N-(17-Phosphonooxylinolenoyl)glutamine and N-(17-phosphonooxylinoleoyl)glutamine from insect gut: the first backbone-phosphorylated fatty acid derivatives in nature

Kurzanzeige
dc.contributor.authorSpiteller, Dieter
dc.contributor.authorOldham, Neil J.deu
dc.contributor.authorBoland, Wilhelmdeu
dc.date.accessioned2011-10-20T08:46:21Zdeu
dc.date.available2011-10-20T08:46:21Zdeu
dc.date.issued2004-02-20
dc.description.abstractN-(17-Phosphonooxylinolenoyl)glutamine (1) and N-(17-phosphonooxylinoleoyl)glutamine (2) were isolated from the regurgitate of Spodoptora exigua and identified as the first natural alkyl chain-phosphorylated fatty acid derivatives. The compounds were characterized by HPLC-MS/MS and the assigned structures confirmed by synthesis via a dissymmetric bis-Wittig approach as the key reaction. Rearing of the larvae on a diet enriched with inorganic phosphate increased the amount of the phosphorylated N-acyl glutamines in the regurgitate.eng
dc.description.versionpublished
dc.identifier.citationPubl. in: The Journal of Organic Chemistry ; 69 (2004), 4. - S. 1104-1109deu
dc.identifier.doi10.1021/jo035382gdeu
dc.identifier.pmid14961658
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/15548
dc.language.isoengdeu
dc.legacy.dateIssued2011-10-20deu
dc.rightsterms-of-usedeu
dc.rights.urihttps://rightsstatements.org/page/InC/1.0/deu
dc.subject.ddc570deu
dc.titleN-(17-Phosphonooxylinolenoyl)glutamine and N-(17-phosphonooxylinoleoyl)glutamine from insect gut: the first backbone-phosphorylated fatty acid derivatives in natureeng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Spiteller2004-02-20N17Ph-15548,
  year={2004},
  doi={10.1021/jo035382g},
  title={N-(17-Phosphonooxylinolenoyl)glutamine and N-(17-phosphonooxylinoleoyl)glutamine from insect gut: the first backbone-phosphorylated fatty acid derivatives in nature},
  number={4},
  volume={69},
  issn={0022-3263},
  journal={The Journal of Organic Chemistry},
  pages={1104--1109},
  author={Spiteller, Dieter and Oldham, Neil J. and Boland, Wilhelm}
}
kops.citation.iso690SPITELLER, Dieter, Neil J. OLDHAM, Wilhelm BOLAND, 2004. N-(17-Phosphonooxylinolenoyl)glutamine and N-(17-phosphonooxylinoleoyl)glutamine from insect gut: the first backbone-phosphorylated fatty acid derivatives in nature. In: The Journal of Organic Chemistry. 2004, 69(4), pp. 1104-1109. ISSN 0022-3263. Available under: doi: 10.1021/jo035382gdeu
kops.citation.iso690SPITELLER, Dieter, Neil J. OLDHAM, Wilhelm BOLAND, 2004. N-(17-Phosphonooxylinolenoyl)glutamine and N-(17-phosphonooxylinoleoyl)glutamine from insect gut: the first backbone-phosphorylated fatty acid derivatives in nature. In: The Journal of Organic Chemistry. 2004, 69(4), pp. 1104-1109. ISSN 0022-3263. Available under: doi: 10.1021/jo035382geng
kops.citation.rdf
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/15548">
    <dc:creator>Oldham, Neil J.</dc:creator>
    <dc:contributor>Spiteller, Dieter</dc:contributor>
    <dcterms:bibliographicCitation>Publ. in: The Journal of Organic Chemistry ; 69 (2004), 4. - S. 1104-1109</dcterms:bibliographicCitation>
    <dcterms:issued>2004-02-20</dcterms:issued>
    <dcterms:title>N-(17-Phosphonooxylinolenoyl)glutamine and N-(17-phosphonooxylinoleoyl)glutamine from insect gut: the first backbone-phosphorylated fatty acid derivatives in nature</dcterms:title>
    <dc:creator>Spiteller, Dieter</dc:creator>
    <dc:rights>terms-of-use</dc:rights>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/28"/>
    <dcterms:abstract xml:lang="eng">N-(17-Phosphonooxylinolenoyl)glutamine (1) and N-(17-phosphonooxylinoleoyl)glutamine (2) were isolated from the regurgitate of Spodoptora exigua and identified as the first natural alkyl chain-phosphorylated fatty acid derivatives. The compounds were characterized by HPLC-MS/MS and the assigned structures confirmed by synthesis via a dissymmetric bis-Wittig approach as the key reaction. Rearing of the larvae on a diet enriched with inorganic phosphate increased the amount of the phosphorylated N-acyl glutamines in the regurgitate.</dcterms:abstract>
    <dc:language>eng</dc:language>
    <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/15548"/>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/28"/>
    <dc:creator>Boland, Wilhelm</dc:creator>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-10-20T08:46:21Z</dcterms:available>
    <dc:contributor>Boland, Wilhelm</dc:contributor>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-10-20T08:46:21Z</dc:date>
    <dc:contributor>Oldham, Neil J.</dc:contributor>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
  </rdf:Description>
</rdf:RDF>
kops.flag.knbibliographyfalse
kops.identifier.nbnurn:nbn:de:bsz:352-155488deu
kops.sourcefieldThe Journal of Organic Chemistry. 2004, <b>69</b>(4), pp. 1104-1109. ISSN 0022-3263. Available under: doi: 10.1021/jo035382gdeu
kops.sourcefield.plainThe Journal of Organic Chemistry. 2004, 69(4), pp. 1104-1109. ISSN 0022-3263. Available under: doi: 10.1021/jo035382gdeu
kops.sourcefield.plainThe Journal of Organic Chemistry. 2004, 69(4), pp. 1104-1109. ISSN 0022-3263. Available under: doi: 10.1021/jo035382geng
kops.submitter.emaillarysa.herasymova@uni-konstanz.dedeu
relation.isAuthorOfPublication0cdf1a72-a100-471b-ae60-229ddfb1ccc9
relation.isAuthorOfPublication.latestForDiscovery0cdf1a72-a100-471b-ae60-229ddfb1ccc9
source.bibliographicInfo.fromPage1104
source.bibliographicInfo.issue4
source.bibliographicInfo.toPage1109
source.bibliographicInfo.volume69
source.identifier.issn0022-3263
source.periodicalTitleThe Journal of Organic Chemistry

Dateien

Lizenzbündel

Gerade angezeigt 1 - 1 von 1
Vorschaubild nicht verfügbar
Name:
license.txt
Größe:
1.92 KB
Format:
Plain Text
Beschreibung:
license.txt
license.txtGröße: 1.92 KBDownloads: 0

Sammlungen

Biologie: Publikationen