Synthesis of (±)-Chokol A by a Tandem Michael-Addition/Dieckmann Cyclization

Kurzanzeige
dc.contributor.authorGroth, Ulrich
dc.contributor.authorHalfbrodt, Wolfgangdeu
dc.contributor.authorKöhler, Thomasdeu
dc.contributor.authorKreye, Pauldeu
dc.date.accessioned2011-03-24T18:16:11Zdeu
dc.date.available2011-03-24T18:16:11Zdeu
dc.date.issued1994deu
dc.description.abstractA total synthesis of (±)-chokol A (rac-12) was accomplished in five steps by starting from the α,β-unsaturated ester (E)-2 in an overall yield of 24%. The key step of this synthesis is the tandem conjugate addition/Dieckmann cyclization of the cuprate derived from vinyl bromide 9 with the α,β-unsaturated ester (E)-2.deu
dc.description.versionpublished
dc.format.mimetypeapplication/pdfdeu
dc.identifier.citationFirst publ. in: Liebigs Annalen der Chemie 1994, 9, pp. 885-890deu
dc.identifier.ppn276763688deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/10041
dc.language.isoengdeu
dc.legacy.dateIssued2008deu
dc.rightsAttribution-NonCommercial-NoDerivs 2.0 Generic
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.0/
dc.subjectChokol Adeu
dc.subjectTandem reactionsdeu
dc.subjectCyclopentanesdeu
dc.subjectOrganometallic reagentsdeu
dc.subjectAntifungal agentsdeu
dc.subjectTerpenesdeu
dc.subject.ddc540deu
dc.titleSynthesis of (±)-Chokol A by a Tandem Michael-Addition/Dieckmann Cyclizationeng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Groth1994Synth-10041,
  year={1994},
  title={Synthesis of (±)-Chokol A by a Tandem Michael-Addition/Dieckmann Cyclization},
  number={9},
  issn={0170-2041},
  journal={Liebigs Annalen der Chemie},
  pages={885--890},
  author={Groth, Ulrich and Halfbrodt, Wolfgang and Köhler, Thomas and Kreye, Paul}
}
kops.citation.iso690GROTH, Ulrich, Wolfgang HALFBRODT, Thomas KÖHLER, Paul KREYE, 1994. Synthesis of (±)-Chokol A by a Tandem Michael-Addition/Dieckmann Cyclization. In: Liebigs Annalen der Chemie. 1994(9), pp. 885-890. ISSN 0170-2041. eISSN 1099-0690deu
kops.citation.iso690GROTH, Ulrich, Wolfgang HALFBRODT, Thomas KÖHLER, Paul KREYE, 1994. Synthesis of (±)-Chokol A by a Tandem Michael-Addition/Dieckmann Cyclization. In: Liebigs Annalen der Chemie. 1994(9), pp. 885-890. ISSN 0170-2041. eISSN 1099-0690eng
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