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Forced rayleigh scattering in mixtures of colloidal particles

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095_progcollpolymsci_1991.pdf
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1991

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Palberg, Thomas
Simon, Rolf

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Progress in Colloid and Polymer Science. 1991, 84, pp. 397-401. Available under: doi: 10.1007/BFb0116011

Zusammenfassung

In this work, forced Rayleigh scattering is combined with a new deionization technique to measure the self-diffusion coefficient of strongly interacting charged polystyrene particles. For each measurement the, actually continuous, deionization process is stopped, allowing the suspension to relax from a sheared state to an equilibrium state. Conductivity and diffusion coefficient are monitored, both during this relaxation to equilibrium, and in dependence of the total deionization time. Relaxational behavior in the diffusion coefficient is observed in samples of both fluid and crystalline equilibrium state, while the conductivity remains unchanged. With increasing total deionization time the conductivity reaches a minimum and rises again to a stable plateau. The self-diffusion coefficient in equilibrium (i.e., at rest) also drops with increasing deianization time for monodisperse samples to unmeasurably low values, On the other hand, a finite, but small diffusion coefficient is found for the charge bidisperse sample.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
530 Physik

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latex spheres, self-diffusion, forced Rayleigh scattering, crystallization, binary mixtures

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ISO 690PALBERG, Thomas, Rolf SIMON, Paul LEIDERER, 1991. Forced rayleigh scattering in mixtures of colloidal particles. In: Progress in Colloid and Polymer Science. 1991, 84, pp. 397-401. Available under: doi: 10.1007/BFb0116011
BibTex
@article{Palberg1991Force-4707,
  year={1991},
  doi={10.1007/BFb0116011},
  title={Forced rayleigh scattering in mixtures of colloidal particles},
  volume={84},
  journal={Progress in Colloid and Polymer Science},
  pages={397--401},
  author={Palberg, Thomas and Simon, Rolf and Leiderer, Paul}
}
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