Cyclodextrin-based porous silica materials as in situ chemical Nanoreactors for the preparation of variable metal-silica hybrids

dc.contributor.authorHan, Bao-Hangdeu
dc.contributor.authorPolarz, Sebastian
dc.contributor.authorAntonietti, Markusdeu
dc.date.accessioned2011-03-24T18:12:50Zdeu
dc.date.issued2001deu
dc.description.abstractInclusion complexs of cyclodextrins with organometallic coordination compounds of Pd, Pt, Rh, Fe, Ni, and Ru have been used to produce porous metal-silica hybrid materials. The cyclodextrins are templates for the structure of the silica and lead to a uniform wormtype pore system. After the templating step the organometallic compounds can be employed as in situ precursors for the preparation of metal nanoparticles within the pore system, thus leading to a one-step synthesis of silica-supported metal catalysts. These new materials are characterized and how the chemical confinement of the silica pores can influence the size, structure, and distribution of the nanoparticles is studied.eng
dc.description.versionpublished
dc.format.mimetypeapplication/pdfdeu
dc.identifier.citationFirst publ. in: Chemistry of Materials ; 13 (2001). - S. 3915-3919deu
dc.identifier.doi10.1021/cm0110425
dc.identifier.ppn282532811deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/9571
dc.language.isoengdeu
dc.legacy.dateIssued2008deu
dc.rightsAttribution-NonCommercial-NoDerivs 2.0 Generic
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.0/
dc.subject.ddc540deu
dc.titleCyclodextrin-based porous silica materials as in situ chemical Nanoreactors for the preparation of variable metal-silica hybridseng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Han2001Cyclo-9571,
  year={2001},
  doi={10.1021/cm0110425},
  title={Cyclodextrin-based porous silica materials as in situ chemical  Nanoreactors  for the preparation of variable metal-silica hybrids},
  number={11},
  volume={13},
  issn={0897-4756},
  journal={Chemistry of Materials},
  pages={3915--3919},
  author={Han, Bao-Hang and Polarz, Sebastian and Antonietti, Markus}
}
kops.citation.iso690HAN, Bao-Hang, Sebastian POLARZ, Markus ANTONIETTI, 2001. Cyclodextrin-based porous silica materials as in situ chemical Nanoreactors for the preparation of variable metal-silica hybrids. In: Chemistry of Materials. 2001, 13(11), pp. 3915-3919. ISSN 0897-4756. eISSN 1520-5002. Available under: doi: 10.1021/cm0110425deu
kops.citation.iso690HAN, Bao-Hang, Sebastian POLARZ, Markus ANTONIETTI, 2001. Cyclodextrin-based porous silica materials as in situ chemical Nanoreactors for the preparation of variable metal-silica hybrids. In: Chemistry of Materials. 2001, 13(11), pp. 3915-3919. ISSN 0897-4756. eISSN 1520-5002. Available under: doi: 10.1021/cm0110425eng
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kops.sourcefield.plainChemistry of Materials. 2001, 13(11), pp. 3915-3919. ISSN 0897-4756. eISSN 1520-5002. Available under: doi: 10.1021/cm0110425eng
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