Intergrowth and Interfacial Structure of Biomimetic Fluorapatite-Gelatin Nanocomposite : A Solid-State NMR Study

Kurzanzeige
dc.contributor.authorVyalikh, Anastasia
dc.contributor.authorSimon, Paul
dc.contributor.authorSturm, Elena V.
dc.contributor.authorBruder, Jana
dc.contributor.authorKniep, Rüdiger
dc.contributor.authorScheler, Ulrich
dc.date.accessioned2015-03-11T14:56:51Z
dc.date.available2015-03-11T14:56:51Z
dc.date.issued2014eng
dc.description.abstractThe model system fluorapatite–gelatin allows mimicking the formation conditions on a lower level of complexity compared to natural dental and bone tissues. Here, we report on solid-state NMR investigations to examine the structure of fluorapatite–gelatin nanocomposites on a molecular level with particular focus on organic–inorganic interactions. Using 31P, 19F, and 1H MAS NMR and heteronuclear correlations, we found the nanocomposite to consist of crystalline apatite-like regions (fluorapatite and hydroxyfluorapatite) in close contact with a more dissolved (amorphous) layer containing first motifs of the apatite crystal structure as well as the organic component. A scheme of the intergrowth region in the fluorapatite–gelatin nanocomposite, where mineral domains interact with organic matrix, is presented.eng
dc.description.versionpublished
dc.identifier.doi10.1021/jp410299xeng
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/30215
dc.language.isoengeng
dc.subject.ddc540eng
dc.titleIntergrowth and Interfacial Structure of Biomimetic Fluorapatite-Gelatin Nanocomposite : A Solid-State NMR Studyeng
dc.typeJOURNAL_ARTICLEeng
dspace.entity.typePublication
kops.citation.bibtex
@article{Vyalikh2014Inter-30215,
  year={2014},
  doi={10.1021/jp410299x},
  title={Intergrowth and Interfacial Structure of Biomimetic Fluorapatite-Gelatin Nanocomposite : A Solid-State NMR Study},
  number={3},
  volume={118},
  issn={1520-6106},
  journal={The Journal of Physical Chemistry B},
  pages={724--730},
  author={Vyalikh, Anastasia and Simon, Paul and Sturm, Elena V. and Bruder, Jana and Kniep, Rüdiger and Scheler, Ulrich}
}
kops.citation.iso690VYALIKH, Anastasia, Paul SIMON, Elena V. STURM, Jana BRUDER, Rüdiger KNIEP, Ulrich SCHELER, 2014. Intergrowth and Interfacial Structure of Biomimetic Fluorapatite-Gelatin Nanocomposite : A Solid-State NMR Study. In: The Journal of Physical Chemistry B. 2014, 118(3), pp. 724-730. ISSN 1520-6106. eISSN 1520-5207. Available under: doi: 10.1021/jp410299xdeu
kops.citation.iso690VYALIKH, Anastasia, Paul SIMON, Elena V. STURM, Jana BRUDER, Rüdiger KNIEP, Ulrich SCHELER, 2014. Intergrowth and Interfacial Structure of Biomimetic Fluorapatite-Gelatin Nanocomposite : A Solid-State NMR Study. In: The Journal of Physical Chemistry B. 2014, 118(3), pp. 724-730. ISSN 1520-6106. eISSN 1520-5207. Available under: doi: 10.1021/jp410299xeng
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kops.sourcefieldThe Journal of Physical Chemistry B. 2014, <b>118</b>(3), pp. 724-730. ISSN 1520-6106. eISSN 1520-5207. Available under: doi: 10.1021/jp410299xdeu
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source.periodicalTitleThe Journal of Physical Chemistry Beng
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