Cyclodextrin-based porous silica materials as in situ chemical Nanoreactors for the preparation of variable metal-silica hybrids
| dc.contributor.author | Han, Bao-Hang | deu |
| dc.contributor.author | Polarz, Sebastian | |
| dc.contributor.author | Antonietti, Markus | deu |
| dc.date.accessioned | 2011-03-24T18:12:50Z | deu |
| dc.date.issued | 2001 | deu |
| dc.description.abstract | Inclusion complexs of cyclodextrins with organometallic coordination compounds of Pd, Pt, Rh, Fe, Ni, and Ru have been used to produce porous metal-silica hybrid materials. The cyclodextrins are templates for the structure of the silica and lead to a uniform wormtype pore system. After the templating step the organometallic compounds can be employed as in situ precursors for the preparation of metal nanoparticles within the pore system, thus leading to a one-step synthesis of silica-supported metal catalysts. These new materials are characterized and how the chemical confinement of the silica pores can influence the size, structure, and distribution of the nanoparticles is studied. | eng |
| dc.description.version | published | |
| dc.format.mimetype | application/pdf | deu |
| dc.identifier.citation | First publ. in: Chemistry of Materials ; 13 (2001). - S. 3915-3919 | deu |
| dc.identifier.doi | 10.1021/cm0110425 | |
| dc.identifier.ppn | 282532811 | deu |
| dc.identifier.uri | http://kops.uni-konstanz.de/handle/123456789/9571 | |
| dc.language.iso | eng | deu |
| dc.legacy.dateIssued | 2008 | deu |
| dc.rights | Attribution-NonCommercial-NoDerivs 2.0 Generic | |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/2.0/ | |
| dc.subject.ddc | 540 | deu |
| dc.title | Cyclodextrin-based porous silica materials as in situ chemical Nanoreactors for the preparation of variable metal-silica hybrids | eng |
| dc.type | JOURNAL_ARTICLE | deu |
| dspace.entity.type | Publication | |
| kops.citation.bibtex | @article{Han2001Cyclo-9571,
year={2001},
doi={10.1021/cm0110425},
title={Cyclodextrin-based porous silica materials as in situ chemical Nanoreactors for the preparation of variable metal-silica hybrids},
number={11},
volume={13},
issn={0897-4756},
journal={Chemistry of Materials},
pages={3915--3919},
author={Han, Bao-Hang and Polarz, Sebastian and Antonietti, Markus}
} | |
| kops.citation.iso690 | HAN, Bao-Hang, Sebastian POLARZ, Markus ANTONIETTI, 2001. Cyclodextrin-based porous silica materials as in situ chemical Nanoreactors for the preparation of variable metal-silica hybrids. In: Chemistry of Materials. 2001, 13(11), pp. 3915-3919. ISSN 0897-4756. eISSN 1520-5002. Available under: doi: 10.1021/cm0110425 | deu |
| kops.citation.iso690 | HAN, Bao-Hang, Sebastian POLARZ, Markus ANTONIETTI, 2001. Cyclodextrin-based porous silica materials as in situ chemical Nanoreactors for the preparation of variable metal-silica hybrids. In: Chemistry of Materials. 2001, 13(11), pp. 3915-3919. ISSN 0897-4756. eISSN 1520-5002. Available under: doi: 10.1021/cm0110425 | eng |
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<dcterms:abstract xml:lang="eng">Inclusion complexs of cyclodextrins with organometallic coordination compounds of Pd, Pt, Rh, Fe, Ni, and Ru have been used to produce porous metal-silica hybrid materials. The cyclodextrins are templates for the structure of the silica and lead to a uniform wormtype pore system. After the templating step the organometallic compounds can be employed as in situ precursors for the preparation of metal nanoparticles within the pore system, thus leading to a one-step synthesis of silica-supported metal catalysts. These new materials are characterized and how the chemical confinement of the silica pores can influence the size, structure, and distribution of the nanoparticles is studied.</dcterms:abstract>
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| source.periodicalTitle | Chemistry of Materials |
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