Publikation:

ansa-Metallocene Derivatives : IV. Synthesis and molecular structures of chiral ansa-titanocene derivatives with bridged tetrahydroindenyl ligands

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1982

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Wild, Ferdinand R. W. P.
Zsolnai, Laszlo
Huttner, Gottfried

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http://nbn-resolving.de/urn:nbn:de:bsz:352-239616
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https://doi.org/10.1016/S0022-328X(00)89067-1
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Journal of Organometallic Chemistry. 1982, 232(3), pp. 233-247. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(00)89067-1

Zusammenfassung

A synthesis for racemic ethylene-bis(4,5,6,7-tetrahydro-1-indenyl)titanium dichloride is described. The molecular structures of this compound, of its meso- isomer and of a binaphtholate complex of the (S,S)-enantiomer have been determined. Cleavage of this binaphtholate complex gives the pure (S,tS)-enentiomer.

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ISO 690WILD, Ferdinand R. W. P., Laszlo ZSOLNAI, Gottfried HUTTNER, Hans-Herbert BRINTZINGER, 1982. ansa-Metallocene Derivatives : IV. Synthesis and molecular structures of chiral ansa-titanocene derivatives with bridged tetrahydroindenyl ligands. In: Journal of Organometallic Chemistry. 1982, 232(3), pp. 233-247. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(00)89067-1
BibTex
@article{Wild1982ansaM-23961,
  year={1982},
  doi={10.1016/S0022-328X(00)89067-1},
  title={ansa-Metallocene Derivatives : IV. Synthesis and molecular structures of chiral ansa-titanocene derivatives with bridged tetrahydroindenyl ligands},
  number={3},
  volume={232},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={233--247},
  author={Wild, Ferdinand R. W. P. and Zsolnai, Laszlo and Huttner, Gottfried and Brintzinger, Hans-Herbert}
}
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