to adsorb WGA whereas no binding to BSA or PNA could be detected. | eng |
| dc.description.version | published | |
| dc.identifier.citation | Publ. in: Macromolecular Bioscience ; 11 (2011), 2. - S. 199-210 | deu |
| dc.identifier.doi | 10.1002/mabi.201000324 | deu |
| dc.identifier.pmid | 21104878 | |
| dc.identifier.uri | http://kops.uni-konstanz.de/handle/123456789/19735 | |
| dc.language.iso | eng | deu |
| dc.legacy.dateIssued | 2012-07-12 | deu |
| dc.rights | terms-of-use | deu |
| dc.rights.uri | https://rightsstatements.org/page/InC/1.0/ | deu |
| dc.subject | atom-transfer radical polymerization (ATRP) | deu |
| dc.subject | glycopolymer | deu |
| dc.subject | gold nanoparticles | deu |
| dc.subject | lectin recognition | deu |
| dc.subject | spherical brushes | deu |
| dc.subject.ddc | 540 | deu |
| dc.title | Glycopolymer-grafted polystyrene nanospheres | eng |
| dc.type | JOURNAL_ARTICLE | deu |
| dspace.entity.type | Publication | |
| kops.citation.bibtex | @article{Pfaff2011-02-11Glyco-19735,
year={2011},
doi={10.1002/mabi.201000324},
title={Glycopolymer-grafted polystyrene nanospheres},
number={2},
volume={11},
issn={1616-5187},
journal={Macromolecular Bioscience},
pages={199--210},
author={Pfaff, André and Shinde, Vaishali S. and Lu, Yan and Wittemann, Alexander and Ballauff, Matthias and Müller, Axel H. E.}
} | |
| kops.citation.iso690 | PFAFF, André, Vaishali S. SHINDE, Yan LU, Alexander WITTEMANN, Matthias BALLAUFF, Axel H. E. MÜLLER, 2011. Glycopolymer-grafted polystyrene nanospheres. In: Macromolecular Bioscience. 2011, 11(2), pp. 199-210. ISSN 1616-5187. eISSN 1616-5195. Available under: doi: 10.1002/mabi.201000324 | deu |
| kops.citation.iso690 | PFAFF, André, Vaishali S. SHINDE, Yan LU, Alexander WITTEMANN, Matthias BALLAUFF, Axel H. E. MÜLLER, 2011. Glycopolymer-grafted polystyrene nanospheres. In: Macromolecular Bioscience. 2011, 11(2), pp. 199-210. ISSN 1616-5187. eISSN 1616-5195. Available under: doi: 10.1002/mabi.201000324 | eng |
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<dcterms:abstract xml:lang="eng">The synthesis and characterization of spherical sugar-containing polymer brushes consisting of PS cores onto which chains of sugar-containing polymers have been grafted via two different techniques are described. Photopolymerization in aqueous dispersion using the functional monomer MAGlc and crosslinked or non-crosslinked PS particles covered with a thin layer of photo-initiator yielded homogeneous glycopolymer brushes attached to spherical PS cores. As an alternative, ATRP was used to graft poly-(N-acetylglucosamine) arms from crosslinked PS cores. Deprotection of the grafted brushes led to water-soluble particles that act as carriers for catalytically active gold nanoparticles. These glycopolymer chains show a high affinity to adsorb WGA whereas no binding to BSA or PNA could be detected.</dcterms:abstract>
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| kops.identifier.nbn | urn:nbn:de:bsz:352-197356 | deu |
| kops.sourcefield | Macromolecular Bioscience. 2011, <b>11</b>(2), pp. 199-210. ISSN 1616-5187. eISSN 1616-5195. Available under: doi: 10.1002/mabi.201000324 | deu |
| kops.sourcefield.plain | Macromolecular Bioscience. 2011, 11(2), pp. 199-210. ISSN 1616-5187. eISSN 1616-5195. Available under: doi: 10.1002/mabi.201000324 | deu |
| kops.sourcefield.plain | Macromolecular Bioscience. 2011, 11(2), pp. 199-210. ISSN 1616-5187. eISSN 1616-5195. Available under: doi: 10.1002/mabi.201000324 | eng |
| kops.submitter.email | larysa.herasymova@uni-konstanz.de | deu |
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| source.bibliographicInfo.toPage | 210 | |
| source.bibliographicInfo.volume | 11 | |
| source.identifier.eissn | 1616-5195 | |
| source.identifier.issn | 1616-5187 | |
| source.periodicalTitle | Macromolecular Bioscience |
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