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Real-space imaging of translational and rotational dynamics of hard spheres from the fluid to the crystal

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2017

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Soft Matter. 2017, 13(44), pp. 8240-8249. ISSN 1744-683X. eISSN 1744-6848. Available under: doi: 10.1039/c7sm01400g

Zusammenfassung

Using real-space imaging of single particles, we investigate the interplay between translational and rotational motion of tracer particles in suspensions of colloidal particles over a wide range of volume fractions from dilute fluid to densely packed crystal. To this end, we introduce a new type of spherical colloidal tracer particles containing two differently labelled fluorescent cores. The tracer particles can be combined with host particles enclosing a single fluorescent core and chemical and physical properties identical to the tracers. This leads to a system of spherical colloidal particles, in which spatio-temporal trajectories of rotation and translation of individual particles can be recorded simultaneously with full 360° resolution of rotational dynamics. Our analysis shows that translation and rotation of colloidal particles are uncorrelated and decoupled for all volume fractions irrespective of the phase of the particle system.

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540 Chemie

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ISO 690SCHÜTTER, Stefan, Jörg ROLLER, Andrea KICK, Janne-Mieke MEIJER, Andreas ZUMBUSCH, 2017. Real-space imaging of translational and rotational dynamics of hard spheres from the fluid to the crystal. In: Soft Matter. 2017, 13(44), pp. 8240-8249. ISSN 1744-683X. eISSN 1744-6848. Available under: doi: 10.1039/c7sm01400g
BibTex
@article{Schutter2017-11-15Reals-40991,
  year={2017},
  doi={10.1039/c7sm01400g},
  title={Real-space imaging of translational and rotational dynamics of hard spheres from the fluid to the crystal},
  number={44},
  volume={13},
  issn={1744-683X},
  journal={Soft Matter},
  pages={8240--8249},
  author={Schütter, Stefan and Roller, Jörg and Kick, Andrea and Meijer, Janne-Mieke and Zumbusch, Andreas}
}
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