Redox-Rich Metallocene Tetrazene Complexes : Synthesis, Structure, Electrochemistry, and Catalysis

Kurzanzeige
dc.contributor.authorVanicek, Stefan
dc.contributor.authorJochriem, Markus
dc.contributor.authorHassenrück, Christopher
dc.contributor.authorRoy, Souvik
dc.contributor.authorKopacka, Holger
dc.contributor.authorWurst, Klaus
dc.contributor.authorMüller, Thomas
dc.contributor.authorWinter, Rainer F.
dc.contributor.authorReisner, Erwin
dc.contributor.authorBildstein, Benno
dc.date.accessioned2019-01-07T13:32:15Z
dc.date.available2019-01-07T13:32:15Z
dc.date.issued2019-03-25
dc.description.abstractThermal or photochemical metal-centered cycloaddition reactions of azidocobaltocenium hexafluoridophosphate or azidoferrocene with (cyclooctadiene)(cyclopentadienyl)cobalt(I) afforded the first metallocenyl-substituted tetrazene cyclopentadienyl cobalt complexes together with azocobaltocenium or azoferrocene as side products. The trimetallic CpCo compounds are highly conjugated, colored, and redox-active metallo-aromatic compounds, as shown by their spectroscopic, structural, and electrochemical properties. The CpCo-tetrazenido complex with two terminally appended cobaltocene units catalyzes electrochemical proton reduction from acetic acid at a mild overpotential (0.35 V). Replacing cobaltocene with ferrocene moieties rendered the complex inactive toward catalysis.eng
dc.description.versionpublishedeng
dc.identifier.doi10.1021/acs.organomet.8b00681eng
dc.identifier.ppn1663335095
dc.identifier.urihttps://kops.uni-konstanz.de/handle/123456789/44423
dc.language.isoengeng
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dc.subject.ddc540eng
dc.titleRedox-Rich Metallocene Tetrazene Complexes : Synthesis, Structure, Electrochemistry, and Catalysiseng
dc.typeJOURNAL_ARTICLEeng
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kops.citation.bibtex
@article{Vanicek2019-03-25Redox-44423,
  year={2019},
  doi={10.1021/acs.organomet.8b00681},
  title={Redox-Rich Metallocene Tetrazene Complexes : Synthesis, Structure, Electrochemistry, and Catalysis},
  number={6},
  volume={38},
  issn={0276-7333},
  journal={Organometallics},
  pages={1361--1371},
  author={Vanicek, Stefan and Jochriem, Markus and Hassenrück, Christopher and Roy, Souvik and Kopacka, Holger and Wurst, Klaus and Müller, Thomas and Winter, Rainer F. and Reisner, Erwin and Bildstein, Benno}
}
kops.citation.iso690VANICEK, Stefan, Markus JOCHRIEM, Christopher HASSENRÜCK, Souvik ROY, Holger KOPACKA, Klaus WURST, Thomas MÜLLER, Rainer F. WINTER, Erwin REISNER, Benno BILDSTEIN, 2019. Redox-Rich Metallocene Tetrazene Complexes : Synthesis, Structure, Electrochemistry, and Catalysis. In: Organometallics. 2019, 38(6), pp. 1361-1371. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/acs.organomet.8b00681deu
kops.citation.iso690VANICEK, Stefan, Markus JOCHRIEM, Christopher HASSENRÜCK, Souvik ROY, Holger KOPACKA, Klaus WURST, Thomas MÜLLER, Rainer F. WINTER, Erwin REISNER, Benno BILDSTEIN, 2019. Redox-Rich Metallocene Tetrazene Complexes : Synthesis, Structure, Electrochemistry, and Catalysis. In: Organometallics. 2019, 38(6), pp. 1361-1371. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/acs.organomet.8b00681eng
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