Size-selected gold clusters on porous titania as the most “gold-efficient” heterogeneous catalysts
Lade...
Dateien
Datum
2014
Autor:innen
Dollinger, Andreas
Stolch, Lukas
Luo, Yuan
Beck, Martin
Strobel, Christoph H.
Hagner, Matthias
Dilger, Stefan
Bein, Malin
Polarz, Sebastian
Ganteför, Gerd
Herausgeber:innen
ISSN der Zeitschrift
Electronic ISSN
ISBN
Bibliografische Daten
Verlag
Schriftenreihe
Auflagebezeichnung
URI (zitierfähiger Link)
DOI (zitierfähiger Link)
Internationale Patentnummer
Link zur Lizenz
Angaben zur Forschungsförderung
Projekt
Open Access-Veröffentlichung
Open Access Green
Core Facility der Universität Konstanz
Titel in einer weiteren Sprache
Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published
Erschienen in
Physical Chemistry Chemical Physics. 2014, 16(22), pp. 11017-11023. ISSN 1463-9076. eISSN 1463-9084. Available under: doi: 10.1039/C4CP00597J
Zusammenfassung
Research on homogeneous and heterogeneous catalysis is indeed convergent and finds subnanometric particles to be at the heart of catalytically active species. Here, monodisperse gold clusters are deposited from the gas phase onto porous titania generating well-defined model systems and the resulting composite materials exhibit a sharp size-dependency on the number of gold atoms per cluster and exceptionally high-turnovers toward the bromination of 1,4-dimethoxybenzene are observed. This indicates that the deliberate generation of active centres is of utmost importance for the creation of the most “gold-efficient” catalysts.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
540 Chemie
Schlagwörter
Konferenz
Rezension
undefined / . - undefined, undefined
Zitieren
ISO 690
DOLLINGER, Andreas, Lukas STOLCH, Yuan LUO, Martin BECK, Christoph H. STROBEL, Matthias HAGNER, Stefan DILGER, Malin BEIN, Sebastian POLARZ, Gerd GANTEFÖR, Young-Dok KIM, Sebastian PROCH, 2014. Size-selected gold clusters on porous titania as the most “gold-efficient” heterogeneous catalysts. In: Physical Chemistry Chemical Physics. 2014, 16(22), pp. 11017-11023. ISSN 1463-9076. eISSN 1463-9084. Available under: doi: 10.1039/C4CP00597JBibTex
@article{Dollinger2014Sizes-29617,
year={2014},
doi={10.1039/C4CP00597J},
title={Size-selected gold clusters on porous titania as the most “gold-efficient” heterogeneous catalysts},
number={22},
volume={16},
issn={1463-9076},
journal={Physical Chemistry Chemical Physics},
pages={11017--11023},
author={Dollinger, Andreas and Stolch, Lukas and Luo, Yuan and Beck, Martin and Strobel, Christoph H. and Hagner, Matthias and Dilger, Stefan and Bein, Malin and Polarz, Sebastian and Ganteför, Gerd and Kim, Young-Dok and Proch, Sebastian}
}RDF
<rdf:RDF
xmlns:dcterms="http://purl.org/dc/terms/"
xmlns:dc="http://purl.org/dc/elements/1.1/"
xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
xmlns:bibo="http://purl.org/ontology/bibo/"
xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
xmlns:foaf="http://xmlns.com/foaf/0.1/"
xmlns:void="http://rdfs.org/ns/void#"
xmlns:xsd="http://www.w3.org/2001/XMLSchema#" >
<rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29617">
<dc:contributor>Kim, Young-Dok</dc:contributor>
<dc:contributor>Beck, Martin</dc:contributor>
<dc:creator>Ganteför, Gerd</dc:creator>
<dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
<dc:creator>Hagner, Matthias</dc:creator>
<dcterms:issued>2014</dcterms:issued>
<dc:contributor>Bein, Malin</dc:contributor>
<dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
<dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
<dcterms:title>Size-selected gold clusters on porous titania as the most “gold-efficient” heterogeneous catalysts</dcterms:title>
<dc:creator>Beck, Martin</dc:creator>
<dc:language>eng</dc:language>
<dc:contributor>Proch, Sebastian</dc:contributor>
<dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2015-01-23T10:47:49Z</dcterms:available>
<dc:creator>Proch, Sebastian</dc:creator>
<dc:creator>Dilger, Stefan</dc:creator>
<dc:creator>Polarz, Sebastian</dc:creator>
<dcterms:abstract xml:lang="eng">Research on homogeneous and heterogeneous catalysis is indeed convergent and finds subnanometric particles to be at the heart of catalytically active species. Here, monodisperse gold clusters are deposited from the gas phase onto porous titania generating well-defined model systems and the resulting composite materials exhibit a sharp size-dependency on the number of gold atoms per cluster and exceptionally high-turnovers toward the bromination of 1,4-dimethoxybenzene are observed. This indicates that the deliberate generation of active centres is of utmost importance for the creation of the most “gold-efficient” catalysts.</dcterms:abstract>
<dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
<bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/29617"/>
<dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2015-01-23T10:47:49Z</dc:date>
<dc:creator>Bein, Malin</dc:creator>
<dc:creator>Luo, Yuan</dc:creator>
<dc:contributor>Ganteför, Gerd</dc:contributor>
<dc:rights>terms-of-use</dc:rights>
<dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
<dc:contributor>Hagner, Matthias</dc:contributor>
<dc:contributor>Dilger, Stefan</dc:contributor>
<dc:creator>Stolch, Lukas</dc:creator>
<dc:creator>Strobel, Christoph H.</dc:creator>
<foaf:homepage rdf:resource="http://localhost:8080/"/>
<dc:creator>Kim, Young-Dok</dc:creator>
<dc:creator>Dollinger, Andreas</dc:creator>
<dc:contributor>Luo, Yuan</dc:contributor>
<void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
<dc:contributor>Polarz, Sebastian</dc:contributor>
<dc:contributor>Stolch, Lukas</dc:contributor>
<dc:contributor>Dollinger, Andreas</dc:contributor>
<dc:contributor>Strobel, Christoph H.</dc:contributor>
<dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/29617/5/Dollinger_0-269436.pdf"/>
<dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/29617/5/Dollinger_0-269436.pdf"/>
</rdf:Description>
</rdf:RDF>Interner Vermerk
xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter
Prüfungsdatum der Dissertation
Finanzierungsart
Kommentar zur Publikation
Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
