Temporal Evolution of Interparticle Potentials of PMMA Colloids in CHB/Decalin

Abstract

Colloidal dispersions composed of polymethylmetacrylate particles dispersed in a mixture of cyclohexyl bromide and decalin find widespread use as model systems in optical microscopy experiments. While the system allows simultaneous density and refractive index matching, preparing particles with hard potentials remains challenging, and strong variations in the physical parameters of samples prepared in the same manner are commonly observed. Here, we present data on the measurement of forces between individual pairs of particles in highly diluted dispersions over the course of tens of days using the blinking optical tweezers method. Our results show that the variations in the particle properties are indeed caused by a temporal evolution of the particles’ charging. Additional measurements of the influence of the addition of tetrabutylammonium bromide (TBAB) to the dispersions show that already small concentrations of added TBAB salt drastically decrease the electrostatic forces between colloidal particles. However, small, non-negligible contact potentials remain even at the highest TBAB concentrations added.