Monitoring the crystallization of tartaric acid with THz spectroscopy
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2017
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2017 42nd International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz) ; Proceedings. Piscataway, NJ: IEEE, 2017. eISSN 2162-2035. ISBN 978-1-5090-6050-4. Available under: doi: 10.1109/IRMMW-THz.2017.8066993
Zusammenfassung
We study the crystallization of L-(+)-Tartaric acid by employing attenuated total reflection THz time-domain spectroscopy (TDS). In the so-called nucleation stage, the absorption spectrum shows a broadband transient increase. Besides, we observed a transient resonance at 750 GHz. This peak can be assigned to aggregation of L-(+)-Tartaric acid molecules including hydrated water molecules. Furthermore, the THz data reveal the vibration of clusters in the solution phase which is confirmed by analytical ultracentrifugation technique.
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540 Chemie
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2017 42nd International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz), 27. Aug. 2017 - 1. Sept. 2017, Cancun, Mexico
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SOLTANI, Amin, Denis GEBAUER, Bernd M. FISCHER, Helmut CÖLFEN, Martin KOCH, 2017. Monitoring the crystallization of tartaric acid with THz spectroscopy. 2017 42nd International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz). Cancun, Mexico, 27. Aug. 2017 - 1. Sept. 2017. In: 2017 42nd International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz) ; Proceedings. Piscataway, NJ: IEEE, 2017. eISSN 2162-2035. ISBN 978-1-5090-6050-4. Available under: doi: 10.1109/IRMMW-THz.2017.8066993BibTex
@inproceedings{Soltani2017-08Monit-41181, year={2017}, doi={10.1109/IRMMW-THz.2017.8066993}, title={Monitoring the crystallization of tartaric acid with THz spectroscopy}, isbn={978-1-5090-6050-4}, publisher={IEEE}, address={Piscataway, NJ}, booktitle={2017 42nd International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz) ; Proceedings}, author={Soltani, Amin and Gebauer, Denis and Fischer, Bernd M. and Cölfen, Helmut and Koch, Martin} }
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